IP Library › Granted Patent US 9,096,701
Granted Patent B2
US 9,096,701 · App. 13/599,986 · Granted Aug 4, 2015

Aqueous tetrafluoroethylene polymer dispersion, process for producing the same, tetrafluoroethylene polymer powder, and molded tetrafluoroethylene polymer

Inventors: Nobuhiko Tsuda (Settsu, JP); Yoshinori Nanba (Settsu, JP); Yasuhiko Sawada (Settsu, JP); Tetsuo Shimizu (Settsu, JP)
Assignee: DAIKIN INDUSTRIES, LTD.
C08F214/26C08F14/26
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Quick Facts
Patent No.
US 9,096,701
App. No.
13/599,986
Granted
Aug 4, 2015
Kind
B2
Abstract

The present invention provides a tetrafluoroethylene polymer aqueous dispersion obtained by carrying out a TFE polymerization in an aqueous medium in the presence of a fluorovinyl group-containing emulsifier, wherein the TFE polymer aqueous dispersion contains a particle comprising a TFE polymer dispersed in the aqueous medium, the fluorovinyl group-containing emulsifier comprises a fluorovinyl group-containing compound, and the TFE polymer aqueous dispersion has a fluorine-containing surfactant content of not higher than 1000 ppm by mass.

Claims (11)

1. A method of producing a tetrafluoroethylene polymer aqueous dispersion by carrying out a tetrafluoroethylene polymerization in an aqueous medium in the presence of a fluorovinyl group-containing emulsifier,

wherein the tetrafluoroethylene polymer has a tetrafluoroethylene unit content exceeding 95 mole percent,

wherein said tetrafluoroethylene polymer aqueous dispersion contains a particle comprising a tetrafluoroethylene polymer dispersed in said aqueous medium and has a fluorine-containing surfactant content of not higher than 1000 ppm by mass,

said fluorovinyl group-containing emulsifier is added in an amount of 0.00001 to 0.06% by mass relative to said aqueous medium, and

said fluorovinyl group-containing emulsifier comprises a fluorovinyl group-containing compound (V) represented by the general formula (V):

CH 2 ═CFCF 2 O—(CF(CF 3 )CF 2 O) f —CF(CF 3 )—Y  (V)

wherein f represents 0 or 1 and Y represents —SO 3 M or —COOM in which M represents H, NH 4 or an alkali metal.

2. The method of producing a tetrafluoroethylene polymer aqueous dispersion according to claim 1 ,

wherein the addition of the fluorovinyl group-containing emulsifier is carried out in the manner of a supplementary addition with the progress of a tetrafluoroethylene polymerization reaction.

3. The method of producing a tetrafluoroethylene polymer aqueous dispersion according to claim 1 ,

wherein the average primary particle diameter is from 175-281 nm.

Priority Claims (1)
JP 2003-362500 · Oct 22, 2003 · national
Continuity (2)
Division 10576450
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