Separator for nonaqueous secondary battery, method for producing the same, and nonaqueous secondary battery
The present invention is to provide a separator that is excellent in heat resistance, shutdown function, flame retardancy and handling property. The separator for a nonaqueous secondary battery of the invention is a separator for a nonaqueous secondary battery that has a polyolefin microporous membrane at least one surface of which is laminated with a heat resistant porous layer containing a heat resistant resin, and is characterized by containing an inorganic filler containing a metallic hydroxide that undergoes dehydration reaction at a temperature of 200 to 400° C.
1. A separator for a nonaqueous secondary battery comprising a polyolefin microporous membrane at least one surface of which is laminated with a heat resistant porous layer consisting of a heat resistant resin and an inorganic filler,
wherein the inorganic filler contains a metallic hydroxide that undergoes dehydration reaction at a temperature of 200 to 400° C.,
the heat resistant resin is a least one of wholly aromatic polyamide, polyimide, polyamideimide, polysulfone, polyketone, polyetherketone, polyetherimide and cellulose, and
a coated amount of the heat resistant porous layer is 2 to 10 g/m 2 ,
wherein the heat resistant porous layer contains the inorganic filler in an amount of 50 to 95% by weight, and
wherein the heat resistant resin has a molecular weight distribution Mw/Mn of 5≦Mw/Mn≦100 and a weight average molecular weight of 8.0×10 3 to 1.0×10 6 .
2. The separator for a nonaqueous secondary battery according to claim 1 , characterized in that the heat resistant resin is wholly aromatic polyamide, and the wholly aromatic polyamide has an end group concentration ratio of [COOX]/[NH 2 ]≧1, wherein X represents an alkali metal or an alkaline earth metal.
3. The separator for a nonaqueous secondary battery according to claim 1 , characterized in that the metallic hydroxide is at least one of aluminum hydroxide and magnesium hydroxide.
4. The separator for a nonaqueous secondary battery according to claim 1 , characterized in that the inorganic filler is surface-treated with a silane coupling agent.
5. A nonaqueous secondary battery comprising a positive electrode, a negative electrode, a separator provided between the electrodes, and a nonaqueous electrolytic solution,
characterized in that the separator is the separator for a nonaqueous secondary battery according to claim 1 .
6. A nonaqueous secondary battery comprising a positive electrode, a negative electrode, a separator provided between the electrodes, and a nonaqueous electrolytic solution,
characterized in that the separator is the separator for a nonaqueous secondary battery according to claim 2 .
7. A nonaqueous secondary battery comprising a positive electrode, a negative electrode, a separator provided between the electrodes, and a nonaqueous electrolytic solution,
characterized in that the separator is the separator for a nonaqueous secondary battery according to claim 3 .
8. A nonaqueous secondary battery comprising a positive electrode, a negative electrode, a separator provided between the electrodes, and a nonaqueous electrolytic solution,
characterized in that the separator is the separator for a nonaqueous secondary battery according to claim 4 .
9. The separator for a nonaqueous secondary battery according to claim 1 , wherein the polyolefin microporous membrane has an average pore diameter of 3.0 to 30 nm.
10. The separator for a nonaqueous secondary battery according to claim 3 , wherein the metallic hydroxide is aluminum hydroxide.
11. The separator for a nonaqueous secondary battery according to claim 10 , wherein the aluminum hydroxide has a gibbsite composition, a bayerite composition, or a mixed composition of a gibbsite composition and a bayerite composition.
12. The separator for a nonaqueous secondary battery according to claim 10 , wherein the aluminum hydroxide has a gibbsite composition.
13. The separator for a nonaqueous secondary battery according to claim 1 , wherein the heat resistant porous layer contains the inorganic filler in an amount of 70 to 85% by weight.