Lubricant composition using ionic liquid as a base oil and having excellent rust prevention properties
The invention provides a lubricant composition containing (A) an ionic liquid having an anion represented by formula 1: (Rf1-SO 2 ) (Rf2-SO 2 ) N − or formula 2: (Rf3) (Rf3) (Rf3) PF 3 − wherein Rf1 and Rf2 in formula 1 may be the same or different and are each F, CF 3 , C 2 F 5 , C 3 F 7 or C 4 F 9 , and Rf3 in formula 2 may be the same or different and is CF 3 , C 2 F 5 , C 3 F 7 or C 4 F 9 ; and (B) a fatty acid amine salt in an amount of 0.1 to 5.0 mass %. The lubricant composition of the invention can favorably be used under a high vacuum or an ultra high vacuum, or under high temperatures, and exhibits excellent rust prevention properties.
1. A lubricant composition comprising;
(A) an ionic liquid having an anion represented by formula 1 or formula 2:
(Rf1-SO 2 ) (Rf2-SO 2 ) N − (formula 1)
(Rf3) (Rf3) (Rf3) PF 3 − (formula 2)
wherein Rf1 and Rf2 in formula 1 may be the same or different and are each F, CF 3 , C 2 F 5 , C 3 F 7 or C 4 F 9 , and Rf3 in formula 2 may be the same or different and is CF 3 , C 2 F 5 , C 3 F 7 or C 4 F 9 , and
(B) a fatty acid amine salt in an amount of 0.1 to 5.0 mass %,
wherein the ionic liquid has a melting point of −20° C. or less, and
wherein the anion of the ionic liquid is at least one selected from the group consisting of bis(perfluoroalkylsulfonyl)imide, (trifluoromethylsulfonyl)(heptafluoropropylsulfonyl)imide, and tris(perfluoroalkyl)trifluorophosphate, and
wherein the cation of the ionic liquid is at least one selected from the group consisting of ethylmethyl imidazolium, butyldimethyl imidazolium; and propyldimethyl isooxazolium.
2. The lubricant composition of claim 1 , wherein the anion of the ionic liquid is at least one selected from the group consisting of bis(trifluoromethylsulfonyl)imide, (trifluoromethylsulfonyl)(heptafluoropropylsulfonyl) imide, and tris(pentafluoroethyl)trifluorophosphate.
3. The lubricant composition of claim 1 , further comprising a thickener.
4. The lubricant composition comprising:
(A) an ionic liquid selected from the group consisting of:
1-butyl-2,3-dimethyl imidazolium bis(trifluoromethylsulfonyl)imide,
1-(2-methoxyethyl)-1-methyl pyrrolidinium bis(trifluoromethylsulfonyl)imide, triethyloctyl phosphonium bis(trifluoromethylsulfonyl)imide, and
1-ethyl-3-methyl imidazolium (trifluoromethylsulfonyl) (hepta-fluoropropylsulfonyl) imide, and
(B) a fatty acid amine salt in an amount of 0.1 to 5.0 mass %.
5. The lubricant composition of claim 1 , wherein the amine is primary, secondary or tertiary amines, having as a functional group an aliphatic group or an aromatic group.
6. The lubricant composition of claim 5 , wherein the fatty acid amine salt is a salt of a fatty acid having 1 to 22 carbon atoms and an amine.
7. The lubricant composition of claim 4 , further comprising a thickener.
8. The lubricant composition of claim 4 , wherein the amine is primary, secondary or tertiary amines, having as a functional group an aliphatic group or an aromatic group.