Dehydrogenation catalyst
This invention relates to a dehydrogenation catalyst having a macropore size and a high active density of platinum, suitable for use in dehydrogenation of a hydrocarbon gas. This dehydrogenation catalyst having a macropore size and a high active density of platinum is highly active, has high active density per unit catalytic surface area, facilitates material transfer of reactants and products, delays deactivation due to coke formation, keeps the initial activity constant after being regenerated thanks to the disposal of coke, has high strength and so is resistant to external impact, and undergoes neither structural changes due to heat nor changes in the properties of active materials.
1. A dehydrogenation catalyst for use in dehydrogenation of a hydrocarbon gas, comprising
platinum,
an assistant metal,
an alkali metal or alkaline earth metal,
and a halogen component, which are supported on a carrier,
wherein
the carrier is alumina having a theta cryslallinity of 90% or more, and having mesopores of 5˜100 nm and macropores of 0.1˜20 μm, and having mesoporc volume of 0.32 -0.47 cc/g and macropore volume of 0.23-0.25 cc/g, and
the platinum has an active density of 0.001-0.009 wt %/m 2 and a strength of 15-70 N.
2. The dehydrogenation catalyst of claim 1 , wherein the catalyst is capable of dehydrogenating a hydrocarbon is a C 2 -C 5 linear hydrocarbon or ethylbenzene.
3. The dehydrogenation catalyst of claim 1 , comprising 0.05˜1.5 wt % of platinum, 0.05˜2.0 wt % of the assistant metal, 0.05˜3.0 wt % of the alkali metal or alkaline earth metal, and 0.1˜3.0 wt % of the halogen component, based on total weight of the catalyst, which are supported on the carrier.
4. The dehydrogenation catalyst of claim 1 , wherein the assistant metal is one or more selected from the group consisting of tin, germanium, gallium, indium, zinc, and manganese.
5. The dehydrogenation catalyst of claim 1 , wherein the alkali metal or alkaline earth metal is one or more selected from the group consisting of calcium, potassium, sodium, magnesium, lithium, strontium, barium, radium, and beryllium.
6. The dehydrogenation catalyst of claim 1 , wherein the halogen component is one or more selected from the group consisting of chlorine, and fluorine.
7. The dehydrogenation catalyst of claim 1 , wherein the carrier has a specific surface area of 50˜170 m 2 /g.
8. The dehydrogenation catalyst of claim 1 , wherein the catalyst has a bulk density of 0.5-0.8 g/cc.