Thin microstructured optical films
Presently described are optical films, such as a brightness enhancing film, having a polymerized microstructured surface disposed on a preformed polymeric film wherein the film has a thickness of no greater than 3 mils and the polymerized microstructured surface consists of the reaction product of a substantially non-brominated polymerizable resin composition.
1. A brightness enhancing film having a polymerized microstructured surface comprising a plurality of prisms, disposed on a preformed polymeric polyethylene terephthalate film and the polymerized microstructured surface is a reaction product of a non-brominated polymerizable resin composition comprising
i) at least about 60 wt-% of one or more bisphenol di(meth)acrylate monomers selected from the group consisting of
and a mixture of
and
ii) about 5 wt-% to about 40 wt-% of one or more (meth)acrylate diluents having a viscosity of less than 300 cps at 25° C. selected from the group consisting of phenoxy ethyl acrylate, 2-phenyl-phenyl acrylate, tetraethylene glycol diacrylate and mixtures thereof; wherein the non-brominated polymerizable composition comprises 0 to 15 wt-% of components comprising three or more (meth)acrylate groups; wherein the preformed polymeric polyethylene terephthalate film has a thickness of less than or equal to about 2 mils and the brightness enhancing film exhibits curl from 0 mm to less than 2 mm.
2. The brightness enhancing film of claim 1 wherein the non-brominated polymerizable resin comprises at least about 65 wt-% of one or more bisphenol di(meth)acrylate monomers.
3. The brightness enhancing film of claim 1 wherein the non-brominated polymerizable resin comprises at least about 70 wt-% of one or more bisphenol di(meth)acrylate monomers.
4. The brightness enhancing film of claim 1 wherein the one or more bisphenol di(meth)acrylate monomers have a molecular weight of greater than 450 g/mole.
5. The brightness enhancing film of claim 1 wherein the one or more (meth)acrylate diluents have a viscosity of less than 100 cps at 25° C.
6. The brightness enhancing film of claim 1 wherein the non-brominated polymerizable resin composition is free of components having three or more (meth)acrylate groups.
7. The brightness enhancing film of claim 1 wherein the preformed polymeric film has a thickness of less than or equal to about 1.5 mils.
8. The brightness enhancing film of claim 1 wherein the preformed polymeric film has a thickness of less than or equal to about 1 mil.
9. The brightness enhancing film of claim 1 wherein the non-brominated polymerizable resin composition is non-halogenated.
10. The brightness enhancing film of any of claim 1 wherein the polymerized microstructured surface is a prismatic structure having a distance between prism peaks of between 10 and 35 microns, and a prism height of between 5 and 18 microns.
11. An optical film having a polymerized microstructured surface, disposed on a preformed polymeric polyethylene terephthalate film and the polymerized microstructured surface is a reaction product of a non-brominated polymerizable resin composition comprising
i) at least about 60 wt-% of one or more bisphenol di(meth)acrylate monomers selected from the group consisting of
and a mixture of
and
ii) about 5 wt-% to about 40 wt-% of one or more (meth)acrylate diluents comprising having a viscosity of less than 300 cps at 25° C. selected from the group consisting of phenoxy ethyl acrylate, 2-phenyl-phenyl acrylate, tetraethylene glycol diacrylate and mixtures thereof; wherein the non-brominated polymerizable composition comprises 0 to 15 wt-% of components comprising three or more (meth)acrylate groups;
wherein the preformed polymeric polyethylene terephthalate film has a thickness of less than or equal to about 2.0 mil and the optical film exhibits curl from 0 mm to less than 2 mm.