IP Library › Granted Patent US 8,859,179
Granted Patent B2
US 8,859,179 · App. 13/679,057 · Granted Oct 14, 2014

Developer for electrophotography, image forming apparatus and process cartridge

Inventors: Hideyuki Santo (Shizuoka, JP); Masahide Yamada (Shizuoka, JP); Kazumi Suzuki (Shizuoka, JP); Shinya Nakayama (Shizuoka, JP); Atsushi Yamamoto (Shizuoka, JP); Tatsuya Morita (Kanagawa, JP); Shingo Sakashita (Shizuoka, JP); Yukiko Nakajima (Kanagawa, JP); Keiji Makabe (Shizuoka, JP); Daiki Yamashita (Kanagawa, JP)
Assignee: Ricoh Company, Ltd.
G03G9/0832G03G9/1131G03G9/08797G03G9/107
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Quick Facts
Patent No.
US 8,859,179
App. No.
13/679,057
Granted
Oct 14, 2014
Kind
B2
Abstract

A developer, including a toner including a binder resin comprising a crystalline resin; and a colorant, and a resin carrier comprising a resin; a magnetic particulate material having a magnetic anisotropy, dispersed in the resin, and having a saturated magnetization of from 16 to 30 emu/g, a coercive force of from 15 to 40 kA/m and an average particle diameter not less than 15 μm and less than 100 μm.

Claims (27)

1. A developer, comprising:

a toner comprising:

a binder resin comprising a crystalline resin; and

a colorant, and

a resin carrier comprising:

a resin;

wherein the resin carrier has a magnetic particulate material having a magnetic anisotropy, dispersed in

the resin, and

wherein the resin carrier has a saturated magnetization of from 16 to 30 emu/g, a coercive force of from 15 to 40 kA/m and an average particle diameter not less than 15 μm and less than 100 μm,

wherein the binder resin comprises the crystalline resin in an amount not less than 50% by weight.

2. The developer of claim 1 , wherein the toner is prepared by dispersing or emulsifying at least the binder resin and the colorant in an aqueous medium.

3. The developer of claim 1 , wherein the crystalline resin is at least a resin selected from the group consisting of a polyester resin, a polyurethane resin, a polyurea resin, a polyamide resin and a polyether resins.

4. The developer of claim 1 , wherein the crystalline resin comprises at least one of a urethane skeleton and a urea skeleton.

5. The developer of claim 1 , wherein the crystalline resin comprises a crystalline resin (A) and a crystalline resin (B) having a weight-average molecular weight (Mw) different from each other.

6. The developer of claim 1 , wherein the toner satisfies the following relationships:

45 ≦Ta≦ 70, and 0.8 ≦Tb/Ta≦ 1.55

wherein Ta (° C.) is the maximum peak temperature of heat of melting the toner measured by a differential scanning calorimeter, and Tb (° C.) is a softening point of the toner measured by an elevated flow tester; and

1.0×10 3 ≦G ′( Ta+ 20)≦5.0×10 6 and 1.0×10 3 ≦G ″( Ta+ 20)≦5.0×10 6

wherein G′(Ta+20) (Pa·s) is the storage elastic modulus of the toner at the temperature of (Ta+20)° C., and G″(Ta+20) (Pa·s) is the loss elastic modulus of the toner at the temperature of (Ta+20)° C.

7. The developer of claim 1 , wherein the resin carrier comprises the resin and the magnetic particulate material in a weight ratio (binder resin/magnetic particulate material) of from 65/35 to 80/20.

8. The developer of claim 1 , wherein the resin carrier is a rare earth-iron-nitrogen magnet powder.

9. The developer of claim 1 , wherein the resin carrier is prepared by melt-kneading the magnetic particulate material in the resin and then leaving the resultant resin powder for 10 sec or longer in a magnetic flux density of 2 T (tesla) or higher.

10. An image forming method, comprising:

forming an electrostatic latent image;

developing the electrostatic latent image with the developer according to claim 1 to form a toner image;

transferring the toner image onto a transfer paper; and

fixing the toner image thereon.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 16, 2012
From: SANTO, HIDEYUKI; YAMADA, MASAHIDE; SUZUKI, KAZUMI; NAKAYAMA, SHINYA; YAMAMOTO, ATSUSHI; MORITA, TATSUYA; SAKASHITA, SHINGO; NAKAJIMA, YUKIKO; MAKABE, KEIJI; YAMASHITA, DAIKI
To: RICOH COMPANY, LTD.
Reel/Frame 029313/0080 →
Priority Claims (1)
JP 2011-278846 · Dec 20, 2011 · national
Continuity (1)
Related Publication 20130157183A1 · Jun 20, 2013