Separator for non-aqueous secondary battery, process for producing the same, and non-aqueous secondary battery
A first object of the present invention is to provide a separator including a polyethylene microporous membrane and a heat-resistant porous layer, and that has a sufficient shutdown function and a sufficient heat resistance, and can be formed with a reduced thickness and can overcome the problem of slidability. A first aspect of the present invention is a separator for a non-aqueous secondary battery. The separator includes a microporous membrane of primarily polyethylene, and a heat-resistant porous layer of a primarily heat-resistant polymer formed on at least one surface of the microporous membrane. (1) The microporous membrane has a Gurley number of 25 to 35 sec/100 cc·μm per unit thickness. (2) The heat-resistant porous layer contains inorganic fine particles having an average particle diameter of 0.1 to 1.0 μm. (3) The inorganic fine particles are 40% to 80% in volume with respect to a total volume of the heat-resistant polymer and the inorganic fine particles. (4) The heat-resistant porous layer has a total thickness of 3 to 12 μm.
1. A separator for a non-aqueous secondary battery, comprising:
a microporous membrane of primarily polyethylene; and
a heat-resistant porous layer of primarily a wholly aromatic polyamide formed on at least one surface of the microporous membrane,
the separator characterized in that:
(1) the heat-resistant porous layer contains inorganic fine particles having an average particle diameter of 0.1 to 1.0 μm; and
(2) the inorganic fine particles are 40% to 80% in volume with respect to a total volume of the wholly aromatic polyamide and the inorganic fine particles.
2. The separator according to claim 1 , wherein the heat-resistant porous layer is formed on both surfaces of the microporous membrane.
3. The separator according to claim 1 , wherein the wholly aromatic polyamide is a meta-type wholly aromatic polyamide.
4. The separator according to claim 1 , wherein the heat-resistant porous layer is formed on both surfaces of the microporous membrane, wherein the microporous membrane is made of polyethylene, and wherein the wholly aromatic polyamide is a meta-type wholly aromatic polyamide.
5. The separator according to claim 3 , wherein the meta-type wholly aromatic polyamide is a poly-m-phenyleneisophthalamide.
6. The separator according to claim 1 , wherein the microporous membrane has a penetration strength of 250 g or more.
7. The separator according to claim 1 , wherein the microporous membrane has a thickness of 7 to 16 μm, and wherein the separator has a thickness of 20 μm or less as a whole.
8. The separator according to claim 1 , wherein the heat-resistant porous layer has a total thickness of 3 to 12 μm when formed on both surfaces of the microporous membrane, and a thickness of 3 to 12 μm when formed on only one surface of the microporous membrane.
9. The separator according to claim 1 , wherein the inorganic fine particles are made of alumina.
10. A producing process of a separator for a non-aqueous secondary battery of claim 1 , the separator including a microporous membrane of primarily polyethylene, and a heat-resistant porous layer of primarily a wholly aromatic polyamide formed on at least one surface of the microporous membrane,
the process characterized by comprising the following steps:
(1) applying a coating liquid to at least one surface of the microporous membrane, the coating liquid including a wholly aromatic polyamide, inorganic fine particles, a solvent for dissolving the wholly aromatic polyamide, and a solvent that serves as a poor solvent for the wholly aromatic polyamide;
(2) solidifying the coating liquid by immersing the microporous membrane in a mixture of the solvent for dissolving the wholly aromatic polyamide, and the solvent that serves as a poor solvent for the wholly aromatic polyamide, after applying the coating liquid to the microporous membrane;
(3) performing water washing to remove the solvent mixture; and
(4) performing drying to remove the water,
the inorganic fine particles used in said step (1) having an average particle diameter of 0.1 to 1.0 μm, and being contained in an amount of 40 to 80 volume % with respect to a total volume of the wholly aromatic polyamide and the inorganic fine particles.
11. A non-aqueous secondary battery using a separator of claim 1 .
12. The separator according to claim 2 , wherein the wholly aromatic polyamide is a meta-type wholly aromatic polyamide.
13. The separator according to claim 4 , wherein the meta-type wholly aromatic polyamide is a poly-m-phenyleneisophthalamide.
14. The separator according to claim 12 , wherein the meta-type wholly aromatic polyamide is a poly-m-phenyleneisophthalamide.
15. The separator according to claim 1 , wherein the inorganic fine particles are 45% to 80% in volume with respect to a total volume of the heat-resistant polymer and the inorganic fine particles.