Copolymer, rubber composition, crosslinked rubber composition and tire
The present invention provides a random copolymer that is used for manufacturing a tire having excellent rollability and wear resistance and that includes randomly arranged monomer units of a conjugated diene compound and of a non-conjugated olefin, a rubber composition containing the random copolymer, a cross-linked rubber composition obtained by crosslinking the rubber composition, and a tire manufactured by using the rubber composition or the cross-linked rubber composition. A copolymer of a conjugated diene compound and a non-conjugated olefin, including a random copolymer having randomly arranged monomer units of the conjugated diene compound and of the non-conjugated olefin, and containing, by more than 30 mol %, a unit derived from the conjugated diene compound.
1. A copolymer of a conjugated diene compound and a non-conjugated olefin, comprising a random copolymer having randomly arranged monomer units of the conjugated diene compound and of the non-conjugated olefin, and containing, by 81 mol % to 97 mol %, a unit derived from the conjugated diene compound,
wherein the copolymer contains, by at least 5 mol %, alternate bonding units of the conjugated diene compound and the non-conjugated olefin in a unit derived from the non-conjugated olefin.
2. The copolymer according to claim 1 , wherein the content of 1,2 adduct units (including 3,4 adduct units) of the conjugated diene compound in the unit derived from the conjugated diene compound is 5% or less.
3. The copolymer according to claim 1 , comprising a copolymer having a polystyrene-equivalent average-weight molecular weight of 10,000 to 10,000,000.
4. The copolymer according to claim 1 , comprising a copolymer having a molecular weight distribution (Mw/Mn) of 10 or less.
5. The copolymer according to claim 1 , wherein the non-conjugated olefin is an acyclic olefin.
6. The copolymer according to claim 1 , wherein the non-conjugated olefin has 2 to 10 carbon atoms.
7. The copolymer according to claim 5 , wherein the non-conjugated olefin is at least one selected from the group consisting of ethylene, propylene, and 1-butene.
8. The copolymer according to claim 7 , wherein the non-conjugated olefin is ethylene.
9. The copolymer according to claim 1 , wherein the conjugated diene compound is at least one selected from the group consisting of 1,3-butadiene and isoprene.
10. A rubber composition comprising the copolymer according to claim 1 .
11. The rubber composition according to claim 10 , comprising, with respect to 100 parts by mass of the rubber component, a reinforcing filler by 5 parts by mass to 200 parts by mass and a crosslinking agent by 0.1 parts by mass to 20 parts by mass.
12. A crosslinked rubber composition obtained by crosslinking the rubber composition according to claim 10 .
13. A tire manufactured by using the rubber composition according to claim 10 .