Reactive ionic liquids
The invention relates to reactive ionic liquids containing organic cations with groups or substituents which are susceptible to electrochemical reduction and anions obtained from fluoroalkyl phosphates, fluoroalkyl phosphinates, fluoroalkyl phosphonates, acetates, triflates, imides, methides, borates, phosphates and/or aluminates, for use in electrochemical cells, such as lithium ion batteries and double-layer capacitors.
1. Ionic liquids of the general formula I
K + A − (I)
in which:
K + denotes at least one cation selected from the group consisting of the general formula IV
where
X denotes CH 2 ;
R 5 denotes —(CH 2 ) n —O—C(O)—R— where n=2; and
R denotes CH 3 ;
and
A − denotes at least one anion selected from the group consisting of
[F y P(C m F 2m+1 ) 6−y ] − ;
(C m F 2m+1 ) 2 P(O)O − ;
(C m F 2m+1 )P(O)O 2 2− ;
O—C(O)—C m F 2m+1 ;
O—S(O) 2 —C m F 2m+1 ;
N(C(O)—C m F 2m+1 ) 2 ;
N(S(O) 2 —C m F 2m+1 ) 2 ;
N(C(O)—C m F 2m+1 )(S(O) 2 —C m F 2m+1 );
N(C(O)—C m F 2m+1 )(C(O)F);
N(S(O) 2 —C m F 2m+1 )(S(O) 2 F);
N(S(O) 2 F) 2 ;
C(C(O)—C m F 2m+1 ) 3 ;
C(S(O) 2 —C m F 2m+1 ) 3 ;
where y=1, 2, 3, 4 or 5 and m=1 to 8, where some of the CF 2 groups may be replaced by O, S(O) 2 , NR or CH 2 , and where
denotes a 1,2- or 1,3-diol, a 1,2- or 1,3-dicarboxylic acid or a 1,2- or 1,3-hydroxycarboxylic acid;
Y denotes B or Al;
R 1 to R 4 denote halogen, and/or a fluorinated or non-fluorinated alkoxy or carboxyl radical.
2. Electrolyte comprising at least one conductive salt, an aprotic solvent or solvent mixture, at least one ionic liquid according to claim 1 and optionally further additives.
3. Electrolyte according to claim 2 , characterized in that the conductive salt is a lithium conductive salt.
4. Electrolyte according to claim 2 , characterized in that the conductive salt is at least one conductive salt selected from the following compounds: N(C 2 H 5 ) 4 BF 4 , N(C 2 H 5 ) 4 PF 6 , N(C 2 H 5 ) 3 (CH 3 )BF 4 , N(C 2 H 5 ) 3 (CH 3 )PF 6 , N(C 2 H 5 ) 4 N(SO 2 CF 3 ) 2 , N(C 2 H 5 ) 3 (CH 3 )N(SO 2 CF 3 ) 2 , N(C 2 H 5 ) 4 F 3 P(C 2 F 5 ) 3 , N(C 2 H 5 ) 3 (CH 3 )F 3 P(C 2 F 5 ) 3 .
5. Electrolyte according to claim 2 , characterized in that the aprotic solvent consists of organic open-chain or cyclic carbonates, carboxylic acid esters, nitrites, ethers, lactones or a mixture thereof.
6. Process for the preparation of ionic liquids of the formula I according to claim 1 , comprising:
preparing heterocyclic cations K + having alkyl-, carboxylate-, carbonate- or cyano-containing side chains according to claim 1 as onium chlorides or bromides from the corresponding amines, phosphines, halocarboxylates, halocarbonates, haloalkyl nitriles or alkyl halides by conventional wet-chemical methods
reacting said cationic onium chlorides or bromides with at least one anion selected from the group consisting of the corresponding anionic potassium, sodium fluoroalkylphosphates, potassium, sodium bis(fluoroalkyl)phosphinates, potassium, sodium fluoroalkylphosphonates, fluoroalkylphosphoric acids, bis(fluoroalkyl)phosphinic acids, fluoroalkylphosphonic acids, alkyl, or
with at least one compound selected from the group consisting of lithium imides or methides, trifluoromethanesulfonic acid or potassium or lithium trifluoroacetates or triflates or alkyl triflates or trimethylsilyl triflates, trifluoromethanesulfonic anhydride or trifluoroacetic anhydride or
with at least one compound selected from the group consisting of lithium or potassium borates, phosphates or aluminates in aqueous and/or alcoholic medium or an organic solvent or without a solvent.
7. Electrochemical and/or electro-optical device containing at least one electrolyte which comprises at least one ionic liquid of the general formula I according to claim 1 .
8. Electrochemical and/or electro-optical device according to claim 7 , characterized in that said device is at least one device selected from the group consisting of solar cell, lithium ion battery, lithium battery, double-layer capacitor or supercapacitor, lithium capacitor, light-emitting device, electrochemical sensor and/or biosensor.
9. An electrochemical or electro-optical cells, comprising an ionic liquid according to claim 1 .
10. A battery, comprising an ionic liquid according to claim 1 .
11. A secondary lithium battery, comprising an ionic liquid according to claim 1 .
12. A double-layer capacitor or supercapacitor or lithium capacitors comprising an ionic liquid according to claim 1 .
13. A lithium or lithium ion battery, comprising an ionic liquid according to claim 1 .
14. The ionic liquids according to claim 1 , wherein m is 1 to 4.
15. The ionic liquids according to claim 1 , wherein A − denotes at least one anion selected from the group consisting of
wherein R 1 to R 4 denote a halogen which is F.
16. The electrolyte according to claim 3 wherein said lithium conductive salt is at least one conductive salt selected from the group consisting of LiPF 6 , LiN(SO 2 CF 3 ) 2 , LiN(SO 2 C 2 F 5 ) 2 , LiF 3 P(C 2 F 5 ) 3 , LiF 3 P(C 4 F 9 ) 3 , LiB(C 2 O 4 ) 2 and LiF 2 B(C 2 O4) 2 .
17. The ionic liquid according to claim 1 , wherein A − is bisoxalatoborate.