IP Library Granted Patent US 9,044,880
Granted Patent B2
US 9,044,880 · App. 13/388,523 · Granted Jun 2, 2015

Method for producing container

Inventors: Takafumi Oda (Kanagawa, JP); Ryoji Otaki (Kanagawa, JP)
Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.
B29C49/0005B29C49/22B65D1/0215C08K5/0083C08L77/06B29K2995/0067B29K2995/0041B29K2995/0069B29K2077/00
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Quick Facts
Patent No.
US 9,044,880
App. No.
13/388,523
Granted
Jun 2, 2015
Kind
B2
Abstract

Provided is a production method for a container, including the steps of: inflating a material in a mold by direct blowing, the material including a polyamide resin composition containing 0.01 to 2 parts by mass of a crystallization promoter and 100 parts by mass of a polyamide resin obtained by polycondensation of a diamine component containing 70 mol % or more of m-xylylenediamine and a dicarboxylic acid component including an α,ω-linear aliphatic dicarboxylic acid having 4 to 12 carbon atoms and an aromatic dicarboxylic acid at a molar ratio of 97:3 to 90:10; and retaining the material in the mold whose temperature is controlled to 0 to 60° C., for a time beginning immediately after the direct blowing and lasting for 30% or more of a semi-crystallization time at cooling of the polyamide resin composition under a constant temperature of 160° C.

Claims (21)

1. A method for producing a container, the method comprising:

inflating a material in a mold by direct blow molding, wherein the material comprises a polyamide resin composition comprising 0.01 to 2 parts by mass of a crystallization promoter and 100 parts by mass of a polyamide resin obtained by polycondensation of (i) a diamine component comprising 70 mol % or more of m-xylylenediamine and (ii) a dicarboxylic acid component comprising an α,ω-linear aliphatic dicarboxylic acid comprising 4 to 12 carbon atoms and an aromatic dicarboxylic acid at a molar ratio of 97:3 to 90:10; and

retaining the material in the mold, which has a temperature held at a temperature of 0 to 60° C., for a time beginning immediately after the direct blow molding and lasting for 30% or more and 1,000% or less of a semi-crystallization time at cooling of the polyamide resin composition under a constant temperature of 160° C.,

wherein a peak temperature due to crystallization during heating in differential calorimetry of the polyamide resin composition is 140 to 160° C.

2. The method of claim 1 , wherein the aromatic dicarboxylic acid is at least one selected from the group consisting of isophthalic acid, terephthalic acid, and 2,6-naphthalenedicarboxylic acid.

3. The method of claim 1 , further comprising forming at least one additional layer which comprises another thermoplastic resin to form a multilayer container, and the direct blow molding of the material is carried out so that the multilayer container comprises a layer comprising the material.

4. The method of claim 3 , wherein the multilayer container comprises a layer comprising a second material comprising a polyolefin resin, which is different than the layer comprising the material.

5. The method of claim 3 , wherein the direct blow molding of the material is carried out so that the layer comprising the material is arranged in an inner surface of the container.

6. The method of claim 1 , wherein a content of the crystallization promoter is 0.1 to 1 parts by mass, based on 100 parts of the polyamide resin.

7. The method of claim 1 , wherein a content of the m-xylylenediamine in the diamine component is 75 mol % or more.

8. The method of claim 1 , wherein a content of the m-xylylenediamine in the diamine component is 85 mol % or more.

9. The method of claim 1 , wherein a content of the m-xylylenediamine in the diamine component is 90 mol % or more.

10. The method of claim 1 , wherein the α,ω-linear aliphatic dicarboxylic acid is at least one selected from the group consisting of succinic acid, glutaric acid, pimelic acid, suberic acid, azelaic acid, adipic acid, sebacic acid, undecanedioic acid, and dodecanedioic acid.

11. The method of claim 1 , wherein the α,ω-linear aliphatic dicarboxylic acid is adipic acid.

12. The method of claim 1 , wherein the aromatic dicarboxylic acid is isophthalic acid.

13. The method of claim 1 , wherein the aromatic dicarboxylic acid is terephthalic acid.

14. The method of claim 1 , wherein the aromatic dicarboxylic acid is 2,6-naphthalenedicarboxylic acid.

15. The method of claim 1 , wherein the crystallization promoter is powdered talc having a particle diameter of about 1.5 to 3.0 μm or less.

16. The method of claim 1 , wherein the crystallization promoter is a bis(benzylidene)sorbitol-based crystallization nucleating agent.

17. The method of claim 1 , wherein the polyamide resin composition has a relative viscosity of 1.5 to 4.2.

18. The method of claim 1 , wherein the retention time in the mold is 6 to 30 seconds.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 5, 2012
From: ODA, TAKAFUMI; OTAKI, RYOJI
To: MITSUBISHI GAS CHEMICAL COMPANY, INC.
Reel/Frame 027804/0848 →
Priority Claims (3)
JP 2009-181868 · Aug 4, 2009 · national
JP 2009-181869 · Aug 4, 2009 · national
JP 2009-181871 · Aug 4, 2009 · national
Continuity (1)
Related Publication 20120146266A1 · Jun 14, 2012