Photosensitive resin composition for light blocking layer and light blocking layer using the same
A photosensitive resin composition for a light blocking layer includes (A) a colorant including a blue material including a dye represented by the following Chemical Formula 1, and a red material, (B) a binder resin, (C) a photopolymerizable monomer, (D) a photopolymerization initiator, and (E) a solvent, and a light blocking layer using the same. In Chemical Formula 1, each substituent is the same as defined in the detailed description.
1. A photosensitive resin composition for a light blocking layer, comprising:
(A) a colorant including a blue material including a dye represented by the following Chemical Formula 1 and a red material, wherein the colorant comprises the dye represented by Chemical Formula 1 and the red material in a weight ratio of about 10:90 to about 90:10;
(B) a binder resin;
(C) a photopolymerizable monomer;
(D) a photopolymerization initiator; and
(E) a solvent:
wherein, in Chemical Formula 1,
X 1 and X 2 are the same or different and are each independently a carbon atom, a sulfur atom, or an oxygen atom,
R 1 to R 6 are the same or different and are each independently hydrogen, substituted or unsubstituted C1 to C20 alkyl, substituted or unsubstituted C2 to C20 alkenyl, substituted or unsubstituted C2 to C20 alkynyl, substituted or unsubstituted C3 to C20 cycloalkyl, substituted or unsubstituted C3 to C20 cycloalkenyl, substituted or unsubstituted C3 to C20 cycloalkynyl, substituted or unsubstituted C2 to C20 heterocycloalkyl, substituted or unsubstituted C2 to C20 heterocycloalkenyl, substituted or unsubstituted C2 to C20 heterocycloalkynyl, substituted or unsubstituted C6 to C30 aryl, or substituted or unsubstituted C2 to C30 heteroaryl,
Y 1 cyclic group and Y 2 cyclic group are the same or different and are each independently substituted or unsubstituted C3 to C20 cycloalkyl, substituted or unsubstituted C3 to C20 cycloalkenyl, substituted or unsubstituted C3 to C20 cycloalkynyl, substituted or unsubstituted C2 to C20 heterocycloalkyl, substituted or unsubstituted C2 to C20 heterocycloalkenyl, substituted or unsubstituted C2 to C20 heterocycloalkynyl, substituted or unsubstituted C6 to C30 aryl, or substituted or unsubstituted C2 to C30 heteroaryl,
A 1 is a halide anion, perhalate anion, tetrafluoroborate anion (BF 4 − ), a hexafluoroantimonate anion (SbF 6 − ), a haloacetate anion, an alkylsulfate anion, a sulfonate anion, or a hexafluorophosphate anion (PF 6 − ), and
n 1 to n 4 are the same or different and are each independently 0 or 1.
2. The photosensitive resin composition for a light blocking layer of claim 1 , wherein the dye represented by the Chemical Formula 1 comprises a dye represented by the following Chemical Formula 2:
wherein, in Chemical Formula 2,
R 7 to R 12 are the same or different and are each independently hydrogen, substituted or unsubstituted C1 to C20 alkyl, substituted or unsubstituted C2 to C20 alkenyl, substituted or unsubstituted C2 to C20 alkynyl, substituted or unsubstituted C3 to C20 cycloalkyl, substituted or unsubstituted C3 to C20 cycloalkenyl, substituted or unsubstituted C3 to C20 cycloalkynyl, substituted or unsubstituted C2 to C20 heterocycloalkyl, substituted or unsubstituted C2 to C20 heterocycloalkenyl, substituted or unsubstituted C2 to C20 heterocycloalkynyl, substituted or unsubstituted C6 to C30 aryl, or substituted or unsubstituted C2 to C30 heteroaryl, and
A 2 is a halide anion, a perhalate anion, a tetrafluoroborate anion (BF 4 − ), a hexafluoroantimonate anion (SbF 6 − ), a haloacetate anion, an alkylsulfate anion, a sulfonate anion, or a hexafluorophosphate anion (PF 6 − ).
3. The photosensitive resin composition for a light blocking layer of claim 1 , wherein the blue material further comprises a violet pigment.
4. The photosensitive resin composition for a light blocking layer of claim 1 , wherein the red material comprises a dye, a pigment, or a combination thereof.
5. The photosensitive resin composition for a light blocking layer of claim 1 , wherein the red material comprises a perylene-based pigment, an anthraquinone-based pigment, a dianthraquinone-based pigment, an azo-based pigment, a diazo-based pigment, a quinacridone-based pigment, an anthracene-based pigment, or a combination thereof.
6. The photosensitive resin composition for a light blocking layer of claim 1 , wherein the colorant further comprises a green material.
7. The photosensitive resin composition for a light blocking layer of claim 6 , wherein the green material comprises a dye, a pigment, or a combination thereof.
8. The photosensitive resin composition for a light blocking layer of claim 6 , wherein the green material comprises a halogenated phthalocyanine-based pigment.
9. The photosensitive resin composition for a light blocking layer of claim 1 , wherein the photosensitive resin composition for a light blocking layer comprises:
about 1 to about 80 wt % of the colorant (A);
about 0.1 to about 30 wt % of the binder resin (B);
about 0.1 to about 30 wt % of the photopolymerizable monomer (C);
about 0.1 to about 5 wt % of the photopolymerization initiator (D); and
a balance amount of the solvent (E).
10. A light blocking layer manufactured using the photosensitive resin composition for a light blocking layer of claim 1 .