Organic compound, organic electronic device using same, and terminal for same
Disclosed are an organic compound, an organic electronic device using the same, and a terminal thereof.
1. A compound represented by Formula below,
wherein in Formula 1 above,
(1) Cz represents a substituted or unsubstituted carbazole derivative represented by Formula 2 below,
wherein in Formula 2, each R is the same or different, and is independently selected from the group consisting of a hydrogen atom, deuterium, tritium, a substituted or unsubstituted aryl group having 5˜60 nuclear carbon atoms, a substituted or unsubstituted hetero aryl group having 5˜60 nuclear carbon atoms, a substituted or unsubstituted C 1 ˜C 60 alkyl group, a substituted or unsubstituted C 1 ˜C 60 alkoxy group, a substituted or unsubstituted aryloxy group having 5˜60 nuclear carbon atoms, a substituted or unsubstituted arylthio group having 5˜60 nuclear carbon atoms, a substituted or unsubstituted alkoxycarbonyl group having 5˜60 nuclear carbon atoms, an amino group substituted by a substituted or unsubstituted alkyl or aryl group having 5˜60 nuclear carbon atoms, a halogen atom, a cyano group, a nitro group, a hydroxyl group and a carboxyl group, and R optionally forms an aliphatic or hetero ring together with an adjacent R group, or N of carbazole optionally forms a ring together with an adjacent R group,
(2) L is selected from the group including a substituted or unsubstituted arylene group having 5˜40 nuclear carbon atoms, a substituted or unsubstituted hetero arylene group having 5˜60 nuclear atoms, and a divalent or trivalent, substituted or unsubstituted aliphatic hydrocarbon group, and
(3) A represents a diamine derivative represented by Formula 3 below,
wherein in Formula 3, Ar 1 is selected from the group including a substituted or unsubstituted pheny group, a biphenyl group, a 1-naphthyl group, a 2-naphthyl group, a thiophene group, a pyrrole group, a furan group, and a pyridyl group, and Ar 2 through Ar 5 are the same or different, and each is independently a substituted or unsubstituted aryl group having 6˜60 nuclear atoms, or a substituted or unsubstituted heteroaryl group having 5˜60 nuclear atoms, and
4) n represents an integer of 0 to 3 and m represents an integer of 1 to 4.
2. The compound as claimed in claim 1 , wherein in Formula 3,
Ar 2 through Ar 5 are selected from the group consisting of functional groups noted in Table 1 below,
TABLE 1
Ar 2 , Ar 4
Ar 3 , Ar 5
1
2
3
4
5
6
7
8
9
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
100
101
102
103
104
105
106
107
108
109
110
111
112
113
114
115
116
117
118
119
120
121
122
123
124
125
126
127
128
129
130
131
132
133
134
135
136
137
138
139
140
141
142
143
144
145
146
147
148
149
150
151
152
153
154
155
156
157
158
159
160
161
162
163
164
165
166
167
168
170
171
172
173
174
175
176
177
178
179
180
181
182
183
184
185
186
187
188
189
190
191
192
193
194
195
196
197
198
199
200
201
202
203
204
205
206
207
208
209
210
211
212
213
214
215
216
217
218
219
220
221
223
224
225
226
227
228
229
230
231
232
233
234
235
Ar 2 , Ar 4
Ar 3 , Ar 5
236
237
238
239
240
241
242
243
244
245
246
247
248
249
250
251
252
253
254
3. The compound as claimed in claim 1 , wherein the compound represented by Formula 1 above comprises an aromatic compound represented by Formula 4 below,
wherein in Formula 4 above,
(1) R 5 through R 12 , and X are the same or different, and each is independently selected from the group consisting of a hydrogen atom, a substituted or unsubstituted aryl group having 5˜60 nuclear carbon atoms, a substituted or unsubstituted hetero aryl group having 5˜60 nuclear carbon atoms, a substituted or unsubstituted C 1 ˜C 60 alkyl group, a substituted or unsubstituted C 1 ˜C 60 alkoxy group, a substituted or unsubstituted aryloxy group having 5˜60 nuclear carbon atoms, a substituted or unsubstituted arylthio group having 5˜60 nuclear carbon atoms, a substituted or unsubstituted alkoxycarbonyl group having 5˜60 nuclear carbon atoms, an amino group substituted by a substituted or unsubstituted aryl group having 5˜60 nuclear carbon atoms, a halogen atom, a cyano group, a nitro group, a hydroxyl group and a carboxyl group,
(2) Ar 6 is a substituted or unsubstituted aryl group having 6˜60 nuclear atoms, a substituted or unsubstituted heteroaryl group having 5˜60 nuclear atoms, or a substituted or unsubstituted C 1 ˜C 60 alkyl group, and
(3) o represents an integer of 1 to 3.
4. The compound as claimed in claim 3 , wherein the compound represented by Formula 4 above is any one of compounds represented by Formula 5 below,
5. The compound as claimed in claim 1 , wherein the compound represented by Formula 1 above comprises an indoloacridine derivative comprising two or more diamine groups, represented by Formula 6 below,
wherein in Formula 6 above,
(1) R 13 through R 22 , and X are the same or different, and each is independently selected from the group consisting of a hydrogen atom, a substituted or unsubstituted aryl group having 5˜60 nuclear carbon atoms, a substituted or unsubstituted heteroaryl group having 5˜60 nuclear carbon atoms, a substituted or unsubstituted C 1 ˜C 60 alkyl group, a substituted or unsubstituted C 1 ˜C 60 alkoxy group, a substituted or unsubstituted aryloxy group having 5˜60 nuclear carbon atoms, a substituted or unsubstituted arylthio group having 5˜60 nuclear carbon atoms, a substituted or unsubstituted alkoxycarbonyl group having 5˜60 nuclear carbon atoms, an amino group substituted by a substituted or unsubstituted aryl group having 5˜60 nuclear carbon atoms, a halogen atom, a cyano group, a nitro group, a hydroxyl group and a carboxyl group, and
(2) p represents an integer of 1 to 2.
6. The compound as claimed in claim 5 , wherein the compound represented by Formula 6 above is any one of compounds represented by Formula 7 below,
7. The compound as claimed in claim 1 , wherein the compound represented by Formula 1 above comprises a compound represented by Formula 8 below,
wherein in Formula 8 above,
(1) R 23 through R 25 , and X are the same or different, and each is independently selected from the group consisting of a hydrogen atom, a substituted or unsubstituted aryl group having 5˜60 nuclear carbon atoms, a substituted or unsubstituted heteroaryl group having 5˜60 nuclear carbon atoms, a substituted or unsubstituted C 1 ˜C 60 alkyl group, a substituted or unsubstituted C 1 ˜C 60 alkoxy group, a substituted or unsubstituted aryloxy group having 5˜60 nuclear carbon atoms, a substituted or unsubstituted arylthio group having 5˜60 nuclear carbon atoms, a substituted or unsubstituted alkoxycarbonyl group having 5˜60 nuclear carbon atoms, an amino group substituted by a substituted or unsubstituted aryl group having 5˜60 nuclear carbon atoms, a halogen atom, a cyano group, a nitro group, a hydroxyl group and a carboxyl group; and
(2) Ar 7 is the same or different, and is independently selected from the group consisting of a hydrogen atom, deuterium, tritium, a substituted or unsubstituted aryl group having 5˜60 nuclear carbon atoms, a substituted or unsubstituted hetero aryl group having 5˜60 nuclear carbon atoms, a substituted or unsubstituted C 1 ˜C 60 alkyl group, a substituted or unsubstituted C 1 ˜C 60 alkoxy group, a substituted or unsubstituted aryloxy group having 5˜60 nuclear carbon atoms, a substituted or unsubstituted arylthio group having 5˜60 nuclear carbon atoms, a substituted or unsubstituted alkoxycarbonyl group having 5˜60 nuclear carbon atoms, an amino group substituted by a substituted or unsubstituted alkyl or aryl group having 5˜60 nuclear carbon atoms, a halogen atom, a cyano group, a nitro group, a hydroxyl group and a carboxyl group; and
(3) q represents an integer of 1 to 3.
8. The compound as claimed in claim 7 , wherein the compound represented by Formula 8 above is any one of compounds represented by Formula 9 below,
9. An organic electronic device comprising one or more organic material layers comprising the compound as claimed in claim 1 .
10. The organic electronic device as claimed in claim 9 , wherein the organic material layers are formed by a soluble process.
11. The organic electronic device as claimed in claim 9 , wherein the organic electronic device comprises a first electrode, said one or more organic material layers, and a second electrode.
12. The organic electronic device as claimed in claim 11 , wherein the organic material layers comprise at least one of a hole injection layer, a hole transport layer, an emitting layer, an electron transport layer, an electron injection layer, and an emitting layer.
13. The organic electronic device as claimed in claim 11 , wherein the organic material layers comprise a hole injection layer, and the hole injection layer comprises the compound.
14. A terminal comprising a display device and a control part for driving the display device, the display device comprising the organic electronic device as claimed in claim 11 .
15. The terminal as claimed in claim 14 , wherein the organic electronic device is any one of an organic light emitting diode (OLED), an organic solar cell, an organic photo conductor (OPC) drum, and an organic transistor (organic TFT).