Adhesive composition for an optical film
A non-crosslinking type adhesive composition for an optical film is provided that has excellent adhesion to a substrate, allows peeling to be carried out at a suitable peeling strength without leaving an adhesive residue, has excellent reworking properties, can maintain good adhesion properties for a long time, and has excellent durability. The adhesive composition for an optical film includes an acrylic triblock copolymer, which does not have an NCO functional group, and an isocyanate compound. The acrylic triblock copolymer (I), which is represented by the formula A1-B-A2, is formed by alkyl methacrylate polymer blocks A1 and A2 having a Tg of 100° C. or more and an alkyl acrylate polymer block B having a Tg of −20° C. or less, wherein the content of the block B is 40 to 95 mass %, Mw is 50,000 to 300,000, and the molecular weight distribution is 1.0 to 1.5. Based on the mass of the solids in the adhesive composition, the content of the acrylic triblock copolymer (I) is 60 mass % or more, and the content of the isocyanate compound is 0.0015 mass % or more to less than 0.35 mass % in terms of NCO group content.
1. An adhesive composition, comprising:
an isocyanate compound; and
an acrylic triblock copolymer (I)
represented by formula (1):
A1-B-A2 (1),
where A1 and A2 each independently represent an alkyl methacrylate polymer block that does not have a functional group that reacts with the isocyanate compound and has a glass transition temperature of 100° C. or more, and B represents an alkyl acrylate polymer block that does not have a functional group that reacts with the isocyanate compound and has a glass transition temperature of −20° C. or less,
wherein:
the acrylic triblock copolymer (I) has a content of the polymer block B of from 40 to 95 mass %, a weight average molecular weight Mw of from 50,000 to 300,000, and a molecular weight distribution Mw/Mn of from 1.0 to 1.5;
the adhesive composition has a content of the acrylic triblock copolymer (I) of 60 mass % or more based on a mass of solids in the adhesive composition;
the adhesive composition has a content of isocyanate groups of from 0.0015 mass % or more to less than 0.35 mass %, based on the mass of solids in the adhesive composition, said isocyanate groups being comprised in the isocyanate compound; and
the adhesive composition is suitable for an optical film.
2. The adhesive composition of claim 1 , further comprising:
from 3 to 25 mass % of an acrylic diblock copolymer (II), based on the mass of solids in the adhesive composition,
wherein
the acrylic diblock copolymer (II)
is represented by formula (2):
C-D (2)
where C represents an alkyl methacrylate polymer block that does not have a functional group that reacts with the isocyanate compound and D represents an alkyl acrylate polymer block that does not have a functional group that reacts with the isocyanate compound; and
the acrylic diblock copolymer (II) has a content of the polymer block D of from 40 to 95 mass %, a weight average molecular weight Mw of from 30,000 to 300,000, and a molecular weight distribution Mw/Mn of from 1.0 to 1.5.
3. The adhesive composition of claim 1 , further comprising:
from 0.1 to 10 mass % of an antistatic agent, based on the mass of solids in the adhesive composition.
4. The adhesive composition of claim 3 , further comprising:
from 0.05 to 9.5 mass % of a polyol compound, based on the mass of solids in the adhesive composition.
5. The adhesive composition of claim 3 , wherein the antistatic agent is an ion conductive agent comprising an alkali metal salt.
6. The adhesive composition of claim 3 , wherein the antistatic agent is an ionic liquid.
7. The adhesive composition of claim 1 , further comprising:
from 0.01 to 3 mass % of a silane coupling agent, based on the mass of solids in the adhesive composition.
8. A film, comprising a pressure sensitive adhesive layer formed from the adhesive composition of claim 1 ,
wherein the film is a pressure sensitive adhesive optical film or a pressure sensitive adhesive protective film for an optical film.
9. An image display device, comprising the film of claim 8 .
10. The adhesive composition of claim 2 , further comprising:
from 0.1 to 10 mass % of an antistatic agent, based on the mass of solids in the adhesive composition.
11. The adhesive composition of claim 10 , further comprising:
from 0.05 to 9.5 mass % of a polyol compound, based on the mass of solids in the adhesive composition.
12. The adhesive composition of claim 4 , wherein the antistatic agent is an ion conductive agent comprising an alkali metal salt.
13. The adhesive composition of claim 10 , wherein the antistatic agent is an ion conductive agent comprising an alkali metal salt.
14. The adhesive composition of claim 4 , wherein the antistatic agent is an ionic liquid.
15. The adhesive composition of claim 10 , wherein the antistatic agent is an ionic liquid.
16. The adhesive composition of claim 2 , further comprising:
from 0.01 to 3 mass % of a silane coupling agent, based on the mass of solids in the adhesive composition.
17. The adhesive composition of claim 3 , further comprising:
from 0.01 to 3 mass % of a silane coupling agent, based on the mass of solids in the adhesive composition.
18. The adhesive composition of claim 4 , further comprising:
from 0.01 to 3 mass % of a silane coupling agent, based on the mass of solids in the adhesive composition.
19. The adhesive composition of claim 5 , further comprising:
from 0.01 to 3 mass % of a silane coupling agent, based on the mass of solids in the adhesive composition.
20. The adhesive composition of claim 1 , wherein the isocyanate compound increases interfacial adhesive strength between the adhesive composition and the optical film.