Method of preparing an edge-strengthened article
A method of preparing an edge-strengthened article comprises polishing of an edge of an article having a first edge strength using magnetorheological finishing, wherein after the polishing the article has a second edge strength and the second edge strength is greater than the first edge strength.
1. A method of preparing an edge-strengthened article, comprising: polishing of an edge of a glass or glass ceramic article having a first edge strength using a magnetorheological fluid, wherein the magnetorheological fluid comprises an etching agent having a pH≦5 and after the polishing, the glass or glass ceramic article has a second edge strength and the second edge strength is greater than the first edge strength.
2. The method of claim 1 , wherein polishing the article comprises a plurality of magnetorheological finishing steps.
3. The method of claim 1 , further comprising providing the article prior to the polishing with an initial edge strength that is different from the first edge strength, and wherein a difference in the initial edge strength and the first edge strength is due at least in part to one of cutting the article, modifying a shape and/or texture of the edge of the article, and chemically-strengthening the article.
4. The method of claim 1 , further comprising cutting the article prior to the polishing.
5. The method of claim 1 , further comprising modifying a shape and/or texture of the edge of the article prior to the polishing.
6. The method of claim 1 , further comprising subjecting the article to an ion-exchange process prior to or after the polishing.
7. The method of claim 1 , wherein the polishing is preceded by cutting the edge of the article and modifying a shape and/or texture of the edge of the article after the cutting, the modifying comprising a plurality of process steps selected from mechanical grinding, and mechanical polishing.
8. The method of claim 1 , wherein polishing the edge of the article comprises applying a magnetic field to the magnetorheological polishing fluid to stiffen the magnetorheological polishing fluid, contacting the edge with the stiffened magnetorheological polishing fluid, and affecting a relative motion between the edge and the stiffened magnetorheological polishing fluid.
9. The method of claim 1 , wherein the etching agent comprises an acid.
10. The method of claim 1 , wherein the etching agent is selected from the group consisting of hydrofluoric acid and sulfuric acid.
11. The method of claim 1 , wherein the edge-strengthened article has an edge strength of from 600 MPa to 900 MPa.
12. The method of claim 1 , wherein the edge is polished for 1 to 5 minutes.
13. The method of claim 1 , wherein the edge-strengthened article has an edge strength greater than 1 GPa.
14. The method of claim 1 , wherein the magnetorheological fluid comprises magnetizable particles having a particle size of from 1 micron to 150 microns.
15. The method of claim 1 , wherein the glass or glass ceramic article comprises a glass sheet.
16. The method of claim 15 , wherein the glass sheet is cut via a mechanical or laser process prior to polishing.
17. The method of claim 15 , wherein, prior to polishing the glass sheet with a magnetorheological fluid, the glass sheet undergoes one or more of the following steps: lapping, mechanical polishing, or mechanical grinding.
18. A method of preparing an edge-strengthened article comprising contacting an edge of a glass or glass ceramic article with a magnetorheological fluid that comprises magnetizable particles, abrasive particles, and an etching agent having a pH≦5.