Processing radioactive waste for shipment and storage
A process for encapsulating a radioactive object to render the object suitable for shipment and/or storage, and including the steps of preparing a plastic material, causing the plastic material to react with a foaming agent, generating a foaming plastic, encapsulating the radioactive object in the foaming plastic, and allowing the foaming plastic to solidify around the radioactive object to form an impervious coating.
1. A method of encapsulating a radioactive object to render the object suitable for shipment and/or storage, and including the steps of:
(a) preparing a plastic material;
(b) causing the plastic material to react with a foaming agent;
(c) generating a foaming plastic; and
(d) encapsulating the object in the foaming plastic wherein the step of encapsulating the object in the foaming plastic includes the steps selected from the group consisting of:
(i) placing a radioactive object in a container, encapsulating the container in the foaming plastic, and allowing the foaming plastic to solidify around the container to form an impervious coating; and
(ii) encapsulating the radioactive object in the foaming plastic, allowing the foaming plastic to solidify around the radioactive object to form an impervious coating;
wherein the foaming plastic comprises a rigid polyurethane foam with the composition comprising:
Polyol blend
Crosslinkers
Water
Fire retardant
Viscosity suppressant
Surfactants
Catalysts
Blowing agent
Polymeric Isocyanate
and the characteristics:
Free Rise Core Density: 2.4 lbs/ft 3
Molded Core Density: 2.8 lbs/ft 3
Compressive Strength: 37 lbs/in 2 .
2. A method according to claim 1 , wherein the foaming plastic comprises a rigid polyurethane foam with the composition comprising:
INGREDIENT
%
Polyol blend
34.78
Crosslinkers
1.45
Water
0.48
Fire retardant
3.60
Viscosity suppressant
1.09
Surfactants
0.72
Catalysts
0.14
Blowing agent
6.04
Polymeric Isocyanate
51.70
TOTAL
100.00
and the characteristics:
Free Rise Core Density: 2.4 lbs/ft 3
Molded Core Density: 2.8 lbs/ft 3
Compressive Strength: 37 lbs/in 2 .
3. A method of encapsulating a radioactive object to render the object suitable for shipment and/or storage, and including the steps of:
(a) preparing a plastic material;
(b) causing the plastic material to react with a foaming agent;
(c) generating a foaming plastic; and
(d) encapsulating the object in the foaming plastic, wherein the step of encapsulating the object in the foaming plastic includes the steps selected from the group consisting of:
(i) placing a radioactive object in a container, encapsulating the container in the foaming plastic, and allowing the foaming plastic to solidify around the container to form an impervious coating; and
(ii) encapsulating the radioactive object in the foaming plastic, allowing the foaming plastic to solidify around the radioactive object to form an impervious coating;
wherein the foaming plastic comprises a rigid polyurethane foam with the composition comprising:
Polyol blend
Crosslinkers
Water
Fire retardant
Viscosity suppressant
Surfactants
Catalysts
Blowing agent
Polymeric Isocyanate
and the characteristics:
Free Rise Core Density: 6.3 lbs/ft 3
Compressive Strength: 135 lbs/in 2 .
4. A method according to claim 3 , wherein the foaming plastic comprises a rigid polyurethane foam with the composition comprising:
INGREDIENT
%
Polyol blend
34.45
Crosslinkers
3.83
Water
0.05
Fire retardant
3.83
Viscosity suppressant
1.41
Surfactants
0.72
Catalysts
0.12
Blowing agent
3.44
Polymeric Isocyanate
52.15
TOTAL
100.00
and the characteristics:
Free Rise Core Density: 6.3 lbs/ft 3
Compressive Strength: 135 lbs/in 2 .
5. A method of encapsulating a radioactive object to render the object suitable for shipment and/or storage, and including the steps of:
(a) preparing a plastic material;
(b) causing the plastic material to react with a foaming agent;
(c) generating a foaming plastic; and
(d) encapsulating the object in the foaming plastic, wherein the step of encapsulating the object in the foaming plastic includes the steps selected from the group consisting of:
(i) placing a radioactive object in a container, encapsulating the container in the foaming plastic, and allowing the foaming plastic to solidify around the container to form an impervious coating; and
(ii) encapsulating the radioactive object in the foaming plastic, allowing the foaming plastic to solidify around the radioactive object to form an impervious coating;
wherein the foaming plastic comprises a rigid polyurethane foam with the composition comprising:
Polyol blend
Crosslinkers
Water
Viscosity suppressant
Surfactants
Catalysts
Blowing agent
Polymeric Isocyanate
and the characteristics:
Free Rise Core Density: 6.0 lbs/ft 3
Compressive Strength: 160 lbs/int.
6. A method according to claim 5 , wherein the foaming plastic comprises a rigid polyurethane foam with the composition comprising:
INGREDIENT
%
Polyol blend
39.38
Crosslinkers
1.65
Water
0.12
Viscosity suppressant
3.07
Surfactants
0.47
Catalysts
0.12
Blowing agent
2.36
Polymeric Isocyanate
52.83
TOTAL
100.00
and the characteristics:
Free Rise Core Density: 6.0 lbs/ft 3
Compressive Strength: 160 lbs/in 2 .
7. A method of encapsulating a radioactive object to render the object suitable for shipment and/or storage, and including the steps of:
(a) preparing a plastic material;
(b) causing the plastic material to react with a foaming agent;
(c) generating a foaming plastic; and
(d) encapsulating the object in the foaming plastic, wherein the step of encapsulating the object in the foaming plastic includes the steps selected from the group consisting of:
(i) placing a radioactive object in a container, encapsulating the container in the foaming plastic, and allowing the foaming plastic to solidify around the container to form an impervious coating; and
(ii) encapsulating the radioactive object in the foaming plastic, allowing the foaming plastic to solidify around the radioactive object to form an impervious coating;
wherein the foaming plastic comprises a rigid polyurethane foam with the composition comprising:
Polyol blend
Crosslinkers
Water
Fire retardant
Viscosity suppressant
Surfactants
Catalysts
Blowing agent
Polymeric Isocyanate
and the characteristics:
Free Rise Core Density: 6.5 lbs/ft 3
Compressive Strength: 150 lbs/in 2 .
8. A method according to claim 7 , wherein the foaming plastic comprises a rigid polyurethane foam with the composition comprising:
INGREDIENT
%
Polyol blend
33.50
Crosslinkers
4.78
Water
0.10
Fire retardant
4.31
Viscosity suppressant
0.57
Surfactants
0.38
Catalysts
1.82
Blowing agent
2.39
Polymeric Isocyanate
52.15
TOTAL
100.00
and the characteristics:
Free Rise Core Density: 6.5 lbs/ft 3
Compressive Strength: 150 lbs/in 2 .
9. A method of encapsulating a radioactive object to render the object suitable for shipment and/or storage, and including the steps of:
(a) preparing a plastic material;
(b) causing the plastic material to react with a foaming agent;
(c) generating a foaming plastic; and
(d) encapsulating the object in the foaming plastic, wherein the step of encapsulating the object in the foaming plastic includes the steps selected from the group consisting of:
(i) placing a radioactive object in a container, encapsulating the container in the foaming plastic, and allowing the foaming plastic to solidify around the container to form an impervious coating; and
(ii) encapsulating the radioactive object in the foaming plastic, allowing the foaming plastic to solidify around the radioactive object to form an impervious coating;
wherein the encapsulated object is coated with a polyurea elastomeric coating with the following composition:
Polyetheramine blend
Amine Crosslinker
Moisture Scavenger
Isocyanate Prepolymer
and the characteristics:
Tensile Strength: 3000 lbs/in 2
Tear Strength: 436 lbs/in
Elongation: 364%
Shore Hardness: 70 Shore D.
10. A method according to claim 9 , wherein the encapsulated object is coated with a polyuria elastomeric coating with the following composition:
INGREDIENT
%
Polyetheramine blend
42.31
Amine Crosslinker
4.81
Moisture Scavenger
0.96
Isocyanate Prepolymer
51.92
TOTAL
100.00
and the characteristics:
Tensile Strength: 3000 lbs/in 2
Tear Strength: 436 lbs/in
Elongation: 364%
Shore Hardness: 70 Shore D.