Semiconductor device and method of manufacturing the same
A semiconductor device includes a channel region extending in a vertical direction perpendicular to a substrate and having a nitrogen concentration distribution, a plurality of gate electrodes arranged on a side wall of the channel region and separated from each other in a vertical direction, and a gate dielectric layer disposed between the channel region and the gate electrodes. The nitrogen concentration distribution has a first concentration near an interface between the channel region and the gate dielectric layer.
1. A semiconductor device comprising:
a channel region extending in a vertical direction perpendicular to a substrate;
a plurality of gate electrodes arranged on a side wall of the channel region and separated from each other in a vertical direction; and
a gate dielectric layer disposed between the channel region and the gate electrodes,
wherein the channel region comprises a first semiconductor layer and a second semiconductor layer,
wherein the first semiconductor layer includes nitrogen atoms of a first concentration near an interface between the channel region and the gate dielectric layer,
wherein one side of the first semiconductor layer is in contact with the gate dielectric layer and other side of the first semiconductor layer is in contact with the second semiconductor layer, and
wherein a thickness of the first semiconductor layer is less than a thickness of the second semiconductor layer.
2. The semiconductor device of claim 1 , wherein the second semiconductor layer includes nitrogen atoms of a second concentration that is lower than the first concentration.
3. The semiconductor device of claim 2 , wherein the second concentration of the nitrogen in the second semiconductor layer ranges from about 20 ppm to about 0.2 at. %.
4. The semiconductor device of claim 2 , wherein the first semiconductor layer is a cylindrical structure including a closed bottom, the closed bottom being in contact with the substrate, and the second semiconductor layer is formed on an entire inner wall of the first semiconductor layer.
5. The semiconductor device of claim 4 , further comprising an insulating pillar disposed on the second semiconductor layer.
6. The semiconductor device of claim 4 , wherein the substrate includes a recessed region and the closed bottom is disposed in the recessed region.
7. The semiconductor device of claim 1 , wherein the first concentration of the nitrogen in the first semiconductor layer ranges from about 0.2 at. % to about 4 at. %.
8. The semiconductor device of claim 1 , wherein a thickness of the second semiconductor layer ranges from twice to twenty times that of the first semiconductor layer.
9. The semiconductor device of claim 8 , wherein the channel region comprises silicon-nitrogen bonding.
10. The semiconductor device of claim 1 , wherein the gate dielectric layer comprises a tunnel insulating layer, a charge trapping layer, and a blocking insulating layer that are sequentially stacked on the side wall of the channel region, wherein the gate dielectric layer is disposed on the channel region.
11. The semiconductor device of claim 1 , wherein the channel region is a pillar structure whose outer wall is a first region and whose inside is a second region disposed in the first region, wherein the first region includes nitrogen atoms at a first concentration and the second region includes nitrogen atoms at a second concentration less than the first concentration.
12. The semiconductor device of claim 1 , further comprising a plurality of insulating layers disposed between the gate electrodes, respectively, wherein a lowermost insulating layer of the insulating layers is in contact with the substrate.
13. The semiconductor device of claim 1 , wherein the first and second semiconductor layers are formed of polysilicon.