Combined heavy reformate dealkylation-transalkylation process for maximizing xylenes production
A method of forming mixed xylenes from a heavy reformate using a dealkylation-transalkylation system includes the step of introducing both a heavy reformate containing methyl ethyl benzenes and tri-methyl benzenes and that is sufficiently free of toluene and a hydrogen-containing material into the dealkylation stage such that the heavy reformate and the hydrogen-containing material intermingle and contact the hydrodealkylation catalyst. The dealkylation-transalkylation system includes dealkylation, non-aromatic product gas separations and transalkylation stages. Toluene forms from the reaction of methyl ethyl benzenes and hydrogen in the presence of the hydrodealkylation catalyst. The method also includes the step of introducing a dealkylated heavy reformate into the transalkylation stage such that the dealkylated heavy reformate contacts a transalkylation catalyst, forming a transalkylation stage product mixture includes mixed xylenes.
1. A method of forming mixed xylenes from a heavy reformate using a dealkylation-transalkylation system, the method comprising the steps of:
introducing both the heavy reformate and a hydrogen-containing material into a dealkylation stage of the dealkylation-transalkylation system such that the heavy reformate and the hydrogen-containing material intermingle and contact a hydrodealkylation catalyst, where the dealkylation stage contains the hydrodealkylation catalyst, where the heavy reformate comprises a significant amount of both methyl ethyl benzenes and tri-methyl benzenes and is substantially free of toluene by weight, and where the hydrogen-containing material comprises hydrogen;
operating the dealkylation stage such that toluene forms from the reaction methyl ethyl benzenes and hydrogen in the presence of the hydrodealkylation catalyst and such that a dealkylation stage product is produced, where the dealkylation stage product comprises toluene, tri-methyl benzenes and non-aromatic product gas;
operating the non-aromatic product gas separations stage such that the non-aromatic product gas and a dealkylation heavy reformate are produced separately and the non-aromatic product gas from the dealkylation stage product is removed before it is introduced into the vessel where transalkylation occurs, where the dealkylation heavy reformate comprises toluene and tri-methyl benzenes;
introducing the dealkylated heavy reformate into the transalkylation stage such that the dealkylated heavy reformate contacts a transalkylation catalyst, where the transalkylation stage contains the transalkylation catalyst; and
operating the transalkylation stage such that mixed xylenes form from reaction of tri-methyl benzenes and toluene in the presence of the transalkylation catalyst and such that a transalkylation stage product is produced, where the transalkylation stage product mixture comprises xylenes.
2. The method of claim 1 where methyl ethyl benzenes comprise at least about 30 percent by weight of the introduced heavy reformate.
3. The method of claim 1 where a weight ratio value of methyl ethyl benzenes to tri-methyl benzenes in the introduced heavy reformate is in a range of from about 0.1 to about 3.
4. The method of claim 1 where the introduced heavy reformate comprises less than a detectable amount of toluene by weight.
5. The method of claim 1 where a feed ratio of hydrogen-containing material to heavy reformate is in a range of from about 1 to about 4.
6. The method of claim 1 where the selective separation non-aromatic product gases by a non-aromatic gas separator and the dealkylation of the heavy reformate occurs in a dealkylation reactor.
7. The method of claim 1 where the transalkylation stage operates at a temperature range of from about 200° C. to about 540° C., a pressure range of from about 10 bars to about 50 bars and a liquid hourly space velocity range of from about 1 hr −1 to about 5 hr −1 .
8. The method of claim 1 further comprising the stop of operating the dealkylation-transalkylation system such that benzene, toluene and mixed xylenes are selectively separated from the produced transalkylation stage product.
9. The method of claim 8 further comprising the step of recycling at least a portion of the selectively separated benzenes into the transalkylation stage.
10. The method of claim 8 further comprising the step of recycling at least a portion of the selectively separated toluene into the transalkylation stage.
11. The method of claim 8 further comprising the step of recycling at least a portion of the selectively separated mixed xylenes into the transalkylation stage.
12. The method of claim 8 further comprising the step of operating The dealkylation-transalkylation system such that ortho-xylene, para-xylene and meta-xylene are selectively separated from the mixed xylenes.
13. The method of claim 12 further comprising the step of recycling at least a portion of the selectively separated meta-xylene into the transalkylation stage.