High diamond frame strength PCD materials
View Patent ↗The present disclosure relates to cutting elements incorporating polycrystalline diamond bodies used for subterranean drilling applications, and more particularly, to polycrystalline diamond bodies having high diamond frame strength and methods for forming and evaluating such polycrystalline diamond bodies. A polycrystalline diamond body is provided, having a top surface, a cutting edge meeting the top surface, and a first region including at least a portion of the cutting edge. The first portion exhibits a diamond frame strength of about 1200 MPa or greater, or about 1300 MPa or greater.
1. A cutting element comprising:
a polycrystalline diamond body comprising:
an interface surface;
a top surface opposite the interface surface;
a cutting edge meeting the top surface; and
a material microstructure comprising a plurality of bonded-together diamond crystals and interstitial regions between the diamond crystals, the microstructure having a first region that includes at least a portion of the cutting edge, and
wherein the first region comprises a diamond frame strength of about 1200 MPa or greater.
2. The cutting element of claim 1 , wherein the diamond frame strength of the first region is about 1300 MPa or greater.
3. The cutting element of claim 2 , wherein the first region comprises a sintered average grain size less than 10 microns.
4. The cutting element of claim 2 , wherein the first region comprises a sintered average grain size less than 7 microns.
5. The cutting element of claim 2 , wherein the first region comprises a sintered average grain size in the range of 5-6 microns.
6. The cutting element of claim 5 , wherein a second region of the microstructure proximate the interface surface comprises a plurality of the interstitial regions comprising the catalyst material disposed therewithin.
7. The cutting element of claim 2 , wherein the first region comprises a plurality of the interstitial regions that are substantially free of a catalyst material, and wherein the first region extends from the cutting edge to a depth of at least 300 microns.
8. The cutting element of claim 2 , wherein the microstructure exhibits a drop in compressive stress of up to 25% after leaching, at room temperature.
9. The cutting element of claim 2 , wherein the diamond volume fraction in the first region is greater than 91%.
10. The cutting element of claim 2 , wherein the first region extends along the entire cutting edge of the cutting element.
11. The cutting element of claim 2 , wherein the first region extends along at least a critical zone of the polycrystalline diamond body.
12. The cutting element of claim 2 , wherein the first region extends along the entire top surface, the cutting edge, and at least a portion of a side surface.
13. The cutting element of claim 2 , wherein the first region comprises the entire polycrystalline diamond body.
14. The cutting element of claim 13 , further comprising a substrate bonded to the interface surface.
15. The cutting element of claim 2 , comprising a catalyst material in at least a portion of the microstructure, and wherein the polycrystalline diamond body has a strength of about 1500 MPa or greater.
16. The cutting element of claim 1 , wherein the interface comprises at least a non-aggressive progression having a height to width ratio less than 0.7.
17. A cutting element comprising:
a substrate; and
a polycrystalline diamond body formed over the substrate, the polycrystalline diamond body comprising:
an interface surface meeting the substrate at an interface;
a top surface opposite the interface surface;
a cutting edge meeting the top surface; and
a material microstructure comprising a plurality of bonded-together diamond crystals and interstitial regions between the diamond crystals, wherein a first region of the microstructure proximate the top surface has a diamond frame strength of about 1300 MPa or greater and an average sintered grain size of less than 10 microns.
18. The cutting element of claim 17 , wherein the interface comprises a non-aggressive shape having a height to diameter ratio of zero to 0.1.
19. The cutting element of claim 18 , wherein the substrate comprises a cobalt content less than or equal to approximately 11% by weight.
20. The cutting element of claim 17 , wherein the first region of the microstructure comprises a plurality of the interstitial regions that are substantially free of a catalyst material, and further comprising a second region of the microstructure proximate the interface surface comprising a plurality of the interstitial regions comprising the catalyst material disposed therewithin.
21. The cutting element of claim 17 , wherein the first region comprises an average sintered grain size less than 7 microns.
22. The cutting element of claim 17 , wherein the interface comprises a non-aggressive shape having a height to diameter ratio of zero to 0.1.
23. The cutting element of claim 17 , wherein the interface comprises at least a non-aggressive progression having a height to width ratio less than 0.7.
24. A cutting element comprising:
a substrate having an interface surface with a height to diameter ratio between 0 and 0.1 and a cobalt content less than 11%; and
a polycrystalline diamond body formed over the interface surface of the substrate, the polycrystalline diamond body comprising:
an interface surface;
a top surface opposite the interface surface;
a cutting edge meeting the top surface; and
a material microstructure comprising a plurality of bonded-together diamond crystals and interstitial regions between the diamond crystals, wherein a first region of the microstructure has a diamond frame strength of about 1300 MPa or greater, an average sintered grain size of less than 14 microns, and a diamond volume fraction of at least 93%, wherein the first region incorporates the cutting edge.
25. The cutting element of claim 24 , wherein the interface comprises a non-aggressive shape having a height to diameter ratio of zero to 0.1.
26. The cutting element of claim 24 , wherein the interface comprises at least a non-aggressive progression having a height to width ratio less than 0.7.