Process for continuous recovering (meth) acrylic acid and apparatus for the process
The present invention relates to a method and apparatus for continuous recovery of (meth)acrylic acid, and more specifically to a method of continuous recovery of (meth)acrylic acid, including: conducting gas phase oxidation of at least one compound selected from the group consisting of propane, propylene, butane, i-butylene, t-butylene, and (meth)acrolein in the presence of a catalyst to obtain a mixed gas containing (meth)acrylic acid; quenching the (meth)acrylic acid-containing mixed gas to remove high boiling point by-products in the (meth)acrylic acid-containing mixed gas; contacting the high boiling point by-product-free (meth)acrylic acid-containing mixed gas with water or an aqueous solution to obtain an aqueous solution containing (meth)acrylic acid; and purifying the aqueous solution containing (meth)acrylic acid to obtain (meth)acrylic acid. The continuous recovery method of (meth)acrylic acid according to the present invention may significantly reduce energy consumption and continuously recover high purity (meth)acrylic acid with excellent production efficiency compared to the previous recovery methods.
1. An apparatus for continuous recovery of (meth)acrylic acid, comprising:
a gas phase oxidation reactor for conducting gas phase oxidation of at least one compound selected from the group consisting of propane, propylene, butane, i-butylene, t-butylene, and (meth)acrolein in the presence of a catalyst to prepare a mixed gas containing (meth)acrylic acid;
a quench tower for quenching the (meth)acrylic acid-containing mixed gas supplied from the gas phase oxidation reactor to remove high boiling point by-products in the (meth)acrylic acid-containing mixed gas;
a (meth)acrylic acid absorption tower for contacting the high boiling point by-product-free (meth)acrylic acid-containing mixed gas with water or an aqueous solution to obtain an aqueous solution containing (meth)acrylic acid; and
a distillation tower for purifying the (meth)acrylic-containing aqueous solution supplied from the (meth)acrylic acid absorption tower to obtain (meth)acrylic acid.
2. The apparatus for continuous recovery of (meth)acrylic acid according to claim 1 , wherein the quench tower is connected to and integrated with the bottom of the (meth)acrylic acid absorption tower.
3. The apparatus for continuous recovery of (meth)acrylic acid according to claim 1 , wherein the distillation tower recycles the aqueous solution remaining after obtaining the (meth)acrylic acid to the (meth)acrylic acid absorption tower, and the recycled aqueous solution contacts the high boiling point by-product-free (meth)acrylic acid-containing mixed gas.
4. The apparatus for continuous recovery of (meth)acrylic acid according to claim 1 , wherein 5 to 80 wt % of the (meth)acrylic acid-containing aqueous solution discharged to the (meth)acrylic acid absorption tower is supplied to the quench tower, and the remainder is supplied in the distillation tower,
the (meth)acrylic acid-containing mixed gas supplied to the quench tower is quenched by the (meth)acrylic acid-containing aqueous solution.
5. The apparatus for continuous recovery of (meth)acrylic acid according to claim 1 , wherein the quenching the (meth)acrylic acid-containing mixed gas is conducted in the quench tower at a pressure of 1 to 1.5 bar and an upper temperature of 70 to 150° C.,
the high boiling point by-products are discharged to the bottom of the quench tower, and the high boiling point by-product-free (meth)acrylic acid-containing mixed gas is discharged to the top of the quench tower.
6. The apparatus for continuous recovery of (meth)acrylic acid according to claim 1 , wherein the contacting the high boiling point by-product-free (meth)acrylic acid-containing mixed gas is conducted in the absorption tower at a pressure of 1 to 1.5 bar and an upper temperature of 50 to 70° C.,
the (meth)acrylic acid-containing aqueous solution is discharged to the bottom of the (meth)acrylic acid absorption tower, and a (meth)acrylic acid-stripped non-condensable gas is discharged to the top of the (meth)acrylic acid absorption tower.
7. The apparatus for continuous recovery of (meth)acrylic acid according to claim 1 , wherein the purifying the (meth)acrylic acid-containing aqueous solution is conducted in the distillation tower supplied with a hydrophobic azeotropic solvent,
discharged liquid including (meth)acrylic acid is recovered from the bottom of the distillation tower, and A discharged liquid including the azeotropic solvent, water, and acetic acid is recovered from the top of the distillation tower.