Thermoplastic polymer composition
A thermoplastic polymer composition has good flexibility, lightweight properties, moldability, and heat resistance, and in particular, is excellent in wear resistance. The thermoplastic polymer composition includes: at least one block copolymer (a) selected from among an α-methylstyrene based block copolymer having a number average molecular weight of 30,000 to 500,000 and a hydrogenated product thereof, the α-methylstyrene based block copolymer including a polymer block A mainly composed of an α-methylstyrene unit and a polymer block B mainly composed of a conjugated diene unit; a propylene-based polymer (b); and an ethylene-based polymer (c) having a density of 0.94 g/cm 3 or less, in a ratio satisfying the following inequalities (1) and (2): 0.1≦ W ( a )/[ W ( a )+ W ( b )+ W ( c )]≦0.8 (1) 1≦ W ( b )/ W ( c ) (2) wherein W(a), W(b), and W(c) represent the masses of the block copolymer (a), the propylene-based polymer (b), and the ethylene-based polymer (c), respectively.
1. A thermoplastic polymer composition comprising:
at least one block copolymer (a) which is a hydrogenated product of an α-methylstyrene block copolymer having a number average molecular weight of 30,000 to 500,000, wherein the α-methylstyrene block copolymer comprises a polymer block A comprising an α-methylstyrene unit and a polymer block B comprising a conjugated diene unit;
a propylene polymer (b); and
an ethylene polymer (c) having a density of 0.94 g/cm 3 or less, in a ratio satisfying the inequalities (1) and (2):
0.1 ≦W ( a )/[ W ( a )+ W ( b )+ W ( c )]≦0.8 (1)
1 ≦W ( b )/ W ( c ) (2)
wherein W(a), W(b), and W(c) represent masses of the block copolymer (a), the propylene polymer (b), and the ethylene polymer (c), respectively,
wherein polymer block A has a number average molecular weight of 1,000 to 50,000,
wherein the polymer block B comprises (1) a block b1 having a number average molecular weight of 1,000 to 30,000 and having a conjugated diene unit in which an amount of 1,4-bonds is less than 30 mole percent and (2) a block b2 having a number average molecular weight of 10,000 to 400,000 and having a conjugated diene unit in which an amount of 1,4-bonds is 30 mole percent or more,
wherein the α-methylstyrene block copolymer has an (A-b1-b2) structure, and
wherein the thermoplastic polymer composition has a wear resistance of 3.0 to 8.4 mm 3 (23° C.) and 3.8 to 10.2 mm 3 (80° C.).
2. The thermoplastic polymer composition according to claim 1 , wherein the ethylene polymer (c) is produced in the presence of a metallocene catalyst.
3. The thermoplastic polymer composition according to claim 1 , wherein the ethylene polymer (c) is produced in the presence of a metallocene catalyst.
4. The thermoplastic polymer composition according to claim 1 , wherein the polymer block A consists of α-methylstyrene.
5. The thermoplastic polymer composition according to claim 1 , wherein the polymer block A further comprises at least one unsaturated monomer unit selected from the group consisting of butadiene, isoprene, 2,3-dimethyl-1,3-butadiene, 1,3-pentadiene, 1,3-hexadiene, isobutylene, styrene, o-methylstyrene, m-methylstyrene, p-methylstyrene, p-t-butylstyrene, 2,4-dimethylstyrene, vinylnaphthalene, vinylanthracene, methyl methacrylate, methyl vinyl ether, N-vinylcarbazole, β-pinene, 8,9-p-menthene, dipentene, methylene norbornene, and 2-methylene tetrahydrofuran.
6. The thermoplastic polymer composition according to claim 1 , wherein the polymer block A has a number average molecular weight before hydrogenation of 2,000 to 40,000.
7. The thermoplastic polymer composition according to claim 1 , wherein the polymer block B consists of structural units derived from a conjugated diene.
8. The thermoplastic polymer composition according to claim 1 , wherein the polymer block B comprises at least one conjugated diene unit selected from the group consisting of butadiene, isoprene, 2,3-dimethyl-1,3-butadiene, 1,3-pentadiene, and 1,3-hexadiene.
9. The thermoplastic polymer composition according to claim 1 , wherein the polymer block B further comprises an anionic polymerizable monomer unit.
10. The thermoplastic polymer composition according to claim 9 , wherein the anionic polymerizable monomer unit is at least one selected from the group consisting of styrene, o-methylstyrene, m-methylstyrene, p-methylstyrene, p-t-butylstyrene, 2,4-dimethylstyrene, vinylnaphthalene, vinylanthracene, methyl methacrylate, methyl vinyl ether, N-vinylcarbazole, β-pinene, 8,9-p-menthene, dipentene, methylene norbornene, and 2-methylene tetrahydrofuran.
11. The thermoplastic polymer composition according to claim 1 , wherein the polymer block A and the polymer block B are linearly linked.
12. The thermoplastic polymer composition according to claim 1 , wherein the block copolymer (a) further comprises at least one functional group selected from the group consisting of carboxyl, hydroxyl, acid anhydride, amino, and epoxy.
13. The thermoplastic polymer composition according to claim 1 , wherein the propylene polymer (b) is at least one selected from the group consisting of homo-polypropylene, random polypropylene, block polypropylene, atactic polypropylene, and syndiotactic polypropylene.
14. The thermoplastic polymer composition according to claim 1 , wherein the ethylene polymer (c) is at least one selected from the group consisting of ethylene homopolymer, ethylene/α-olefin copolymer, ethylene/vinyl acetate copolymer, ethylene/acrylic acid copolymer, and ethylene/methacrylic acid copolymer.
15. The thermoplastic polymer composition according to claim 14 , wherein the ethylene/α-olefin copolymer is at least one selected from the group consisting of ethylene/1-butene copolymer, ethylene/1-hexene copolymer, ethylene/1-heptene copolymer, ethylene/1-octane copolymer, ethylene/4-methyl-1-pentene copolymer, ethylene/1-nonene copolymer, and ethylene/1-decene copolymer.
16. The thermoplastic polymer composition according to claim 1 , wherein the inequality (1) is within the range of 0.2 to 0.7.
17. The thermoplastic polymer composition according to claim 1 , wherein the inequality (2) is within the range of 2 to 7.
18. An injection molded article formed of a thermoplastic polymer composition comprising:
at least one block copolymer (a) which is a hydrogenated product of an α-methylstyrene block copolymer having a number average molecular weight of 30,000 to 500,000, wherein the α-methylstyrene block copolymer comprises a polymer block A comprising an α-methylstyrene unit and a polymer block B comprising a conjugated diene unit;
a propylene polymer (b); and
an ethylene polymer (c) having a density of 0.94 g/cm 3 or less, in a ratio satisfying the inequalities (1) and (2):
0.1 ≦W ( a )/[ W ( a )+ W ( b )+ W ( c )]≦0.8 (1)
1 ≦W ( b )/ W ( c ) (2)
wherein W(a), W(b), and W(c) represent masses of the block copolymer (a), the propylene polymer (b), and the ethylene polymer (c), respectively,
wherein polymer block A has a number average molecular weight of 1,000 to 50,000,
wherein the polymer block B comprises (1) a block b1 having a number average molecular weight of 1,000 to 30,000 and having a conjugated diene unit in which an amount of 1,4-bonds is less than 30 mole percent and (2) a block b2 having a number average molecular weight of 10,000 to 400,000 and having a conjugated diene unit in which an amount of 1,4-bonds is 30 mole percent or more,
wherein the α-methylstyrene block copolymer has an (A-b1-b2) structure, and
wherein the thermoplastic polymer composition has a wear resistance of 3.0 to 8.4 mm 3 (23° C.) and 3.8 to 10.2 mm 3 (80° C.).