IP Library › Granted Patent US 9,153,819
Granted Patent B2
US 9,153,819 · App. 13/036,000 · Granted Oct 6, 2015

Negative electrode for a lithium ion battery

Inventors: Xiaosong Huang (Novi, MI); Yan Wu (Troy, MI)
Assignee: GM Global Technology Operations LLC
H01M4/622H01M4/13H01M4/386H01M4/387H01M4/583H01M4/625H01M4/626H01M10/0525Y02E60/122Y02T10/7011Y10T29/49108Y10T29/49115
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Quick Facts
Patent No.
US 9,153,819
App. No.
13/036,000
Granted
Oct 6, 2015
Kind
B2
Abstract

A negative electrode for a lithium ion battery includes an active electrode material, a conductive additive, and a binder for holding the active electrode material and the conductive additive together. The binder is chosen from polyethyleneimine, copolymers of polyethyleneimine, amine functionalized polyamides, proteins, and combinations thereof.

Claims (24)

1. A negative electrode for a lithium ion battery, comprising:

an active electrode material selected from the group consisting of FeSn, FeSn 2 , Cu 6 Sn 5 , Sn—Sb, SnO 2 , and combinations thereof;

a conductive additive; and

a binder holding the active electrode material and the conductive additive together, the binder being a protein in a form of a solid particle or pellet;

wherein: the active electrode material is present in an amount ranging from about 80 wt % to about 98 wt % of the negative electrode; the conductive additive is present in an amount ranging from about 1 wt % to about 10 wt % of the negative electrode; and the binder is present in an amount ranging from about 5 wt % to about 15 wt % of the negative electrode.

2. The negative electrode as defined in claim 1 wherein the conductive additive is selected from the group consisting of carbon blacks and nickel powders.

3. The negative electrode as defined in claim 1 wherein the negative electrode includes 85 wt % of the active electrode material, 5 wt % of the conductive additive, and 10 wt % of the binder.

4. A lithium ion battery, comprising:

a positive electrode;

the negative electrode of claim 1 ; and

an electrolyte disposed between the positive electrode and the negative electrode.

5. The lithium ion battery as defined in claim 4 wherein the conductive additive is selected from the group consisting of carbon blacks and nickel powders.

6. The lithium ion battery as defined in claim 4 wherein the positive electrode is selected from the group consisting of lithium composite oxide, a polyanion, and combinations thereof.

7. The lithium ion battery as defined in claim 4 wherein the electrolyte is selected from the group consisting of lithium hexafluorophosphate, lithium tetrafluoroborate, lithium perchlorate, lithium hexafluoroarsenate, lithium bisperfluoroethanesulfonimide, and combinations thereof.

8. A method of forming a negative electrode for a lithium ion battery, the method comprising:

dissolving a binder in water to form a solution having a concentration ranging from about 5 wt % to about 15 wt % of the binder, the binder being a protein in a form of a solid particle or pellet;

mixing an active electrode material with the binder solution to form a mixture, the active electrode material being selected from the group consisting of FeSn, FeSn 2 , Cu 6 Sn 5 , Sn—Sb, and SnO 2 ; and

introducing a conductive additive to the mixture;

wherein the negative electrode consists of the binder, the active electrode material and the conductive additive,

and wherein: the active electrode material is present in an amount ranging from about 80 wt % to about 98 wt % of the negative electrode; the conductive additive is present in an amount ranging from about 1 wt % to about 10 wt % of the negative electrode; and the binder is present in an amount ranging from about 5 wt % to about 15 wt % of the negative electrode.

9. The method as defined in claim 8 wherein prior to mixing the active electrode material with the binder solution, the method further comprises sonicating the solution at ambient temperature for a predetermined amount of time.

10. The method as defined in claim 8 wherein after the conductive additive is introduced, the method further comprises removing at least a portion of the water from the mixture to obtain a slurry having a viscosity ranging from about 100 cP to about 100,000 cP.

11. The method as defined in claim 10 wherein the electrode includes a current collector, and wherein the method further comprises applying the slurry onto a surface of the current collector to form a substantially uniform coating on the surface of the current collector.

12. The method as defined in claim 8 wherein the mixing is accomplished by i) stirring, or ii) ultrasonicating, or iii) ultrasonicating followed by stirring.

Assignments (3)
RELEASE OF SECURITY INTEREST Recorded Nov 7, 2014
From: WILMINGTON TRUST COMPANY
To: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Reel/Frame 034287/0159 →
SECURITY AGREEMENT Recorded Jun 28, 2012
From: GM GLOBAL TECHNOLOGY OPERATIONS LLC
To: WILMINGTON TRUST COMPANY
Reel/Frame 028466/0870 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 1, 2011
From: HUANG, XIAOSONG; WU, YAN
To: GM GLOBAL TECHNOLOGY OPERATIONS LLC
Reel/Frame 025878/0629 →
Continuity (1)
Related Publication 20120219852A1 · Aug 30, 2012