Rechargeable lithium battery
In one aspect, a rechargeable lithium battery including a positive electrode having a positive active material, a negative electrode having a negative active material, and an electrolyte is provided. The positive active material can include manganese-based oxide, and the electrolyte can include fluoroethylene carbonate, lithium bis(oxalato)borate, and tris(trialkylsilyl)borate.
1. A rechargeable lithium battery comprising
a positive electrode including a positive active material, wherein the positive active material comprises Li a Mn b O 4 where 0.5≦a≦1.5, and 1≦b≦3;
a negative electrode including a negative active material; and
an electrolyte including an organic solvent, a lithium salt, and an additive, and
the additive comprises fluoroethylene carbonate in an amount of 1 to 20 parts by weight, lithium bis(oxalato)borate in an amount of 0.5 to 5 parts by weight, and a tris(trialkylsilyl)borate in an amount of 0.5 to 3 parts by weight based on 100 parts by weight of the non-aqueous organic solvent and the lithium salt, wherein the sum of the lithium bis(oxalato)borate and the tris(trialkylsilyl)borate by parts by weight is less than the amount of the fluoroethylene carbonate by weight, and wherein the tris(trialkylsilyl)borate is a compound represented by Chemical Formula 3:
wherein, R 1 to R 9 are each a substituted or unsubstituted C 1 to C 5 alkyl group.
2. The rechargeable lithium battery of claim 1 , wherein the positive active material further comprises nickel-based oxide.
3. The rechargeable lithium battery of claim 2 , wherein the nickel-based oxide comprises a compound represented by the following Chemical Formula 5, a compound represented by the following Chemical Formula 6, or a combination thereof,
Li e Ni d Co e Mn f O 2 [Chemical Formula 5]
wherein, 0.5≦c≦1.5, 0.1≦d≦0.6, 0.1≦e≦0.5, and 0.1≦f≦0.5
Li g Ni h Co i Al j O 2 [Chemical Formula 6]
wherein, 0.5≦g≦1.5, 0.7≦h≦0.9, 0.1≦i≦0.2, and 0.01≦j≦0.10.
4. The rechargeable lithium battery of claim 2 , wherein the positive active material comprises 70 to 90 wt % of the manganese-based oxide and 10 to 30 wt % of the nickel-based oxide.
5. The rechargeable lithium battery of claim 1 , wherein the organic solvent comprises a carbonate moiety, ester moiety, ether moiety, ketone moiety, or alcohol moiety.
6. The rechargeable lithium battery of claim 1 , wherein the organic solvent comprises an aprotic solvent.
7. The rechargeable lithium battery of claim 1 , wherein the lithium salt comprises at least one of LiPF 6 , LiBF 4 , LiSbF 6 , LiAsF 6 , LiC 4 F 9 SO 3 , LiClO 4 , LiAlO 2 , LiAlCl 4 , LiN(SO 2 C x F 2x+1 )(SO 2 C y F 2y+1 ) (where x and y are natural numbers), LiCl, LiI, or a combination thereof.
8. The rechargeable lithium battery of claim 7 , wherein the lithium salt is LiPF 6 .
9. The rechargeable lithium battery of claim 1 , wherein R 1 to R 9 is methyl.
10. The rechargeable lithium battery of claim 1 , wherein the compound represented by Chemical Formula 4 is LiMn 2 O 4 .
11. The rechargeable lithium battery of claim 3 , wherein the compound represented by Chemical Formula 5 is LiNi 0.5 Co 0.2 Mn 0.3 O 2 .
12. The rechargeable lithium battery of claim 1 , wherein the organic solvent comprises one or more components selected from the group consisting of ethylene carbonate (EC), ethylmethyl carbonate (EMC), and dimethyl carbonate (DMC).
13. The rechargeable lithium battery of claim 12 , wherein the lithium salt is LiPF 6 .
14. The rechargeable lithium battery of claim 13 , wherein the tris(trialkylsilyl)borate is tris(trimethylsilyl)borate.