Separator and rechargeable lithium battery
In one aspect, a separator that includes a porous substrate; and a coating layer including an inorganic compound-organic/inorganic binder, and a binder polymer, and a rechargeable lithium battery including the separator is provided.
1. A separator comprising
a porous substrate; and
a coating layer including an (inorganic compound)-(organic/inorganic binder)-(binder polymer), where the (inorganic compound)-(organic/inorganic binder)-(binder polymer) is formed by reacting an inorganic compound, an organic/inorganic binder, and a binder polymer, wherein the inorganic compound is hydrophilic particles having a hydroxyl group on the surface, wherein the binder polymer is a particle having a particle diameter of about 0.01 μm to about 0.5 μm.
2. The separator of claim 1 , wherein the porous substrate comprises at least one component selected from the group consisting of a glass fiber, polyester, polyolefin, polytetrafluoroethylene (PTFE), and polyacrylonitrile.
3. The separator of claim 1 , wherein the inorganic compound-organic/inorganic binder has an average particle diameter of about 1 nm to about 1000 nm.
4. The separator of claim 3 , wherein the particle of the inorganic compound-organic/inorganic binder is coated continuously or discontinuously on the surface of the binder polymer.
5. The separator of claim 1 , wherein the inorganic compound comprises at least one selected component selected from the group consisting of metal oxide, semi-metal oxide, and metal fluoride.
6. The separator of claim 1 , wherein the organic/inorganic binder comprises epoxyalkylalkoxysilane.
7. The separator of claim 1 , wherein the binder polymer comprises a cross-linking functional group.
8. The separator of claim 7 , wherein the cross-linking functional group comprises one selected from a hydroxyl group, a glycidyl group, an amino group, an N-methylol group, a vinyl group, and a combination thereof.
9. The separator of claim 1 , wherein the binder polymer comprises one selected from the group consisting of a styrene-butadiene rubber, an acrylated styrene-butadiene rubber, an acrylonitrile-butadiene rubber, an acrylonitrile-butadiene-styrene rubber, an acrylic rubber, a butyl rubber, a fluorine rubber, polytetrafluoroethylene, polyethylene, polypropylene, an ethylene propylene copolymer, polyethylene oxide, polyvinylpyrrolidone, polyepichlorohydrine, polyphosphazene, polyacrylate, polyacrylonitrile, polystyrene, ethylenepropylenedienecopolymer, polyvinylpyridine, chlorosulfonated polyethylene, latex, a polyester resin, an acrylic resin, a phenolic resin, an epoxy resin, polyvinyl alcohol, carboxylmethyl cellulose, hydroxypropylmethyl cellulose, hydroxypropyl cellulose, and diacetyl cellulose.
10. The separator of claim 1 , wherein the binder polymer is a particle having a particle diameter of about 0.01 μm to about 0.5 μm.
11. The separator of claim 1 , wherein the coating layer is formed by mixing the particle of the inorganic compound and the organic/inorganic binder with an emulsion solution of the binder polymer to prepare a composition and coating the composition.
12. The separator of claim 1 , wherein the porous substrate comprises at least one component selected from the group consisting of a glass fiber, polyester, polyolefin, polytetrafluoroethylene (PTFE), and polyacrylonitrile.
13. A rechargeable lithium battery comprising:
a positive electrode including a positive active material;
a negative electrode including a negative active material;
a non-aqueous electrolyte; and
a separator according to claim 1 .