Process for producing a polymeric film with a cured polysiloxane coating
Process for producing a polymeric film which is furnished on one side with a cured polysiloxane coating and has an overall thickness of ≦45 μm by furnishing both sides of a collapsed tubular film with a cured polysiloxane coating.
1. A process for producing a single- or multilayer plastics film provided with a thermally cured polysiloxane coating on one of its surfaces, according to which a tubular, single- or multilayer plastic film is first flattened and then
(a) is coated on one side with at least one polysiloxane that has not yet been cured,
(b) this polysiloxane coating is cured by exposure to heat under drying,
(c) the second side of the flattened tubular, plastics film is coated with at least one polysiloxane that has not yet been cured,
(d) this polysiloxane coating is cured by exposure to heat under drying, and
(e) at least along one lateral edge the flattened, tubular plastics film which has been provided with a cured polysiloxane coating on each side, is opened and the resulting one or two flat films with cured polysiloxane coatings on one surface is/are stored in the form of a roll.
2. The process of claim 1 , wherein before carrying out step (c) the film is turned about 180°.
3. The process of claim 1 wherein the process is continuous.
4. The process of claim 1 , wherein the tubular plastics film is based on a thermoplastic polymer.
5. The process of claim 4 , wherein the tubular plastics film is based on at least one biodegradable thermoplastic polymer.
6. The process of claim 5 , wherein the thermoplastic, biodegradable polymers used comprised at least one biodegradable polymer selected from the group consisting of lactic acid homo/copolymers, cellulose, cellulose derivatives, thermoplastic starch, polyesters, at least partially hydrolyzed polyvinyl acetates, ethylene-vinyl alcohol copolymers and mixtures of at least two of said polymers.
7. The process of claim 6 , wherein the thermoplastic, biodegradable polymer used comprised at least one polylactide.
8. The process of claim 4 , wherein the tubular plastics film is based on at least one thermoplastic polymer selected from the group consisting of olefin homo- or copolymers, homo- or copolyamides, and biodegradable natural, semisynthetic, or synthetic polymers.
9. The process of claim 8 , wherein the thermoplastic olefin homo- or copolymers used comprised at least one thermoplastic olefin homo- or copolymer of α,β-unsaturated olefins having from 2 to 10 carbon atoms.
10. The process of claim 8 , wherein the thermoplastic homo- or copolyamides used comprise at least one homo- or copolyamide selected from the group consisting of thermoplastic, aliphatic, semiaromatic, or aromatic homo-and copolyamides.
11. The process of claim 1 , wherein the tubular plastics film has one layer.
12. The process of claim 11 , wherein the tubular plastics film is composed of LDPE or HDPE.
13. The process of claim 1 , wherein the tubular plastics film has a multilayer structure.
14. The process of claim 13 , wherein the multilayer structure has an internal copolyamide layer with a layer made of a propylene copolymer on each of its surfaces.
15. The process of claim 1 , wherein the thickness of each cured polysiloxane coating is ≦2 μm.
16. The process of claim 1 , wherein the flat laid, tubular plastics film is embossed before polysiloxane coating.
17. The process of claim 1 , wherein before carrying out step (c) the film is rolled up and, after intermediate storage, is unrolled for carrying out step (c).