Fuel cell system
The degree of dryness in a fuel cell can be judged more accurately. A system has: an impedance calculation part that calculates an impedance of a fuel cell, extracts from the calculated impedance a high-frequency impedance which is an impedance in a high frequency range and a low-frequency impedance which is an impedance in a low frequency range, and subtracts the high-frequency impedance from the low-frequency impedance to calculate a differential impedance; a water content calculation part that calculates the water content of an electrolyte membrane using the high-frequency impedance and calculates the water content of a catalyst layer using the differential impedance; and a water content control part that performs water content recovery processing to increase the water content of the catalyst layer if the water content of the catalyst layer is smaller than a predetermined water content.
1. A fuel cell system comprising:
a fuel cell having a membrane-electrode assembly in which both surfaces of an electrolyte membrane are sandwiched between a pair of catalyst layers, the fuel cell being supplied with reactant gas to generate electric power through an electrochemical reaction of the reactant gas;
an impedance calculation part is programmed to calculate a first impedance which is an impedance of the fuel cell in a first frequency range and which corresponds to resistance of the electrolyte membrane, and also calculates a second impedance which is an impedance of the fuel cell in a second frequency range which is lower than the first frequency range; the second impedance corresponding to the sum of resistance of the electrolyte membrane and resistance of the catalyst layer; and
a water content calculation part is programmed to calculate a differential impedance which is a difference between the second impedance and the first impedance, and, by referring to a correlation between the differential impedance and water content of the catalyst layer, the correlation having been stored in a memory in advance, calculates the water content of the catalyst layer that corresponds to the calculated differential impedance.
2. The fuel cell system according to claim 1 , further comprising a water content control device that performs water content recovery processing to increase the water content of the catalyst layer if the water content of the catalyst layer calculated by the water content calculation part is smaller than a predetermined water content that is set to prevent the catalyst layer from drying.
3. The fuel cell system according to claim 2 , wherein:
the fuel cell has a plurality of unit cells each having the membrane-electrode assembly;
the impedance calculation part is programmed to calculate the first impedance and the second impedance for each of the unit cells;
the water content calculation part is programmed to calculate the water content of the catalyst layer for each of the unit cells by using the differential impedance obtained for each of the unit cells; and
the water content control device performs the water content recovery processing if the water content of the catalyst layer calculated for each of the unit cells includes at least one water content smaller than the predetermined water content.
4. The fuel cell system according to claim 3 , wherein the impedance calculation part is programmed to calculate the first impedance and the second impedance for each divided section prepared by dividing a surface of the unit cell into a plurality of surfaces, and, by using the first impedance and the second impedance calculated for each of the divided sections, calculates the first impedance and the second impedance for each of the unit cells.