Method and apparatus for recovering rare metal
View Patent ↗Disclosed is a method and apparatus for recovering rare metal, which separates and collects rare metals by making use of chemical actions in an efficient combination of adsorption and separation, thereby reducing work load and improving work safety. The method for recycling rare metals includes a leaching step in which a rare metal of palladium, platinum, and rhodium is mixed with hydrochloric acid into a hydrochloric acid mixture, which is then stirred at one atmospheric pressure or lower at a temperature from 50 to 90 degrees Centigrade. The vapor resulting from the stirring is condensed, and the hydrochloric acid resulting from the condensing is fed back to the original hydrochloric acid mixture to produce a hydrochloric acid leaching solution. The hydrochloric acid leaching solution produced in the leaching step is used to collect the rare metals.
1. A rare metal recovery method, which comprises:
mixing, under a pressure of 1 atmosphere or less at a temperature of from 50° C. to 90° C., a hydrochloric acid mixture liquid obtained by mixing a waste material of rare metal comprising palladium, platinum and rhodium with hydrochloric acid to form hydrochloric acid vapor;
condensing the hydrochloric acid vapor obtained by said mixing to form hydrochloric acid liquid
flowing the hydrochloric acid liquid back to the hydrochloric acid mixture liquid to prepare a hydrochloric acid leaching liquid; and
recovering the rare metal from the hydrochloric acid leaching liquid.
2. The rare metal recovery method, as claimed in claim 1 , further comprising:
a palladium adsorption step of causing the hydrochloric acid leaching liquid to pass through a palladium adsorbent impregnated with adsorbent for adsorbing the palladium and causing the palladium to adsorb on the palladium adsorbent;
a platinum adsorption step of causing a residual liquid from said palladium adsorption step to pass through a platinum adsorbent impregnated with adsorbent for adsorbing the platinum and causing the platinum to adsorb on the platinum adsorbent; and
a rhodium adsorption step of causing a residual liquid from said platinum adsorption step to pass through a rhodium adsorbent impregnated with adsorbent for adsorbing the rhodium and causing the rhodium to adsorb on the rhodium adsorbent.
3. The rare metal recovery method, as claimed in claim 2 , further comprising:
a hydrochloric acid reuse step of condensing a residual liquid from said rhodium adsorption step; and flowing a hydrochloric acid solution obtained by said condensing back to said hydrochloric acid mixture liquid.
4. The rare metal recovery method, as claimed in claim 2 , further comprising:
a palladium elution step of causing a hydrochloric acid solution containing thiourea to pass through said palladium adsorbent and eluting the palladium to prepare a palladium elution liquid including the palladium;
a platinum elution step of causing a hydrochloric acid solution to pass through said platinum adsorbent and eluting the platinum to prepare a platinum elution liquid including the platinum; and
a rhodium elution step of causing a hydrochloric acid solution to pass through said rhodium adsorbent and eluting the rhodium to prepare a rhodium elution liquid including the rhodium.
5. The rare metal recovery method, as claimed in claim 4 , further comprising:
a palladium precipitation step of adding a sodium hydroxide solution to the palladium elution liquid obtained by said palladium elution step to precipitate a palladium oxide;
a platinum precipitation step of adding a saturated ammonium chloride solution to the platinum elution liquid obtained by said platinum elution step to precipitate a platinum oxide; and
a rhodium precipitation step of adding a nitrous acid solution to the rhodium elution liquid obtained by said rhodium elution step to precipitate a rhodium oxide.
6. The rare metal recovery method, as claimed in claim 2 , wherein said palladium adsorbent comprises a di-n-hexyl sulfide (DHS)-impregnated resin.
7. The rare metal recovery method, as claimed in claim 2 , wherein said platinum adsorbent and said rhodium adsorbent comprise an ion-exchange resin.