Method for producing low-chlorine polybiphenyl sulfone polymers
The present invention relates to a process for the production of low-chlorine-content polybiphenyl sulfone polymers, to the polybiphenyl sulfone polymers obtainable in this way, to polybiphenyl sulfone polymers with less than 800 ppm content of organically bonded chlorine, to thermoplastic molding compositions and moldings, fibers, films, membranes, or foams comprising the polybiphenyl sulfone polymers mentioned, and also to their use for the production of moldings, of fibers, of films, of membranes, or of foams.
1. A process for the production of hydroxy terminated polybiphenyl sulfone polymers comprising (a) reacting component (a1) which comprises at least one aromatic dihydroxy compound and (a2) 4,4′-dichlorodiphenyl sulfone, wherein component (a1) comprises 4,4′-dihydroxydiphenyl and the reaction is carried out with a molar excess of component (a1) in a solvent comprising N-methylpyrrolidone, wherein the molar ratio of component (a1) to (a2) is from 1.01 to 1.05.
2. The process according to claim 1 , wherein component (a1) comprises at least 50% by weight of 4,4′-dihydroxybiphenyl.
3. The process according to claim 1 , wherein component (a1) is 4,4′-dihydroxybiphenyl.