Process for producing resin-coated pigment, resin-coated pigment, aqueous pigment dispersion and aqueous colorant composition containing the same
A process for producing a resin-coated pigment capable of providing an ink and a paint being superior in dispersion stability of a pigment and having rapid drying property, high gloss and density without containing those such as an organic solvent and a salt that cause the lowering of performance of pigment dispersion, characterized in that a pigment is dispersed in an aqueous solution in which an anionic group-containing resin is dissolved in the presence of a basic compound and then, the anionic group-containing resin is precipitated on the surface of the pigment by removing the basic compound in the aqueous solution, using an ion exchange means.
1. A process for producing a pigment coated with a resin, comprising the steps of:
dispersing a pigment into an aqueous solution in which an anionic group-containing resin is dissolved in the presence of a basic compound, wherein the basic compound is used for dissolving the anion group-containing resin, and
then removing the basic compound in the aqueous solution by using an inorganic ion exchanger or an ion exchange resin to precipitate the anionic group-containing resin on the surface of the pigment.
2. The process for producing a pigment coated with a resin of claim 1 , wherein the basic compound in the aqueous solution is removed by replacing the cation of the basic compound by a hydrogen ion, using an organic ion exchanger and/or an inorganic ion exchanger as the ion exchange means.
3. The process for producing a pigment coated with a resin of claim 2 , wherein substantially the whole amount of the basic compound in the aqueous solution is removed.
4. The process for producing a pigment coated with a resin of claim 2 , wherein the ion exchange is carried out until the pH of the aqueous solution is less than 4.
5. The process for producing a pigment coated with a resin of claim 1 , wherein the acid value of the anionic group-containing resin is 40 to 300 KOH mg/g.
6. A process for producing an aqueous pigment dispersion, comprising the steps of:
dispersing a pigment into an aqueous solution in which an anionic group-containing resin is dissolved in the presence of a basic compound, wherein the basic compound is used for dissolving the anion group-containing resin, and
then partially removing the basic compound in the aqueous solution by using an inorganic ion exchanger or an ion exchange resin.
7. The process for producing an aqueous pigment dispersion of claim 6 , wherein the basic compound in the aqueous solution is partially removed by replacing a portion of the cation of the basic compound by a hydrogen ion, using an organic ion exchanger and/or an inorganic ion exchanger as the ion exchange means.
8. The process for producing an aqueous pigment dispersion of claim 7 , wherein the ion exchange is carried out until the pH of the aqueous solution is within a range of 4 to 8.
9. The process for producing an aqueous pigment dispersion of claim 6 , wherein the acid value of the anionic group-containing resin is 40 to 300 KOH mg/g.