Electroactive polymers containing pendant pi-interacting/binding substituents, their carbon nanotube composites, and processes to form the same
A composition of matter comprises a polymer with a fully conjugated backbone or a conjugated block with a plurality of binding groups connected to the backbone by a linking moiety. The binding groups permit a non-covalent binding to a graphitic surface such as a carbon nanotube. A composition of matter where an electroactive polymer with binding groups connected to a conjugated backbone through a linking moiety is bound to carbon nanotubes. Such compositions can be used for a variety of applications using electroactive materials.
1. A composition of matter, comprising:
an electroactive polymer having a backbone including at least one conjugated block;
a plurality of pendant binding groups comprising at least one polycyclic aromatic group selected from the group consisting of anthracene, pentacene, ovalene, perylene, pentaphene, corannulene, tetracene, benzo[rst]pentaphene, benzo[pqr]tetraphene, dibenzo[c,pqr]tetraphene, dibenzo[f,pqr]tetraphene, naphtho[1,2,3,4-pqr]tetraphene, naphtho[2,1,8-qra]tetracene, benzo[k]tetraphene, tribenzo[c,f,pqr]tetraphene, benzo[g]chrysene, dibenzo[h,rst]pentaphene, benzo[c]chrysene, tetraphene, chrysene, benzo[c]phenanthrene, dibenzo[a,j]anthracene, benzo[f]tetraphene, benzo[e]pyrene, phenanthrene, triphenylene, benzo[a]tetracene, dibenzo[c,g]phenanthrene, picene, dibenzo[f,k]tetraphene, dibenzo[fg,op]tetracene, benzo[c]pentaphene, benzo[a]pentacene, naphtho[7,8,1,2,3-nopqr]tetraphene, pyrene, benzo[ghi]perylene, coronene, or any combination thereof, wherein said pendant binding groups are capable of binding non-covalently to a carbon nanotube or a graphite-like structure; and
a non-conjugated linking moiety consisting of a C 1 -C 12 alkylene chain uninterrupted or interrupted by one or more oxygen atoms connecting said pendant binding group to said backbone.
2. The composition of claim 1 , wherein said polycyclic aromatic group contains at least one heteroatom selected from the group consisting of O, S, N, P, B and Si.
3. The composition of claim 1 , wherein said polymer backbone is fully conjugated.
4. The composition of claim 1 , wherein said backbone includes aromatic units.
5. The composition of claim 1 , wherein said conjugated block of said polymer backbone comprises polythiophene, polypyrrole, polydioxythiophene, polydioxypyrrole, polyfluorene, polycarbazole, polyfuran, polydioxyfuran, polyacetylene, poly(phenylene), poly(phenylene-vinylene), polyaniline, polypyridine, substituted variations thereof, or copolymers thereof.
6. The composition of claim 1 , wherein said polymer is an electrically conductive polymer.
7. The composition of claim 1 , wherein said polymer is a block copolymer.
8. The composition of claim 1 , wherein said polymer comprises poly(3,4-alkylenedioxythiophene).
9. The composition of claim 1 , further comprising a plurality of carbon nanotubes, wherein at least one of said pendant binding groups is non-covalently bound to a surface of said carbon nanotubes.
10. The composition of claim 9 , wherein said nanotubes are bound exclusively to said electroactive polymer by non-covalent bonds to said pendant groups.
11. The composition of claim 9 , wherein said nanotubes are bound to said electroactive polymer by non-covalent bonds to said pendant groups and to said conjugated blocks.
12. The composition of claim 9 , wherein nanotubes are uniformly coated by said composition of matter recited in claim 1 .
13. A method to prepare electroactive polymer coated nanotubes comprising the steps of:
providing a solution of the electroactive polymer according to claim 1 ;
dispersing a plurality of carbon nanotubes in said solution of said electroactive polymer; and
filtering said dispersion wherein a filtrate of electroactive polymer coated nanotubes is supported on a filter.
14. The method of claim 13 , further comprising the step of washing said filtrate with a solvent.
15. A method to prepare an electroactive polymer coated nanotubes film comprising the steps of:
providing a film comprising a plurality of carbon nanotubes on a substrate; and
wetting said film with a solution of the electroactive polymer according to claim 1 .
16. The method of claim 15 , further comprising the step of washing said wetted film on said support to remove excess of said electroactive polymer.
17. The method of claim 15 , further comprising the step of drying said wetted film.
18. The composition of claim 1 , wherein said polycyclic aromatic group is selected from the group consisting of pentacene, ovalene, perylene, pentaphene, corannulene, tetracene, benzo[rst]pentaphene, benzo[pqr]tetraphene, dibenzo[c,pqr]tetraphene, dibenzo[f,pqr]tetraphene, naphtho[1,2,3,4-pqr]tetraphene, naphtho[2,1,8-qra]tetracene, benzo[k]tetraphene, tribenzo[c,f,pqr]tetraphene, benzo[g]chrysene, dibenzo[h,rst]pentaphene, benzo[c]chrysene, tetraphene, chrysene, benzo[c]phenanthrene, dibenzo[a,j]anthracene, benzo[f]tetraphene, benzo[e]pyrene, triphenylene, benzo[a]tetracene, dibenzo[c,g]phenanthrene, picene, dibenzo[f,k]tetraphene, dibenzo[fg,op]tetracene, benzo[c]pentaphene, benzo[a]pentacene, naphtho[7,8,1,2,3-nopqr]tetraphene, pyrene, benzo[ghi]perylene, coronene, or any combination thereof.