Foamable sunscreen formulation
The present application relates to sunscreen formulations, including foamable sunscreen formulations, that comprise zinc oxide and titanium dioxide particles, suitably in the size range of about 1-100 nm. The compositions suitably produce a minimal residual whitening effect when applied to a skin surface.
1. A foamable sunscreen formulation consisting essentially of:
a) about 1 wt % to about 25 wt % zinc oxide particles having a primary particle size of about 10 nm to about 50 nm;
b) about 1 wt % to about 25 wt % titanium dioxide particles having a primary particle size of about 10 nm to about 50 nm;
c) about 0.1 wt % to about 10 wt % emulsion stabilizer;
d) about 0.1 wt % to about 25 wt % skin conditioner;
e) about 1 wt % to about 10 wt % emulsifier;
f) about 0.1 wt % to about 10 wt % suspending agent; and
g) the remainder water,
wherein the formulation produces a minimal residual whitening effect when applied to a skin surface.
2. The foamable sunscreen formulation of claim 1 , wherein the zinc oxide particles have a primary particle size of about 10 nm to about 30 nm.
3. The foamable sunscreen formulation of claim 2 , wherein the zinc oxide particles have a primary particle size of about 20 nm.
4. The foamable sunscreen formulation of claim 3 , wherein the zinc oxide particles have a primary particle size of about 10 nm.
5. The foamable sunscreen formulation of claim 1 , comprising about 10 wt % zinc oxide particles.
6. The foamable sunscreen formulation of claim 1 , wherein the titanium dioxide particles have a primary particle size of about 30 nm.
7. The foamable sunscreen formulation of claim 6 , wherein the titanium dioxide particles have a primary particle size of about 20 nm.
8. The foamable sunscreen formulation of claim 5 , comprising about 3 wt % titanium dioxide particles.
9. The foamable sunscreen formulation of claim 1 , wherein the emulsion stabilizer is selected from the group consisting of microcrystalline cellulose, cellulose gum and combinations thereof.
10. The foamable sunscreen formulation of claim 1 , wherein the skin conditioner is selected from the group consisting of C 12-15 alkyl benzoate, octyldodecyl neopentanoate, butyl octyl salicylate, caprylyl glycol, glycerin and combinations thereof.
11. The foamable sunscreen formulation of claim 1 , wherein the emulsifier is selected from the group consisting of glyceryl stearate, ceteareth-20, polysorbate 80 and combinations thereof.
12. The foamable sunscreen formulation of claim 1 , wherein the suspending agent is selected from the group consisting of polyhydroxystearic acid, methyl methacrylate crosspolymer and combinations thereof.
13. The foamable sunscreen formulation of claim 1 , further comprising about 0.5 wt % to about 3 wt % film former.
14. The foamable sunscreen formulation of claim 13 , wherein the film former is selected from the group consisting of polyurethane-2, polymethyl methacrylate, tricontanyl poly(vinyl pyrollidone) (PVP) and combinations thereof.
15. The foamable sunscreen formulation of claim 1 , further comprising about 0.01 wt % to about 1 wt % iron oxide particles having a primary particle size of about 10 nm to about 50 nm.
16. A foamable sunscreen formulation consisting essentially of:
a) about 9 wt % to about 11 wt % zinc oxide particles having a primary particle size of about 20 nm;
b) about 2 wt % to about 4 wt % titanium dioxide particles having a primary particle size of about 30 nm;
c) about 0.5 wt % to about 10.0 wt % emulsion stabilizer;
d) about 15 wt % to about 25 wt % skin conditioner;
e) about 2.5 wt % to about 4.5 wt % emulsifier;
f) about 3.5 wt % to about 5.5 wt % suspending agent;
g) about 1 wt % to about 2.5 wt % film former; and
h) the remainder water,
wherein the formulation produces a minimal residual whitening effect when applied to a skin surface.
17. The foamable sunscreen formulation of claim 16 , comprising about 10 wt % zinc oxide particles.
18. The foamable sunscreen formulation of claim 16 , comprising about 3 wt % titanium dioxide particles.
19. The foamable sunscreen formulation of claim 16 , comprising about 10 wt % zinc oxide particles and about 3 wt % titanium dioxide particles.
20. The foamable sunscreen formulation of claim 16 , wherein the emulsion stabilizer is selected from the group consisting of microcrystalline cellulose, cellulose gum and combinations thereof.
21. The foamable sunscreen formulation of claim 16 , wherein the skin conditioner is selected from the group consisting of C 12-15 alkyl benzoate, octyldodecyl neopentanoate, butyl octyl salicylate, caprylyl glycol, glycerin and combinations thereof.
22. The foamable sunscreen formulation of claim 16 , wherein the emulsifier is selected from the group consisting of glyceryl stearate, ceteareth-20, polysorbate 80 and combinations thereof.
23. The foamable sunscreen formulation of claim 16 , wherein the suspending agent is selected from the group consisting of polyhydroxystearic acid, methyl methacrylate crosspolymer and combinations thereof.
24. The foamable sunscreen formulation of claim 16 , wherein the film former is selected from the group consisting of polyurethane-2, polymethyl methacrylate, tricontanyl poly(vinyl pyrollidone) (PVP) and combinations thereof.
25. The foamable sunscreen formulation of claim 16 , further comprising about 0.05 wt % to about 0.5 wt % iron oxide particles having a primary particle size of about 10 nm to about 50 nm.
26. A foamable sunscreen formulation consisting essentially of:
a) about 10 wt % zinc oxide particles having a primary particle size of about 20 nm;
b) about 3 wt % titanium dioxide particles having a primary particle size of about 30 nm;
c) about 1 wt % microcrystalline cellulose and about 0.2 wt % cellulose gum;
d) about 16 wt % C 12-15 alkyl benzoate, about 1 wt % octyldodecyl neopentanoate, about 1 wt % butyl octyl salicylate;
e) about 1.2 wt % glyceryl stearate, about 0.5 wt % ceteareth-20, and about 2 wt % polysorbate 80;
f) about 1.8 wt % polyhydroxystearic acid and about 2.7 wt % methyl methacrylate crosspolymer;
g) about 0.8 wt % polyurethane-2, about 0.3 wt % polymethyl methacrylate and about 0.6 wt % tricontanyl PVP film; and
i) about 50 wt % to about 60 wt % water,
wherein the formulation produces a minimal residual whitening effect when applied to a skin surface.
27. The foamable sunscreen formulation of claim 26 , further comprising about 0.05 wt % to about 1.0 wt % iron oxide particles having a primary particle size of about 10 nm to about 50 nm.
28. A method of preventing sun damage to a patient's skin surface, comprising applying the foamable sunscreen formulation of claim 1 to the skin surface.
29. The method of claim 28 , wherein the foamable sunscreen formulation is applied at least once a day.
30. The method of claim 28 , wherein the foamable sunscreen formulation is applied to the arms, face, legs, chest, trunk or hands.