IP Library Granted Patent US 9,165,721
Granted Patent B2
US 9,165,721 · App. 14/327,753 · Granted Oct 20, 2015

Inkjet-printed flexible electronic components from graphene oxide

Inventors: Woo Young Lee (Ridgewood, NJ); Linh Le (New York, NY); De Kong (Hoboken, NJ); Matthew Henderson Ervin (Clarksville, MD); James L. Zunino, III (Booton Township, NJ); Brian E. Fuchs (Hackettstown, NJ)
Assignees: THE TRUSTEES OF THE STEVENS INSTITUTE OF TECHNOLOGY; THE UNITED STATES OF AMERICA, as represented by the Secretary of the Army
H01G11/42H01G11/36H01G11/48H01G11/80H01G11/86H05K1/162H05K3/125H05K1/0393H05K1/092H05K2201/0323Y02E60/13
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Quick Facts
Patent No.
US 9,165,721
App. No.
14/327,753
Granted
Oct 20, 2015
Kind
B2
Abstract

An electrical component includes an inkjet-printed graphene electrode. Graphene oxide flakes are deposited on a substrate in a graphene oxide ink using an inkjet printer. The deposited graphene oxide is thermally reduced to graphene. The electrical properties of the electrode are comparable to those of electrodes made using activated carbon, carbon nanotubes or graphene made by other methods. The electrical properties of the graphene electrodes may be tailored by adding nanoparticles of other materials to the ink to serve as conductivity enhancers, spacers, or to confer pseudocapacitance. Inkjet-printing can be used to make graphene electrodes of a desired thickness in preselected patterns. Inkjet printing can be used to make highly-transparent graphene electrodes. Inkjet-printed graphene electrodes may be used to fabricate double-layer capacitors that store energy by nanoscale charge separation at the electrode-electrolyte interface (i.e., “supercapacitors”).

Claims (6)

1. A capacitor, comprising

a first inkjet-printed electrode formed on a surface of a substrate, said first electrode including a first plurality of overlapping dot-like structures which include graphene flakes;

a second inkjet-printed electrode formed on said surface of said substrate, said second electrode including a second plurality of overlapping dot-like structures which include graphene flakes, wherein said first and second electrodes have a fingered geometry and are spaced away from each other in a cross-finger interdigitated arrangement.

2. The capacitor of claim 1 , further comprising first and second current collectors, wherein said first and second electrodes are respectively in contact with said first and second current collectors.

3. The capacitor of claim 2 , wherein said first and second electrodes and an electrolyte are packaged together by a hermetic seal, said first and second current collectors being exposed outside of said hermetic seal.

4. The capacitor of claim 1 , wherein said first and second electrodes are formed by a process including the steps of depositing graphene oxide flakes in droplets of liquid onto said surface of said substrate so as to form said overlapping dot-like structures which include said graphene oxide flakes, and then reducing at least some of said graphene oxide flakes so to convert them to graphene flakes, thereby making said first and second electrodes electrically conductive.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 18, 2015
From: ERVIN, MATTHEW HENDERSON; ZUNINO, III, JAMES L.; FUCHS, BRIAN E.
To: GOVERNMENT OF THE UNITED STATES, AS REPRESENTED BY THE SECRETARY OF THE ARMY
Reel/Frame 035194/0762 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 4, 2015
From: LEE, WOO YOUNG; LE, LINH; KONG, DE
To: THE TRUSTEES OF THE STEVENS INSTITUTE OF TECHNOLOGY
Reel/Frame 035086/0343 →
Continuity (3)
Division 13301124 · Nov 21, 2011
Provisional Application 61416062 · Nov 22, 2010
Related Publication 20140334065A1 · Nov 13, 2014