Apparatus and method of in-situ measurement of membrane fluid crossover
Systems and methods for measuring in-situ membrane fluid crossover are provided. One embodiment of a system for diagnosing in situ degradation of membranes in a fuel cell stack comprises an inert gas supply configured to be connected to the fuel cell stack to supply an inert gas to an anode side of the fuel cell stack during diagnosis and an analyzer, for example, for detecting an amount of crossover cathode gas in exhaust from the anode side of the fuel cell stack during diagnosis.
1. A system for diagnosing in situ degradation of membranes in a fuel cell stack comprising:
an inert gas supply configured to be connected to the fuel cell stack to supply an inert gas to an anode side of the fuel cell stack during diagnosis;
a collection cell configured to receive an exhaust from the anode side of the fuel cell stack, collect condensed liquid from the exhaust and release dewatered exhaust;
a gas detector for detecting an amount of crossover cathode gas in the dewatered exhaust from the collection cell; and
a sparger for bubbling additional inert gas into the condensed liquid collected in the collection cell.
2. The system of claim 1 , wherein the gas detector is one of a trace gas analyzer, a mass spectrometer and a gas chromatograph.
3. The system of claim 1 , wherein the inert gas is nitrogen and the crossover cathode gas is oxygen.
4. The system of claim 1 further comprising a gas drying unit on the dewatered exhaust from the collection cell configured to further dry the exhaust prior to reaching the means for detecting.
5. The system of claim 1 further comprising a dissolved gas or conductivity meter in the collection cell configured to measure dissolved crossover cathode gas in the condensed liquid collected in the collection cell.
6. The system of claim 1 further comprising a control unit having preprogrammed baseline data relating an amount of crossover cathode gas to an amount of membrane degradation, the control unit configured to receive data from the gas detector and compare the data to the preprogrammed baseline data to determine membrane degradation.
7. The system of claim 1 , wherein the gas detector comprises a plurality of oxygen sensors, each oxygen sensor located on a respective anode of a fuel cell within the fuel cell stack to detect an amount of crossover cathode gas in exhaust from the respective anode.
8. The system of claim 7 , further comprising a control unit having preprogrammed baseline data relating an amount of crossover cathode gas to an amount of membrane degradation, the control unit configured to receive data from each of the oxygen detectors and to compare the data to the preprogrammed baseline data to determine membrane degradation.