IP Library › Granted Patent US 9,067,186
Granted Patent B2
US 9,067,186 · App. 13/366,216 · Granted Jun 30, 2015

Stability control of a hydrogen generating system and method

Inventor: Jeff Carey (Oakland, CA)
Assignee: MARINE POWER PRODUCTS INCORPORATED
B01J7/02C25B15/08B01J23/8926B01J2219/00006B01J2219/00144C01B3/04C01B13/0203C25B1/04C25B15/02Y02E60/364Y02E60/366
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Quick Facts
Patent No.
US 9,067,186
App. No.
13/366,216
Granted
Jun 30, 2015
Kind
B2
Abstract

A method of and apparatus for efficient on-demand production of H 2 and O 2 from water and heat using environmentally safe metals are disclosed. In one aspect, the apparatus for hydrogen generation through water-decomposition reaction includes a main reactor, an oxidizer reactor, and a computer-control system. The computer system is configured to control each of the components of the hydrogen gas production system for stable hydrogen-gas production.

Claims (32)

1. A method of maintaining a performance of an electric-catalytic-hydrolysis system comprising:

a. preparing the electric-catalytic-hydrolysis system comprising a reactor core and an oxidizer reactor, wherein a basic solution is maintained within the reactor core and contains a hydrogen generating catalyst, wherein the hydrogen generating catalyst contains an aluminum complex, a copper complex, and a silver complex;

b. optimizing hydrogen production by maintaining a pH value of the basic solution in the reactor core below 9.5; and

c. regenerating the silver complex by photolysis utilizing a light providing device within the oxidizer reactor.

2. The method of claim 1 , wherein the optimizing hydrogen production comprises maintaining the of the basic solution in the reactor core pH value below 8.5.

3. The method of claim 1 , wherein the optimizing hydrogen production comprises maintaining the pH value of the basic solution in the oxidizer reactor below 11.

4. The method of claim 1 , wherein the optimizing hydrogen production comprises optimizing an amount of the hydrogen generating catalyst.

5. The method of claim 4 , wherein optimizing the amount of the hydrogen generating catalyst comprises increasing a regeneration rate of the hydrogen generating catalyst.

6. The method of claim 5 , wherein the regeneration rate of the hydrogen generating catalyst comprises a rate of converting a reacted hydrogen generating catalyst back to the hydrogen generating catalyst.

7. The method of claim 1 , wherein optimizing the hydrogen production comprises optimizing a regeneration rate of an Ag 0 .

8. The method of claim 1 , wherein optimizing the hydrogen production comprises optimizing an amount of an Ag 0 , an Ag 1+ , or a combination thereof.

9. The method of claim 1 , wherein optimizing the hydrogen production comprises increasing the rate of dissociating oxygen from the silver complex within the oxidizer reactor.

10. The method of claim 1 , wherein optimizing the hydrogen production comprises converting a hydroxide of a hydroxide containing compound into an oxide of a metal oxide.

11. The method of claim 1 , wherein optimizing the hydrogen production comprises increasing the rate of dissociating a hydroxide from the copper complex.

12. The method of claim 1 , wherein regenerating the silver complex by photolysis comprises optimizing light providing duration, a light providing intensity, or a light providing frequency, a combination thereof through the light providing device.

13. The method of claim 1 , wherein optimizing the hydrogen production comprises optimizing a voltage providing amount, a current providing amount, or a combination thereof through the electric energy providing device.

14. A method of maintaining a performance of an electric-catalytic-hydrolysis system comprising:

a. preparing the electric-catalytic-hydrolysis system comprising a reactor core and an oxidizer reactor, wherein a basic solution is maintained within the reactor core and contains a hydrogen generating catalyst, wherein the hydrogen generating catalyst contains an aluminum complex, a copper complex, and a silver complex;

b. optimizing hydrogen production by maintaining a pH value of the basic solution in the reactor core below 9.5; and

c. regenerating the silver complex by thermolysis utilizing a heat providing device after the reactor core.

15. The method of claim 14 , wherein the optimizing hydrogen production comprises maintaining the pH value of the basic solution in the reactor core below 8.5.

16. The method of claim 14 , wherein the optimizing hydrogen production comprises maintaining the pH value of the basic solution in the oxidizer reactor below 11.

17. The method of claim 14 , wherein the optimizing hydrogen production comprises optimizing an amount of the hydrogen generating catalyst.

18. The method of claim 14 , wherein optimizing the amount of the hydrogen generating catalyst comprises increasing a regeneration rate of the hydrogen generating catalyst.

19. The method of claim 14 , wherein the regeneration rate of the hydrogen generating catalyst comprises a rate of converting a reacted hydrogen generating catalyst back to the hydrogen generating catalyst.

20. The method of claim 14 , wherein optimizing the hydrogen production comprises optimizing a regeneration rate of an Ag 0 .

21. The method of claim 14 , wherein optimizing the hydrogen production comprises optimizing an amount of an Ag 0 , an Ag 1+ , or a combination thereof.

22. The method of claim 14 , wherein optimizing the hydrogen production comprises increasing the rate of dissociating oxygen from the silver complex within the oxidizer reactor.

23. The method of claim 14 , wherein optimizing the hydrogen production comprises converting a hydroxide of a hydroxide containing compound into an oxide of a metal oxide.

24. The method of claim 14 , wherein optimizing the hydrogen production comprises increasing the rate of dissociating a hydroxide from the copper complex.

25. The method of claim 14 , wherein regenerating the silver complex by thermolysis comprises optimizing a heat providing duration, a heat providing amount, or a combination thereof through the heat providing device.

26. The method of claim 14 , wherein optimizing the hydrogen production comprises optimizing a voltage providing amount, a current providing amount, or a combination thereof through an electric energy providing device.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 3, 2012
From: CAREY, JEFFREY M.
To: MARINE POWER PRODUCTS INCORPORATED
Reel/Frame 027653/0215 →
Continuity (4)
Continuation In Part 12706639 · Feb 16, 2010
Provisional Application 61154282 · Feb 20, 2009
Provisional Application 61441193 · Feb 9, 2011
Related Publication 20120132535A1 · May 31, 2012