Polyethylene blend compositions and film
A polymer blend comprising first and second polyethylene copolymers is presented which has good processability, and which when made into film shows good toughness-stiffness balance, reasonable MD tear, as well as good optical properties.
1. A polymer blend comprising:
a) from about 5 to about 95 wt % of a first polyethylene copolymer having a density of from about 0.916 to about 0.936 g/cm 3 , a melt index (I 2 ) of from about 0.1 to about 2.0 g/10 min, a melt flow ratio (I 21 /I 2 ) of from about 32 to about 50, a molecular weight distribution (M w /M n ) of from about 3.6 to about 6.5, a reverse comonomer distribution profile as determined by GPC-FTIR, a multimodal TREF profile, a composition distribution breadth index CDBI 50 of from 50 wt % to 75 wt % as determined by TREF and which further satisfies the relationship: (M w /M n )≧72 [(I 21 /I 2 ) −1 +10 −6 (M n )];
and
b) from about 95 to about 5 wt % of a second polyethylene copolymer which is a linear low density polyethylene (LLDPE) different from the first polyethylene copolymer and having a density of from about 0.910 to about 0.940 g/cm 3 , a melt index (I 2 ) of from about 0.2 to about 5.0 g/10 min, and a melt flow ratio (I 21 /I 2 ) of less than about 35.
2. The polymer blend of claim 1 , wherein the first polyethylene copolymer has a δ XO of from about 55° to about 70°; wherein δ XO is the phase angle at which the complex modulus (G*) and the complex viscosity (η*) are numerically equivalent in a plot of phase angle vs complex modulus and complex viscosity as determined by dynamic mechanical analysis.
3. The polymer blend of claim 1 , wherein the first polyethylene copolymer satisfies the relationship: δ XO ≦80.7−(CDBI 50 )/(M w /M n ) at a δ XO of from about 55° to about 70°; wherein δ XO is the phase angle at which the complex modulus (G*) and the complex viscosity (η*) are numerically equivalent in a plot of phase angle vs complex modulus and complex viscosity as determined by dynamic mechanical analysis.
4. The polymer blend of claim 1 , wherein the first polyethylene copolymer satisfies the relationship: δ XO ≦83.0−1.25(CDBI 50 )/(M w /M n ); wherein δ XO is the phase angle at which the complex modulus (G*) and the complex viscosity (η*) are numerically equivalent in a plot of phase angle vs complex modulus and complex viscosity as determined by dynamic mechanical analysis.
5. The polymer blend of claim 1 , wherein the first polyethylene copolymer has a multimodal TREF profile comprising two intensity maxima at elution temperatures T(low) and T(high); wherein T(low) is from about 65° C. to about 85° C., and T(high) is from about 90° C. to about 98° C.
6. The polymer blend of claim 1 , wherein the blend comprises from about 5 to about 50 wt % of the first polyethylene copolymer and from about 95 to about 50 wt % of the second polyethylene copolymer.
7. The polymer blend of claim 1 , wherein the first polyethylene copolymer has a molecular weight distribution (M w /M n ) of from about 4.0 to about 6.0.
8. The polymer blend of claim 1 , wherein the first polyethylene copolymer has a melt index (I 2 ) of from about 0.25 to about 0.80 g/10 min.
9. The polymer blend of claim 1 , wherein the first polyethylene copolymer has a density of from about 0.917 to about 0.927 g/cm 3 .
10. The polymer blend of claim 1 , wherein the first polyethylene copolymer has a Z-average molecular weight distribution (M z /M w ) of from about 2.0 to about 4.0.
11. The polymer blend of claim 1 , wherein the first polyethylene copolymer has an amount eluting at a temperature of from about 90° C. to about 105° C. of from about 5 to about 30 weight percent as determined by TREF.
12. The polymer blend of claim 1 , wherein the first polyethylene copolymer has an amount eluting at a temperature of above about 100° C. of about 0 weight percent as determined by TREF.
13. The polymer blend of claim 1 , wherein the second polyethylene copolymer has a density of from about 0.916 to about 0.930 g/cm 3 .
14. The polymer blend of claim 1 , wherein the second polyethylene copolymer has a CDBI 50 of at least about 50 wt %.
15. The polymer blend of claim 1 , wherein the second polyethylene copolymer has a molecular weight distribution (M w /M n ) of from about 1.7 to about 5.0.
16. A film structure comprising a least one layer comprising the polymer blend of claim 1 .
17. A blown film comprising the polymer blend of claim 1 , the film having a haze of less than about 10% and a gloss at about 45° of greater than about 55.
18. A cast film comprising the polymer blend of claim 1 , the film having a haze of less than about 10% and a gloss at about 45° of greater than about 55.
19. A polymer blend comprising:
a) from about 5 to about 95 wt % of a first polyethylene copolymer having a density of from about 0.916 to about 0.936 g/cm 3 , a melt index (I 2 ) of from about 0.1 to about 1.0 g/10 min, a melt flow ratio (I 21 /I 2 ) of from about 32 to about 50, a molecular weight distribution (M w /M n ) of from about 3.6 to about 6.5, a reverse comonomer distribution profile as determined by GPC-FTIR, a multimodal TREF profile, a composition distribution breadth index CDBI 50 of from 50 wt % to 75 wt % as determined by TREF and which further satisfies the relationship: (M w /M n )≧72[(I 21 /I 2 ) −1 +10 −6 (M n )];
and
b) from about 95 to about 5 wt % of a second polyethylene copolymer which is a linear low density polyethylene (LLDPE) having a density of from about 0.910 to about 0.940 g/cm 3 , a melt index (I 2 ) of from about 0.2 to about 5.0 g/10 min, and a melt flow ratio (I 21 /I 2 ) of less than about 32.
20. The polymer blend of claim 19 , wherein the first polyethylene copolymer has a δ XO of from about 55° to about 70°; wherein δ XO is the phase angle at which the complex modulus (G*) and the complex viscosity (η*) are numerically equivalent in a plot of phase angle vs complex modulus and complex viscosity as determined by dynamic mechanical analysis.
21. A film structure comprising a least one layer comprising the polymer blend of claim 19 .
22. A blown film comprising the polymer blend of claim 19 , the film having a haze of less than about 10% and a gloss at about 45° of greater than about 55.
23. A cast film comprising the polymer blend of claim 19 , the film having a haze of less than about 10% and a gloss at about 45° of greater than about 55.
24. A polymer blend comprising:
a) from about 5 to about 95 wt % of a first polyethylene copolymer having a density of from about 0.916 to about 0.936 g/cm 3 , a melt index (I 2 ) of from about 0.1 to about 1.0 g/10 min, a melt flow ratio (I 21 /I 2 ) of at least about 30, a molecular weight distribution (M w /M n ) of from about 3.6 to about 6.5, a reverse comonomer distribution profile as determined by GPC-FTIR, a multimodal TREF profile, a composition distribution breadth index CDBI 50 of from 50 wt % to 75 wt % as determined by TREF and which further satisfies the relationship: (M w /M n )≧72 [(I 21 /I 2 ) −1 +10 −6 (M n )];
and
b) from about 95 to about 5 wt % of a second polyethylene copolymer which is a linear low density polyethylene (LLDPE) having a density of from about 0.910 to about 0.940 g/cm 3 , a melt index (I 2 ) of from about 0.2 to about 5.0 g/10 min, and a melt flow ratio (I 21 /I 2 ) of less than about 35.
25. The polymer blend of claim 24 , wherein the first polyethylene copolymer has a δ XO of from about 55° to about 70°; wherein δ XO is the phase angle at which the complex modulus (G*) and the complex viscosity (η*) are numerically equivalent in a plot of phase angle vs complex modulus and complex viscosity as determined by dynamic mechanical analysis.
26. A film structure comprising a least one layer comprising the polymer blend of claim 24 .
27. A blown film comprising the polymer blend of claim 24 , the film having a haze of less than about 10% and a gloss of greater than about 55.
28. A cast film comprising the polymer blend of claim 24 , the film having a haze of less than about 10% and a gloss at about 45° of greater than about 55.