High efficiency thermoelectric materials based on metal/semiconductor nanocomposites
Composite epitaxial materials that comprise semimetallic ErAs nanoparticles or nanoislands epitaxially embedded in a semiconducting In 0.53 Ga 0.47 As matrix both as superlattices and randomly distributed throughout the matrix are disclosed. The presence of these particles increases the free electron concentration in the material while providing scattering centers for phonons. Electron concentration, mobility, and Seebeck coefficient of these materials are discussed and their potential for use in thermoelectric power generators is postulated. These composite materials in accordance with the present invention have high electrical conductivity, low thermal conductivity, and a high Seebeck coefficient. The ErAs nanoislands provides additional scattering mechanism for the mid to long wavelength phonon—the combination reduces the thermal conductivity below the alloy limit.
1. A nanocomposite material, comprising:
a III-V material; and
a plurality of semi-metallic nanoparticles, co-deposited and randomly distributed within at least some layers of the III-V material in a three-dimensional matrix of the III-V material, wherein the plurality of semi-metallic nanoparticles increase a thermoelectric figure of merit of the III-V material.
2. The nanocomposite material of claim 1 , wherein the plurality of semi-metallic nanoparticles are erbium arsenide.
3. The nanocomposite material of claim 1 , wherein the plurality of semi-metallic nanoparticles are rare-earth-group V compounds.
4. The nanocomposite material of claim 1 , wherein the plurality of semi-metallic nanoparticles have a rocksalt structure.
5. The nanocomposite material of claim 2 , wherein the III-V material is indium gallium arsenide.
6. The nanocomposite material of claim 5 , wherein the plurality of semi-metallic nanoparticles are epitaxially grown within the III-V material.
7. The nanocomposite material of claim 5 , wherein a total atomic fraction of the erbium arsenide is 0.3%.
8. A nanocomposite material, comprising:
a III-V superlattice material comprised of a plurality of layers; and
a plurality of nanoparticles, co-deposited, epitaxially embedded, and randomly distributed, within at least some of the layers of a three-dimensional matrix of the III-V superlattice material, wherein the plurality of nanoparticles increase a thermoelectric figure of merit of the III-V superlattice material.
9. The nanocomposite material of claim 8 , wherein the plurality of nanoparticles are semi-metallic nanoparticles.
10. The nanocomposite material of claim 9 , wherein the semi-metallic nanoparticles are erbium arsenide.
11. The nanocomposite material of claim 9 , wherein the semi-metallic nanoparticles have a rocksalt structure.
12. The nanocomposite material of claim 9 , wherein the semi-metallic nanoparticles are rare-earth-group V compounds.
13. The nanocomposite material of claim 10 , wherein the III-V superlattice material is indium gallium arsenide.
14. The nanocomposite material of claim 13 , wherein a total atomic fraction of the erbium arsenide is 0.3%.