Removal of atmospheric pollutants from gas, related apparatus, processes and uses thereof
One aspect of the invention relates to a method comprising a single-stage conversion of NO and/or NO 2 in a first stream to one or more mineral acids and/or salts thereof by reacting with nonionic gas phase chlorine dioxide ((ClO 2 ) 0 ). Another aspect of the invention relates to a method comprising first adjusting the NO and NO 2 concentrations in a first stream to a molar ratio of about 1:1, and then reacting with an aqueous metal hydroxide solution (MOH). Another aspect of the invention relates to an apparatus that can be used to carry out the methods disclosed herein. The methods disclosed herein are unexpectedly efficient and cost effective, and can be applied to a stream comprising high concentration and large volume of NO and/or NO 2 .
1. A method comprising:
contacting a first stream comprising NO and/or NO 2 with a second stream comprising (ClO 2 ) 0 to provide a third stream comprising NO and NO 2 at a molar ratio of about 1:1; and
contacting the third stream with a fourth stream comprising an aqueous metal hydroxide (MOH) solution to convert NO and NO 2 to MNO 2 .
2. The method of claim 1 , wherein the fourth stream further comprises an oxidant at a concentration by weight of about 2% to about 6%.
3. The method of claim 2 , wherein the oxidant is selected from the group consisting of NaOCl, H 2 O 2 , KMnO 4 , NaClO 2 , NaClO 3 and combinations thereof.
4. The method of claim 1 , wherein:
the second stream comprises (ClO 2 ) 0 adsorbed, suspended and/or dissolved in a liquid composition; and/or
the second stream comprises (ClO 2 ) 0 gas and the first stream contacts the second stream.