IP Library Granted Patent US 9,012,529
Granted Patent B2
US 9,012,529 · App. 11/572,167 · Granted Apr 21, 2015

Hot-melt composition comprising hydrocolloids

Inventors: Pia Frei (Rickenbach, CH); Andreas Dobmann (Oberkirch, CH); Judith Nyffeler (Sempach-Stadt, CH)
Assignee: Nolax AG
A61L15/58A61L15/60
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 9,012,529
App. No.
11/572,167
Granted
Apr 21, 2015
Kind
B2
Abstract

A hot-melt formulation useful as a wound dressing comprises a chemically crosslinked polymer matrix obtainable from prepolymers crosslinkable by means of photopolymerization. Hydrocolloids are embedded in the chemically crosslinked polymer, matrix. The formulation is obtainable by combining the prepolymers and hydrocolloids, and heating and processing the mixture through a slot die, wherein the mixture has a viscosity of less than 100 Pa*s and a processing temperature of less than 150° C. The prepolymers are crosslinked by means of photopolymerization by irradiation with UV light.

Claims (25)

1. A formulation comprising

(a) a chemically crosslinked polymer matrix, obtainable from acrylic prepolymers crosslinkable by means of photopolymerization; and

(b) hydrocolloids embedded in the chemically crosslinked polymer matrix; and

(c) an additive which improves dynamic water absorption capacity, said additive being a sulfonated copolyester;

obtainable by

combining the acrylic prepolymers, hydrocolloids, and the additive which improves dynamic water absorption capacity, and heating and processing the mixture through a slot die at a processing temperature of less than 150° C., wherein the mixture has a viscosity of less than 100 Pa*s, at said processing temperature; and

crosslinking the acrylic prepolymers by means of photopolymerization by irradiation with UV light.

2. The formulation of claim 1 , wherein the formulation is a hydrocolloid pressure-sensitive adhesive.

3. The formulation of claim 1 , comprising about 30% to about 80% by weight crosslinked polymer.

4. The formulation of claim 1 , wherein the hydrocolloids are selected from the group consisting of superabsorbents.

5. The formulation of claim 4 , comprising about 10% to about 40% by weight hydrocolloids.

6. The formulation of claim 1 , further comprising a compound chosen from the group consisting of a tackifier, a plasticizer, one or more stabilizers, and mixtures thereof.

7. The formulation of claim 6 , wherein the tackifier comprises compounds chosen from the group consisting of copolymers of vinyl methyl ether and maleic acid; copolymers of vinyl methyl ether and pyrrolidone; and mixtures thereof.

8. An absorbent medical or cosmetics article comprising a formulation of claim 1 .

9. A process for reducing the occurrence of discolorations in the provision or processing of a formulation of claim 1 , wherein the provision or processing of a hot-melt formulation takes place at a melt temperature of not more than 150° C.

10. A process for providing or processing a hydrocolloid pressure-sensitive adhesive formulation, which comprises the following steps:

a) providing at least one crosslinkable acrylic prepolymer whose nature and amount are such as to give a melt viscosity of less than 100 Pa*s, at a processing temperature of less than 150° C.;

b) providing hydrocolloids;

c) providing an additive which improves dynamic water absorption capacity, said additive being a sulfonated copolyester;

d) combining the acrylic prepolymers, hydrocolloids and the additive which improves dynamic water absorption capacity, and heating and processing the mixture through a slot die, wherein the mixture has a viscosity of less than 100 Pa*s, at a processing temperature of less than 150° C.; and

e) crosslinking the acrylic prepolymer of the formulation by means of photopolymerization, by irradiation with UV light.

11. The process of claim 10 , wherein the mixture is laminated with a backing film before crosslinking.

12. The process of claim 10 , wherein the mixture is applied to a release material before crosslinking.

13. The process of claim 12 , comprising the step of irradiation through a backing film or the release material, or a double-sided irradiation of a hot-melt situated on the release material.

14. A process for crosslinking acrylic prepolymers in a hot-melt formulation comprising acrylic prepolymers crosslinkable by means of photopolymerization, hydrocolloids and an additive which improves dynamic water absorption capacity, said additive being a sulfonated copolyester, wherein all components are premixed and then applied to a release material, wherein the crosslinking takes place by means of irradiation with UV light.

Assignments (5)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 13, 2017
From: NOLAX AG
To: ARTIMELT AG
Reel/Frame 041989/0983 →
CHANGE OF NAME Recorded Oct 17, 2014
From: COLLANO AG
To: COLLANO SERVICES AG
Reel/Frame 033968/0821 →
CHANGE OF NAME Recorded Oct 17, 2014
From: COLLANO SERVICES AG
To: EMERELL AG
Reel/Frame 033968/0872 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 17, 2014
From: EMERELL AG
To: NOLAX AG
Reel/Frame 033968/0937 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 31, 2007
From: FREI, PIA; DOBMANN, ANDREAS; NYFFELER, JUDITH
To: COLLANO AG
Reel/Frame 018832/0031 →
Priority Claims (1)
EP 04016789 · Jul 16, 2004 · regional
Continuity (1)
Related Publication 20080051485A1 · Feb 28, 2008