Pneumatic tire having first tread cap zone and second tread cap zone
The invention is directed to a pneumatic tire having a rubber tread of a cap/base construction comprising an outer rubber tread cap layer containing an outer running surface and an underlying rubber tread base layer; wherein said tread cap layer comprises at least two circumferential, longitudinal rubber tread cap zones; wherein said tread cap zones individually extend from said tread cap running surface radially inward to said tread base layer; wherein said at least two tread cap zones comprises a first tread cap zone and a second tread cap zone adjacent to the first tread cap zone; the first tread cap zone and the second tread cap zone each independently comprising a vulcanizable rubber composition.
1. A pneumatic tire having a rubber tread of a cap/base construction comprising an outer rubber tread cap layer containing an outer running surface and an underlying rubber tread base layer; wherein said tread cap layer comprises at least two circumferential, longitudinal rubber tread cap zones; wherein said tread cap zones individually extend from said tread cap running surface radially inward to said tread base layer; wherein said at least two tread cap zones comprises a first tread cap zone and a second tread cap zone adjacent to the first tread cap zone; the first tread cap zone and the second tread cap zone each independently comprising a vulcanizable rubber composition comprising:
30 to 70 parts by weight, per 100 parts by weight of elastomer (phr) of a first styrene-butadiene rubber; wherein the first styrene-butadiene rubber is i) a solution-polymerized styrene-butadiene rubber with a bound styrene content of from 30 to 50 percent by weight, a vinyl 1,2 content of from 10 to 40 percent by weight based on the rubber weight, and a Tg of from about −40° C. to about −20° C.;
30 to 70 phr of a second styrene-butadiene rubber wherein the second styrene-butadiene rubber is a solution-polymerized styrene-butadiene rubber with a bound styrene content of from 25 to 45 percent by weight, a vinyl 1,2 content of from 20 to 60 percent by weight based on the rubber weight, and a Tg of from about −30° C. to about −5° C.;
40 to 60 phr of a low PCA process oil having a polycyclic aromatic content of less than 3 percent by weight as determined by the IP346 method, and 15 to 35 phr of a resin, wherein the total amount of oil and resin ranges from 55 to 75 phr; and
carbon black and silica in a combined amount of from 115 to 135 phr;
wherein at least one of the first and second styrene-butadiene rubbers has a weight average molecular weight greater than 1,000,000;
wherein the first styrene-butadiene rubber and the second styrene-butadiene rubber have a difference in Tg ranging from 10 to 20° C.;
wherein the weight ratio of silica to carbon black in the rubber composition of the first tread cap zone is in a range of from 4:1 to 6:1 and the weight ratio of silica to carbon black in the rubber composition of the second tread cap zone is in a range of from 0.7:1 greater than 1:1 to less than or equal to 1.3:1.
2. The pneumatic tire of claim 1 , wherein the resin is selected from a group consisting of i) a styrene-butadiene copolymer having a number average molecular weight (Mn) ranging from 1,000 to 15,000; a styrene content of from 17 to 27 percent by weight, and a vinyl content of 60 to 80 percent by weight, ii) a dimerized gum rosin; and (iii) a styrene/alphamethyl styrene resin.
3. The pneumatic tire of claim 1 , wherein the rubber composition further comprises from 5 to 20 phr of cis-1,4 polybutadiene having a Tg of from −110° C. to −90° C.