Water-soluble film having blend of PVOH polymers, and packets made therefrom
Disclosed are plasticized, water-soluble films having favorable cold-water solubility, wet handling, and thermoforming characteristics, and which can include a PVOH resin made up of blend of two or more PVOH polymers each having a monomodal molecular weight distribution, and the PVOH resin characterized by a viscosity in a range of about 13.5 cP to about 20 cP (or a corresponding weight average molecular weight), a degree of hydrolysis of about 84% to about 92%, a polydispersity index value in a range of about 1 to about 5, a residual water content of about 4 wt. % to about 10 wt. %, and a Resin Selection Index value in a range of 0.255 to 0.315; methods of making the films; compositions including PVOH resins for making the films; and pouch and packet articles made from the films.
1. A water-soluble film comprising:
at least 50 wt. % of a water-soluble polyvinyl alcohol (PVOH) resin that is a vinyl alcohol-vinyl acetate copolymer consisting of vinyl alcohol and vinyl acetate units, the PVOH resin having an average viscosity in a range of about 13.5 cP to about 20 cP, and a degree of hydrolysis in a range of about 84% to about 92%, the PVOH resin comprising a blend of first and second PVOH polymers that are vinyl-alcohol-vinyl acetate copolymers consisting of vinyl alcohol and vinyl acetate units, the first PVOH polymer having a viscosity in a range of about 8 cP to about 40 cP, the second PVOH polymer having a viscosity in a range of about 10 cP to about 40 cP, and the viscosity of the first PVOH polymer being less than the viscosity of the second PVOH polymer; and
the film further having no more than 30 wt. % of a PVOH polymer having a viscosity less than about 11 cP.
2. The water-soluble film of claim 1 , wherein the first PVOH polymer has a viscosity in a range of about 10 cP to about 20 cP.
3. The water-soluble film of claim 2 , wherein the first PVOH polymer has a viscosity in a range of about 10 cP to about 15 cP.
4. The water-soluble film of claim 1 , wherein the second PVOH polymer has a viscosity in a range of about 20 cP to about 30 cP.
5. The water-soluble film of claim 4 , wherein the second PVOH polymer has a viscosity in a range of about 20 cP to about 25 cP.
6. The water-soluble film of claim 1 further comprising about 1 wt. % to about 40 wt. % of a plasticizer.
7. The water-soluble film of claim 6 , wherein the plasticizer comprises a material selected from the group consisting of glycerin, sorbitol, propylene glycol, 2-methyl-1,3-propanediol, and a mixture thereof.
8. The water-soluble film of claim 6 , wherein the film comprises about 15 wt. % to about 35 wt. % of the plasticizer.
9. The water-soluble film of claim 1 , further comprising a residual moisture content in a range of about 4 wt. % to about 10 wt. %.
10. The water-soluble film of claim 1 , further characterized by a Resin Selection Index value in a range of 0.255 to 0.315.
11. The water-soluble film of claim 1 , further characterized by a Water-Drop Resistance Test value of 60% or less.
12. The water-soluble film of claim 11 , wherein the Water-Drop Resistance Test value is 45% or less.
13. The water-soluble film of claim 1 , further characterized by a Wash-Residue Test value of 4.5 or less.
14. The water-soluble film of claim 13 , wherein the Wash-Residue Test value is 3.5 or less.
15. A water-soluble film comprising:
at least 50 wt. % of a PVOH resin that is a vinyl alcohol-vinyl acetate copolymer consisting of vinyl alcohol and vinyl acetate units, the PVOH resin having an average viscosity in a range of about 13.5 cP to about 20 cP; a degree of hydrolysis in a range of about 84% to about 90%, and the PVOH resin comprising a blend of first and second PVOH polymers that are vinyl alcohol-vinyl acetate copolymers consisting of vinyl alcohol and vinyl acetate units, the first PVOH polymer having a viscosity in a range of about 8 cP to about 40 cP; the second PVOH polymer having a viscosity in a range of about 10 cP to about 40 cP; and the viscosity of the first PVOH polymer being less than the viscosity of the second PVOH polymer;
about 10 wt. % to about 40 wt. % of a plasticizer;
a residual moisture content of at least 4 wt. %; and
the film further having no more than 30 wt. % of a PVOH polymer having a viscosity less than about 11 cP.
16. The water-soluble film of claim 15 , wherein the residual moisture content is in a range of about 4 wt. % to about 10 wt. %.
17. A pouch comprising the water-soluble film of claim 1 .
18. The pouch of claim 17 comprising two or more compartments.