Organic electroluminescence element
A top-emission organic electroluminescence device ( 1 ) includes in order a first electrode ( 20 ), one or more organic layers ( 30 B) including a blue-emitting layer ( 34 B), a second electrode ( 40 ), and a capping layer ( 50 ), wherein the capping layer ( 50 ) is formed of a material that satisfies the expression “n(λ=430 nm)−n(λ=460 nm)>0.08” (where, n(λ=x nm) indicates a refractive index at a wavelength of x nm) and has an extinction coefficient of 0.1 or less at a wavelength of 430 to 500 nm.
1. A top-emission organic electroluminescence device, comprising, in the following order:
a substrate;
a first electrode;
an organic layer comprising a blue-emitting layer;
a second electrode; and
a capping layer,
wherein:
the capping layer comprises a material having (i) an extinction coefficient of 0.1 or less at a wavelength of 430 to 500 nm, and (ii) an amount of charge in refractive index that satisfies an expression (1):
n (λ=430 nm)− n (λ=460 nm)>0.08 (1),
wherein, n(λ=x nm) is a refractive index at a wavelength of x nm;
the organic layer further comprises a red-emitting layer and a green-emitting layer; and
a blue pixel, a red pixel, and a green pixel are disposed on a common substrate, and the capping layer is provided common to the blue pixel, the red pixel, and the green pixel.
2. The device of claim 1 , wherein the second electrode comprises a metal.
3. The device of claim 1 , wherein the capping layer has a thickness of 200 nm or less.
4. The device of claim 1 , wherein the blue-emitting layer comprises an emitting material having a peak wavelength of a photoluminescence (PL) spectrum of 430 to 500 nm.
5. The device of claim 1 , wherein the second electrode has a transmittance of 20% or more at a wavelength of 430 to 500 nm.
6. The device of claim 1 , wherein the material in the capping layer comprises a compound satisfying expression (1) selected from the group consisting of
an aromatic hydrocarbon compound comprising a carbon atom and a hydrogen atom, optionally substituted with a substituent optionally comprising an oxygen atom, a nitrogen atom, a fluorine atom, a silicon atom, a chlorine atom, a bromine atom, or an iodine atom,
an aromatic heterocyclic compound comprising a carbon atom and a hydrogen atom, optionally substituted with a substituent optionally comprising an oxygen atom, a nitrogen atom, a fluorine atom, a silicon atom, a chlorine atom, a bromine atom, or an iodine atom, and
an amine compound comprising a carbon atom and a hydrogen atom, optionally substituted with a substituent optionally comprising an oxygen atom, a nitrogen atom, a fluorine atom, a silicon atom, a chlorine atom, a bromine atom, or an iodine atom.
7. The device of claim 1 , wherein the capping layer comprises a compound of formula (11):
wherein:
A 21 and A 22 are each independently a substituted or unsubstituted aromatic ring group comprising 6 to 60 carbon atoms; and
R 21 to R 28 are each independently a hydrogen atom, a substituted or unsubstituted aromatic ring group comprising 6 to 50 carbon atoms, a substituted or unsubstituted aromatic heterocyclic group comprising 5 to 50 atoms, a substituted or unsubstituted alkyl group comprising 1 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted alkoxy group comprising 1 to 50 carbon atoms, a substituted or unsubstituted aralkyl group comprising 6 to 50 carbon atoms, a substituted or unsubstituted aryloxy group comprising 5 to 50 atoms, a substituted or unsubstituted alkoxycarbonyl group comprising 1 to 50 carbon atoms, a substituted or unsubstituted silyl group, a carboxyl group, a halogen atom, a cyano group, a nitro group, or a hydroxy group.
8. The device of claim 2 , wherein the metal is at least one selected from the group consisting of Ag, Mg, Al, Ca, and an alloy thereof.
9. The device of claim 8 , wherein the second electrode has a thickness of 30 nm or less.
10. The device of claim 8 , wherein the capping layer has a thickness of 40 to 140 nm.
11. The device of claim 1 , wherein, in expression (1), the amount of change in refractive index is more than 0.08 and 1.0 or less.
12. The device of claim 11 , wherein, in expression (1), the amount of change in refractive index is between 0.1 and 1.0.
13. The device of claim 12 , wherein, in expression (1), the amount of change in refractive index is between 0.12 and 1.0.
14. The device of claim 1 , wherein the red-emitting layer and the green-emitting layer each comprising a host material and a dopant material.
15. The device of claim 14 , wherein:
the red-emitting layer host material is selected from the group consisting of a naphthcene derivative, a pentacene derivative, a naphthalene compound, a phenanthrene compound, and a fluoranthene compound; and
the red-emitting layer dopant material is selected from the group consisting of a fused aromatic ring comprising a substituted or unsubstituted arylamino group and a metal complex.
16. The device of claim 14 , wherein:
the green-emitting layer host material is selected from the group consisting of an anthracene derivative, a pyrene derivative, a carbazole derivative, a dibenzofuran derivative, a ladder furan compound, and a pyrimidine derivative; and
the green-emitting layer dopant material is selected from the group consisting of (i) a fused aromatic ring derivative comprising a substituted or unsubstituted pyrene group, anthracene group, and chrysene group, (ii) a styrylamine compound, (iii) a boron complex, (iv) a fluoranthene compound, and (iv) a metal compound.