Polyamide-based thermoplastic polymer compositions
Polyamide-based thermoplastic polymer compositions that exhibit a good balance among the properties thereof, in particular their mechanical properties, and a high fluidity in the molten state; such compositions contain at least one high-fluidity polyamide and a shock modification agent having functional groups that react with the polyimide.
1. A polymer composition comprising:
a) a polyamide 6 or 66 obtained via a process of polymerization of monomers of polyamide 6 or 66, in the presence of a monofunctional compound comprising n-hexadecylamine, n-octadecylamine, n-dodecylamine, acetic acid, lauric acid, benzylamine or benzoic acid, and/or a difunctional compound comprising succinic acid, terephthalic acid, isophthalic acid, sebacic acid, azelaic acid, dodecanoic acid, fatty acid dimers, di(β-ethylcarboxy)cyclohexanone, 5-methyl pentamethylenediamine, metaxylylenediamine, isophorone diamine or 1,4-cyclohexanediamine,
said polyamide 6 being a polyamide comprising at least 80 mol % of recurring units derived from caprolactam monomer,
said polyamide 66 being a polyamide comprising at least 80 mol % of recurring units derived from adipic acid and hexamethylenediamine monomers,
said polyamide having a melt flow index of greater than or equal to 10 g/10 min. according to the ISO1133 standard measured at a temperature of 275° C. with a load of 325 g; and
b) at least one impact modifier selected from the group consisting of ethylene/acrylic ester/glycidyl methacrylate terpolymers, ethylene/n-butyl acrylate/glycidyl methacrylate copolymers, and ethylene/maleic anhydride copolymers.
2. The polymer composition as defined by claim 1 , wherein the molecular weight Mn of the polyamide ranges from 5,000 g/mol to 15,000 g/mol.
3. The polymer composition as defined by claim 1 , wherein the polyamide has a polydispersity index less than or equal to 2.
4. The polymer composition as defined by claim 1 , wherein the polyamide has a melt flow index ranging from 10 to 50 g/10 min.
5. The polymer composition as defined by claim 1 , wherein the polyamide has a melt flow index ranging from 20 to 40 g/10 min.
6. The polymer composition as defined by claim 1 , wherein the proportion of the at least one impact modifier present therein ranges from 0.1% to 10% by weight of the total composition.
7. The polymer composition as defined by claim 1 , comprising at least one reinforcing and/or bulking filler.
8. A method for producing a polymer composition as defined by claim 1 , comprising melt blending said polyamide a) and said impact modifier b).
9. The polymer composition of claim 1 , wherein the difunctional compound is present in an excess, based on the stoichiometry, during the polymerization of the monomers.
10. The polymer composition as defined by claim 1 , wherein said polyamide 6 or 66 comprises acid terminal end groups and amine terminal end groups, the proportion of acid terminal end groups is different than the proportion of amine terminal end groups and the ratio of acid terminal end groups/amine terminal end groups is ≧2 or ≦0.5.
11. The polymer composition as defined by claim 1 , wherein the composition has an unnotched Charpy impact of 78.8 to 88.8 KJ/m 2 , when measured according to ISO standard 179/1 eU.
12. The polymer composition as defined by claim 1 , wherein when the composition is tested in a spiral test by melting the granules and injecting them into a spiral-shaped mold with a semicircular cross section of thickness 2 mm and of width 4 cm, in a BM-Biraghi 85T press at a barrel temperature of 275° C. and a mold temperature of 80° C. and with a maximum injection pressure of 130 bar, the length of the mold filled by the composition is from 41 cm to 47 cm.