Wetting agents and dispersants based on mixtures of structure copolymers
The invention relates to compositions comprising two structured linear copolymers selected from the group consisting of block copolymers and gradient copolymers, these copolymers being prepared by different controlled polymerization techniques and the difference in the polydispersities of these copolymers, Δ(M w /M n ), being ≧0.25. The invention further relates to the production of such blends and to their use as wetting agents and dispersants.
1. A composition comprising two structured linear copolymers selected from the group consisting of block copolymers, wherein:
the copolymers are prepared by different controlled polymerization techniques and the difference in the polydispersities of the copolymers, Δ(M w /M n ), is ≧0.25;
one or more of the block copolymers being AB, ABA or ABC block copolymers; and
at least one of the blocks of the block copolymer being composed of at least two different copolymerized ethylenically unsaturated monomers.
2. Composition according to claim 1 , one block copolymer being an AB block copolymer and the other block copolymer being an AB, ABA or ABC block copolymer.
3. Composition according to claim 1 , all blocks within a block copolymer being composed of in each case at least two different copolymerized ethylenically unsaturated monomers.
4. Composition according to claim 1 , the two structured linear copolymers being present in a weight ratio of 5:95 to 95:5 to one another.
5. Composition according to claim 1 , the polydispersity of the copolymers possessing in each case a value from 1.05 to 4.
6. Composition according to claim 1 , the number-average molar mass of the copolymers being in each case from 1000 to 20 000 g/mol.
7. Composition according to claim 1 , the controlled polymerization techniques being selected from the group consisting of RAFT, NMP, ATRP, GTP, controlled free-radical polymerization with tetraphenylethane, controlled free-radical polymerization with 1,1-diphenylethene, controlled free-radical polymerization with iniferters, and controlled free-radical polymerization with organocobalt complexes.
8. Composition according to claim 1 , being a wetting agent and dispersant.
9. Composition according to claim 8 , containing not more than 10% by weight of one or more random copolymers or homopolymers.
10. Composition according to claim 9 , being substantially free from random copolymers and homopolymers.
11. Process for producing the compositions according to claim 1 , the copolymers being blended in solution, with heating where appropriate.
12. Paints, inks, paper coatings, colours for leather or for textiles, pastes, pigment concentrates, ceramics, cosmetic preparations, casting or moulding compounds, colour filters for liquid-crystal displays, liquid-crystal screens, colour resolution devices, sensors, plasma screens, SED-based displays, and for MLCC; comprising the composition of claim 1 .
13. Pigments or fillers coated with the wetting agent and/or dispersant composition of claim 8 .
14. The pigments or fillers of claim 13 , said pigments or fillers possessing a particle size below 100 nm.
15. Paints, pastes, casting compounds or moulding compounds comprising a composition according to claim 1 .
16. Pigments or fillers coated with a composition obtained by the process according to claim 11 .
17. The composition of claim 1 , wherein the Δ(M w /M n ) is from about 0.5 to about 1.3.
18. The composition of claim 1 , wherein the Δ(M w /M n ) is from about 0.25 to about 1.30.
19. The composition of claim 1 , wherein the Δ(M w /M n ) is from about 0.25 to about 3.