Method of preparing nano-sized catalyst on carbon support
The present invention provides a method of synthesizing a nano-sized transition metal catalyst on a carbon support, including dissolving a stabilizer in ethanol thus preparing a mixture solution, adding a support to the mixture solution thus preparing a dispersion solution, dissolving a transition metal precursor in ethanol thus preparing a precursor solution, mixing the precursor solution with the dispersion solution with stirring, and then performing reduction, thus preparing the nano-sized transition metal catalyst. This method enables the synthesis of transition metal nanoparticles supported on carbon powder having a narrow particle size distribution and a wide degree of dispersion through a simple process, and is thus usefully applied to the formation of an electrode material or the like of a fuel cell.
1. A method of synthesizing a nano-sized transition metal catalyst, comprising:
dissolving cetyltrimethylammonium bromide as a stabilizer in ethanol to prepare a mixture solution;
adding a support to the mixture solution to prepare a dispersion solution;
dissolving a transition metal precursor comprising Ir in ethanol to prepare a precursor solution and mixing the precursor solution with the dispersion solution to prepare a dispersed precursor solution; and
reducing the dispersed precursor solution using NaBH 4 as a reducing agent to prepare nanoparticles,
wherein cetyltrimethylammonium bromide is present in a molar ratio relative to transition metal precursor comprising iridium of from about 0.25 to about 1.0.
2. The method of claim 1 , wherein the ethanol is anhydrous ethanol.
3. The method of claim 1 further comprising washing and drying the nanoparticles to obtain the nanoparticles as a powder.
4. A method of synthesizing a nano-sized transition metal catalyst, comprising: dissolving cetyltrimethylammonium bromide as a stabilizer in ethanol to prepare a mixture solution;
adding a support to the mixture solution to prepare a dispersion solution;
dissolving a transition metal precursor comprising Pt in ethanol to prepare a precursor solution and mixing the precursor solution with the dispersion solution to prepare a dispersed precursor solution; and
reducing the dispersed precursor solution using NaBH 4 as a reducing agent to prepare nanoparticles,
wherein cetyltrimethylammonium bromide is present in a molar ratio relative to transition metal precursor comprising platinum of from about 10 to about 30.
5. The method of claim 4 , wherein the ethanol is anhydrous ethanol.
6. The method of claim 4 , further comprising washing and drying the nanoparticles to obtain the nanoparticles as a powder.