Dielectric composition and ceramic electronic component including the same
There is provided a dielectric composition, including; a base powder including Ba m TiO 3 (0.995≦m≦1.010); a first sub-component including 0.05 to 4.00 moles of an oxide or carbonate containing at least one rare-earth element based on 100 moles of the base powder; a second sub-component including 0.05 to 0.70 moles of an oxide or carbonate containing at least one transition metal; a third sub-component including 0.20 to 2.00 moles of a Si oxide; a fourth sub-component including 0.02 to 1.00 mole of an Al oxide; and a fifth sub-component including 20 to 140% of an oxide containing at least one of Ba and Ca, based on the third sub-component.
1. A dielectric composition for a dielectric constant of a ceramic body being at least 1600 or more comprising:
a base powder including Ba m TiO 3 (0.995≦m≦1.010);
a first sub-component including 0.05 to 4 moles of an oxide or carbonate containing at least one rare-earth element based on 100 moles of the base powder;
a second sub-component including 0.05 to 0.7 moles of an oxide or carbonate containing at least one transition metal based on 100 moles of the base powder;
a third sub-component including 0.2 to less than 2 moles of a Si oxide based on 100 moles of the base powder;
a fourth sub-component including 0.02 to 1 mole of an Al oxide based on 100 moles of the base powder; and
a fifth sub-component including 20 to 140% of an oxide containing at least one of Ba and Ca, based on the third sub-component.
2. The dielectric composition of claim 1 , wherein an average grain size is 0.75 μm or less.
3. The dielectric composition of claim 1 , further comprising 0.01 to 2.5 moles of an Mg oxide or carbonate, based on 100 moles of the base powder.
4. The dielectric composition of claim 1 , further comprising 0.01 to 1 mole of a Zr oxide, based on 100 moles of the base powder.
5. The dielectric composition of claim 1 , wherein the rare-earth element of the first sub-component is at least one selected from the group consisting of Y, Dy, Ho, Er and Gd.
6. The dielectric composition of claim 1 , wherein the transition metal of the second sub-component is at least one selected from the group consisting of Mo, W, Mn, Fe, Co, Ni, V, Cr, Cu and Zn.
7. A ceramic electronic component comprising:
a ceramic body having a plurality of dielectric layers laminated therein;
internal electrodes provided within the ceramic body and including a base metal; and
external electrodes provided on an outer surface of the ceramic body and electrically connected to the internal electrodes,
wherein the dielectric layers include: a base powder including Ba m TiO 3 (0.995≦m≦1.010); a first sub-component including 0.05 to 4 moles of an oxide or carbonate containing at least one rare-earth element based on 100 moles of the base powder; a second sub-component including 0.05 to 0.7 moles of an oxide or carbonate containing at least one transition metal based on 100 moles of the base powder; a third sub-component including 0.2 to less than 2 moles of a Si oxide based on 100 moles of the base powder; a fourth sub-component including 0.02 to 1 mole of an Al oxide based on 100 moles of the base powder; and a fifth sub-component including 20 to 140% of an oxide containing at least one of Ba and Ca, based on the third sub-component, wherein
a dielectric constant of the ceramic body is at least 1600 or more.
8. The ceramic electronic component of claim 7 , wherein the dielectric composition has an average grain size of 0.75 μm or less.
9. The ceramic electronic component of claim 7 , wherein the dielectric composition further includes 0.01 to 2.5 moles of an Mg oxide or carbonate, based on 100 moles of the base powder.
10. The ceramic electronic component of claim 7 , wherein the dielectric composition further includes 0.01 to 1 mole of a Zr oxide, based on 100 moles of the base powder.
11. The ceramic electronic component of claim 7 , wherein the rare-earth element of the first sub-component is at least one selected from the group consisting of Y, Dy, Ho, Er and Gd.
12. The ceramic electronic component of claim 7 , wherein the transition metal of the second sub-component is at least one selected from the group consisting of Mo, W, Mn, Fe, Co, Ni, V, Cr, Cu and Zn.
13. The ceramic electronic component of claim 7 , wherein each of the dielectric layers has a thickness in a range of 0.2 to 10 μm.
14. The ceramic electronic component of claim 7 , wherein the internal electrodes include Ni or a Ni alloy.
15. The ceramic electronic component of claim 7 , wherein the internal electrodes are alternately laminated with the dielectric layers.