Organic electroluminescence element, manufacturing method thereof, and organic electroluminescence display device
An organic EL element ( 1 ) includes a three-layer-structured light-emitting layer ( 5 ). A first light-emitting layer ( 5 a ) is made of a host material higher in HOMO than an organic light-emitting material (|HOMO (host material for first light-emitting layer)|>|HOMO (phosphorescence-emitting material)|). A second light-emitting layer ( 5 c ) is made of a host material lower in LUMO than the organic light-emitting material (|LUMO (host material for second light-emitting layer) |<|LUMO (phosphorescence-emitting material)|). A third light-emitting layer ( 5 b ) is made of a material higher in HOMO and lower in LUMO than the organic light-emitting material (|HOMO (host material for third light-emitting layer)|>|HOMO (phosphorescence-emitting material)|, |LUMO (host material for third light-emitting layer)|<|LUMO (phosphorescence-emitting material)|). This ensures transferring holes and electrons to the third light-emitting layer ( 5 c ). Consequently, a recombination ratio between holes and electrons increases, a voltage for driving the organic EL element ( 1 ) decreases, and light-emitting efficiency increases.
1. An organic electroluminescence element, comprising: on a substrate, a cathode and an anode; and an organic layer between the cathode and the anode, the organic layer including at least a light-emitting layer,
the light-emitting layer including:
a first light-emitting layer which is positioned closer to the cathode and which is made of a first host material;
a second light-emitting layer which is positioned closer to the anode and which is made of a second host material; and
a third light-emitting layer which is positioned between the first light-emitting layer and the second light-emitting layer and which is made of a third host material,
the first host material, the second host material, and the third host material being different from one another, and the first host material, the second host material, and the third host material being doped with a same organic light-emitting material, and
the first host material, the second host material, the third host material, and the organic light-emitting material meeting equations (1) and (2) below in terms of Highest Occupied Molecular Orbital (HOMO) and Lowest Unoccupied Molecular Orbital (LUMO):
|HOMO of the first host material|>|HOMO of the organic light-emitting material| and |HOMO of the organic light-emitting material|<|HOMO of the third host material| (1)
|LUMO of the second host material|<|LUMO of the organic light-emitting material| and |LUMO of the organic light-emitting material|>|LUMO of the third host material| (2).
2. The organic electroluminescence element as set forth in claim 1 , wherein the first host material, the second host material, and the organic light-emitting material meet equations (3) and (4) below in terms of Highest Occupied Molecular Orbital (HOMO) and Lowest Unoccupied Molecular Orbital (LUMO):
|LUMO of the first host material|>|LUMO of the organic light-emitting material| (3)
|HOMO of the second host material|<|HOMO of the organic light-emitting material| (4).
3. The organic electroluminescence element as set forth in claim 1 , wherein the first host material, the second host material, and the third host material each have an excited triplet level higher than an excited triplet level of the organic light-emitting material.
4. The organic electroluminescence element as set forth in claim 1 , wherein the first host material, the second host material, and the third host material meet equations (5) and (6) below in terms of electron hole mobility and electron mobility:
Electron hole mobility of the first host material>electron hole mobility of the third host material (5)
Electron mobility of the second host material>electron mobility of the third host material (6).
5. The organic electroluminescence element as set forth in claim 1 , wherein the first host material, the second host material, and the third host material meet equations (7) and (8) below in terms of thickness:
Thickness of the first light-emitting layer>thickness of the third light-emitting layer, and thickness of the third light-emitting layer<thickness of the second light-emitting layer (7)
5 {acute over (Å)}<thickness of the third light-emitting layer<42 {acute over (Å)} (8).
6. The organic electroluminescence element as set forth in claim 1 , wherein the third light-emitting layer meets equation (9) below in terms of thickness:
10 {acute over (Å)}<thickness of the third light-emitting layer<30 {acute over (Å)} (9).
7. The organic electroluminescence element as set forth in claim 1 , wherein the first host material, the second host material, and the organic light-emitting material meet at least one of equations (10) and (11) below in terms of Highest Occupied Molecular Orbital (HOMO) and Lowest Unoccupied Molecular Orbital (LUMO):
0 eV<(|LUMO of the first host material|−|LUMO of the organic light-emitting material|)≦0.5 eV (10)
0 eV<(|HOMO of the organic light-emitting material|−|HOMO of the second host material|)≦0.5 eV (11).
8. The organic electroluminescence element as set forth in claim 1 , wherein the first host material, the second host material, and the organic light-emitting material meet at least one of equations (12) and (13) below in terms of Highest Occupied Molecular Orbital (HOMO) and Lowest Unoccupied Molecular Orbital (LUMO):
0.1 eV≦(|LUMO of the first host material|−|LUMO of the organic light-emitting material|)≦0.3 eV (12)
0.1 eV (|HOMO of the organic light-emitting material|−|HOMO of the second host material|)≦0.3 eV (13).
9. The organic electroluminescence element as set forth in claim 1 , wherein
the organic layer includes
an electron hole injection layer doped with a dopant for facilitating injection of electron holes from the cathode to the organic layer, and
an electron injection layer doped with a dopant for facilitating injection of electrons from the anode to the organic layer.
10. The organic electroluminescence element as set forth in claim 9 , wherein between the electron hole injection layer and the light-emitting layer, there is provided a region which is not doped with the dopant and the organic light-emitting material.
11. The organic electroluminescence element as set forth in claim 10 , wherein between the electron injection layer and the light-emitting layer, there is provided a region which is not doped with the dopant and the organic light-emitting material.
12. The organic electroluminescence element as set forth in claim 1 , wherein the organic light-emitting material is a phosphorescence-emitting material.
13. An organic electroluminescence display device, comprising display means in which an organic electroluminescence element as set forth in claim 1 is formed on a thin film transistor substrate.
14. A manufacturing method of an organic electroluminescence element including: on a substrate, a cathode and an anode; and an organic layer between the cathode and the anode, the organic layer including at least a light-emitting layer,
the manufacturing method comprising:
a cathode formation step of forming the cathode on the substrate;
an electron hole injection layer formation step of forming, on the cathode, an electron hole injection layer to which electron holes are injected from the cathode;
an electron hole transportation layer formation step of forming, on the electron hole injection layer, an electron hole transportation layer via which electron holes injected from the cathode to the organic layer are transported;
a first light-emitting layer formation step of forming, on the electron hole transportation layer, a first light-emitting layer as the light-emitting layer, the first light-emitting layer being made of a first host material;
a third light-emitting layer formation step of forming, on the first light-emitting layer, a third light-emitting layer as the light-emitting layer, the third light-emitting layer being made of a third host material;
a second light-emitting layer formation step of forming, on the third light-emitting layer, a second light-emitting layer as the light-emitting layer, the second light-emitting layer being made of a second host material;
an electron transportation layer formation step of forming, on the second light-emitting layer, an electron transportation layer via which electrons injected from the anode to the organic layer are transported;
an electron injection layer formation step of forming, on the electron transportation layer, an electron injection layer to which electrons are injected from the anode; and
an anode formation step of forming the anode on the electron injection layer,
in the first light-emitting layer formation step, the second light-emitting layer formation step, and the third light-emitting layer formation step,
the first host material, the second host material, and the third host material being different from one another,
the first host material, the second host material, and the third host material being doped with a same organic light-emitting material, and
the first host material, the second host material, the third host material, and the organic light-emitting material meeting equations (14) and (15) below in terms of Highest Occupied Molecular Orbital (HOMO) and Lowest Unoccupied Molecular Orbital (LUMO):
|HOMO of the first host material|>|HOMO of the organic light-emitting material| and |HOMO of the organic light-emitting material|<|HOMO of the third host material| (14)
|LUMO of the second host material |<|LUMO of the organic light-emitting material |and |LUMO of the organic light-emitting material |>|LUMO of the third host material| (15).
15. The manufacturing method as set forth in claim 14 , wherein the first host material, the second host material, and the organic light-emitting material meet at least one of equations (16) and (17) below in terms of Highest Occupied Molecular Orbital (HOMO) and Lowest Unoccupied Molecular Orbital (LUMO):
|LUMO of the first host material|>|LUMO of the organic light-emitting material| (16)
|HOMO of the second host material |<|HOMO of the organic light-emitting material | (17).