Anticorrosive flux
Aluminum parts, such as heat exchangers, with improved resistance towards corrosion caused by contact with stationary water or aqueous compositions can be obtained by addition of Li compounds to the flux used for brazing such parts. LiF and especially Li fluoroaluminates are very suitable. Another aspect of the invention concerns fluxes containing Li salts and their use for brazing of aluminum parts.
1. A process for enhancing the corrosion resistance of brazed parts made of aluminum or aluminum alloys against corrosion caused by the contact with water or aqueous compositions, comprising
applying a modified flux for aluminum brazing to at least a portion of a surface of the parts to be brazed which are made of aluminum or aluminum alloys, said modified flux containing a basic flux and Li cations, wherein the basic flux contains equal to or less than 5% by weight of K 3 AlF 6 ;
assembling the parts to be brazed; and
brazing the assembled parts.
2. The process of claim 1 wherein the basic flux is selected from the group consisting of potassium fluoroaluminate fluxes; potassium fluoroaluminate and cesium fluoroaluminate containing fluxes; potassium fluorozincate containing fluxes; potassium fluoroaluminate and Si and optionally cesium fluoroaluminate containing fluxes; and potassium hexafluorosilicate containing fluxes.
3. The process of claim 1 wherein the Li cations in the modified flux are contained in an additive which is selected from the group consisting of LiF, Li fluoroaluminates, lithium potassium fluoroaluminates, and their precursors.
4. The process of claim 2 wherein the basic flux contains at least one compound selected from the group consisting of KAlF 4 , K 2 AlF 5 , CsAlF 4 , Cs 2 AlF 5 , Cs 3 AlF 6 , KZnF 3 , K 2 SiF 6 , and their hydrates.
5. The process of claim 3 wherein the additive is selected from the group consisting of LiF and Li 3 AlF 6 .
6. The process of claim 1 , further comprising a post-treatment step to enhance corrosion resistance of said brazed parts against corrosion caused by fluoride ions leached from flux residues during their contact with water or aqueous compositions.
7. The process of claim 6 wherein the post-treatment is a heat treatment, and wherein the process comprises subjecting the brazed parts to said heat treatment with oxygen or an oxygen-containing gas at a temperature of equal to or higher than 400° C. and equal to or lower than 530° C.
8. The process of claim 7 wherein the heat treatment is performed for a duration equal to or longer than 30 seconds, and equal to or shorter than 15 minutes.
9. A modified flux for aluminum brazing comprising Li cations and a basic flux suitable for aluminum brazing with the proviso that, if the basic flux is a potassium fluoroaluminate flux, the content of K 3 AlF 6 in said modified flux is equal to or lower than 5% by weight.
10. The modified flux of claim 9 wherein the basic flux is selected from the group consisting of KAlF 4 , K 2 AlF 5 , CsAlF 4 , Cs 2 AlF 5 , Cs 3 AlF 6 , KZnF 3 , K 2 SiF 6 , their hydrates, and mixtures of two, three or more thereof.
11. The modified flux of claim 9 containing Li cations in the form of LiF or Li fluoroaluminate.
12. The modified flux of claim 11 containing Li cations in the form of Li 3 AlF 6 .
13. The modified flux of claim 9 wherein the content of Li + in said modified flux is equal to or greater than 0.1% by weight and equal to or less than 4.6% by weight when the total dry weight of the modified flux is set as 100% by weight.
14. The modified flux of claim 9 wherein the basic flux consists essentially of KAlF 4 and 10 to 40% by weight K 2 AlF 5 or their hydrates, relative to the basic flux, and wherein the modified flux comprises from 5 to 36% by weight of Li 3 AlF 6 , with the balance to 100% by weight in the modified flux being the basic flux.
15. A flux composition containing a modified flux comprising Li cations and a basic flux suitable for aluminum brazing with the proviso that, if the basic flux is a potassium fluoroaluminate flux, the content of K 3 AlF 6 in said modified flux is equal to or lower than 5% by weight, and one or more brazing and/or fluxing additives.
16. Aluminum parts for brazing, coated at least partially with a modified flux comprising Li cations and a basic flux suitable for aluminum brazing with the proviso that, if the basic flux is a potassium fluoroaluminate flux, the content of K 3 AlF 6 in said modified flux is equal to or lower than 5% by weight.
17. A process for brazing of parts made from aluminum or aluminum alloys, comprising:
coating at least partially the parts to be brazed with a modified flux comprising Li cations and a basic flux suitable for aluminum brazing with the proviso that, if the basic flux is a potassium fluoroaluminate flux, the content of K 3 AlF 6 in said modified flux is equal to or lower than 5% by weight;
assembling the parts;
heating the parts to a temperature sufficiently high to braze the parts; and
brazing the parts.
18. The process of claim 2 wherein the basic flux consists of at least one compound selected from the group consisting of KAlF 4 , K 2 AlF 5 , CsAlF 4 , Cs 2 AlF 5 , Cs 3 AlF 6 , KZnF 3 , K 2 SiF 6 , and their hydrates.
19. The modified flux according to claim 9 wherein the basic flux is a potassium fluoroaluminate flux, and wherein the content of K 3 AlF 6 in said modified flux is equal to or lower than 2% by weight.
20. The modified flux according to claim 9 wherein the basic flux is a potassium fluoroaluminate flux, and wherein the content of K 3 AlF 6 in said modified flux is equal to or less than 1% by weight including 0% by weight.
21. Aluminum parts for brazing, coated at least partially with a flux composition containing a modified flux comprising Li cations and a basic flux suitable for aluminum brazing with the proviso that, if the basic flux is a potassium fluoroaluminate flux, the content of K 3 AlF 6 in said modified flux is equal to or lower than 5% by weight and one or more brazing and/or fluxing additives.