Polycarbonate-siloxane copolymer compositions with improved appearance properties
Disclosed herein are methods and compositions polycarbonate blend compositions with improved appearance characteristics and impact characteristics. The resulting compositions, comprising a polycarbonate polymer, a first polysiloxane-polycarbonate copolymer, a second polysiloxane-polycarbonate copolymer, and optionally a color composition, can be used in the manufacture of articles while still retaining advantageous mechanical properties, melt flow properties, and appearance characteristics such as the ability to achieve deep black and bright white colors. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.
1. A polycarbonate blend composition comprising:
a) a first polycarbonate-polysiloxane polymer, wherein the first polycarbonate-polysiloxane polymer:
i. has a weight average molecular weight from about 21,000 to about 25,000 as measured by gel permeation chromatography;
ii. comprises polydiorganosiloxane with an average block length of from about 30 to about 100; and
iii. comprises diorganosiloxane from about 4 wt % to about 8 wt % based on the total weight of the first polysiloxane-polycarbonate polymer being 100%;
b) a second polycarbonate-polysiloxane polymer, wherein the second polycarbonate-polysiloxane polymer:
i. has a weight average molecular weight from about 28,000 to about 32,000 as measured by gel permeation chromatography;
ii. is present in an amount from about 5 wt % to about 10 wt % based on the total weight of a), b), and c) being 100%;
iii. comprises polydiorganosiloxane with an average block length of from about 30 to about 100; and
iv. comprises diorganosiloxane from about 15 wt % to about 30 wt % based on the total weight of the second polysiloxane-polycarbonate polymer being 100%; and
c) a first polycarbonate polymer comprising bisphenol A residues, wherein the first polycarbonate polymer:
i. has a weight average molecular weight from about 17,500 to about 19,500 as measured by gel permeation chromatography; and
ii. is present in an amount greater than or equal to about 5 wt % based on the total weight of a), b), and c) being 100%;
wherein the wt % ratio of the first polycarbonate-polysiloxane polymer to the second polycarbonate-polysiloxane polymer is greater than or equal to about 8; and
wherein the polycarbonate blend composition has a melt volume rate from about 14 cm 3 /10 min to about 30 cm 3 /10 min when determined in accordance with ASTM D1238 at about 300° C. under a load of about 1.2 kg.
2. The polycarbonate blend composition of claim 1 , wherein the polydiorganosiloxane of the first polycarbonate-polysiloxane polymer has an average block length of from about 30 to about 60.
3. The polycarbonate blend composition of claim 1 , wherein the diorganosiloxane of the first polycarbonate-polysiloxane polymer is present in the amount of from about 4 wt % to about 7 wt % based on the total weight of the first polysiloxane-polycarbonate being 100%.
4. The polycarbonate blend composition of claim 1 , wherein the diorganosiloxane of the first polycarbonate-polysiloxane polymer is present in the amount of from about 5 wt % to about 7 wt % based on the total weight of the first polysiloxane-polycarbonate being 100%.
5. The polycarbonate blend composition of claim 1 , wherein the first polycarbonate-polysiloxane polymer is present in an amount greater than or equal to 91 wt % based on the total weight of a), b), and c) being 100%.
6. The polycarbonate blend composition of claim 1 , wherein the first polycarbonate-polysiloxane polymer has a weight average molecular weight from about 21.000 to about 25,000 as measured by gel permeation chromatography.
7. The polycarbonate blend composition of claim 1 , wherein the polydiorganosiloxane of the second polycarbonate-polysiloxane polymer has with an average block length of from about 40 to about 100.
8. The polycarbonate blend composition of claim 1 , wherein the polydiorganosiloxane of the second polycarbonate-polysiloxane polymer has with an average block length of from about 30 to about 90.
9. The polycarbonate blend composition of claim 1 , wherein the diorganosiloxane of the of the second polycarbonate-polysiloxane polymer is present in the amount of from about 15 wt % to about 25 wt % based on the total weight of the second polysiloxane-polycarbonate being 100%.
10. The polycarbonate blend composition of claim 1 , wherein the diorganosiloxane of the of the second polycarbonate-polysiloxane polymer is present in the amount of from about 17 wt % to about 23 wt % based on the total weight of the second polysiloxane-polycarbonate being 100%.
11. The polycarbonate blend composition of claim 1 , wherein the diorganosiloxane of the of the second polycarbonate-polysiloxane polymer is present in the amount of from about 19 wt % to about 21 wt % based on the total weight of the second polysiloxane-polycarbonate being 100%.
12. The polycarbonate blend composition of claim 1 , further comprising:
d) a second polycarbonate polymer comprising bisphenol A residues with a weight average molecular weight from about 20,500 to about 32,000 as measured by gel permeation chromatography, wherein the polycarbonate blend composition has a total diorganosiloxane content of from about 2.5 wt % to about 7.5 wt % based on the total weight of the polycarbonate blend composition being 100%.
13. The polycarbonate blend composition of claim 12 , wherein the second polycarbonate-polysiloxane polymer is present in an amount from about 5 wt % to about 9 wt % based on the total weight of the polycarbonate blend composition being 100%.
14. The polycarbonate blend composition of claim 1 , wherein the wt % ratio of the first polycarbonate-polysiloxane polymer to the second polycarbonate-polysiloxane polymer is from about 8 to about 13.
15. The polycarbonate blend composition of claim 1 , further comprising a filler composition.
16. The polycarbonate blend compositions of claim 15 , wherein the filler composition comprises TiO 2 .
17. The polycarbonate blend compositions of claim 15 , wherein the filler composition is present in an amount from about 1 wt % to about 20 wt % based on the total weight of the polycarbonate blend composition being 100%.
18. The polycarbonate blend composition of claim 1 , wherein polycarbonate blend composition has a ductile/brittle transition temperature of less than or equal to about −20° C. as determined in accordance with ASTM D256-2010 on a molded part having a thickness of about 3.2 mm.
19. The polycarbonate blend composition of claim 1 , wherein a molded article comprising the disclosed polycarbonate blend compositions has reduced black streaking compared to a reference composition consisting essentially of substantially the same components, the reference composition having a wt % ratio of the first polysiloxane-polycarbonate polymer to the second polysiloxane-polycarbonate polymer less than or equal to about 8.
20. The polycarbonate blend composition of claim 1 , wherein a molded article comprising the disclosed polycarbonate blend compositions has reduced knitline compared to a reference composition consisting essentially of substantially the same components, the reference composition having a wt % ratio of the first polysiloxane-polycarbonate polymer to the second polysiloxane-polycarbonate polymer less than or equal to about 8.
21. An article of manufacture formed from the polycarbonate blend composition claim 1 .
22. The article of claim 21 , wherein the article is one of an injection molded part and an extruded film or sheet.
23. The article of claim 21 , wherein the article is a component for an electronic device.
24. The article of claim 21 , wherein the article is a housing for a cell phone, smart phone, GPS device, laptop computer, tablet computer, e-reader, or copier.
25. A method of improving appearance properties of a molded article formed from a polycarbonate blend composition, the method comprising combining:
a) a first polycarbonate-polysiloxane polymer, wherein the first polycarbonate-polysiloxane polymer:
i. has a weight average molecular weight from about 21,000 to about 25,000 as measured by gel permeation chromatography;
ii. comprises a polydiorganosiloxane block with an average block length of from about 30 to about 100; and
iii. comprises a diorganosiloxane content from about 4 wt % to about 8 wt % based on the total weight of the first polysiloxane-polycarbonate being 100%;
b) a second polycarbonate-polysiloxane polymer, wherein the second polycarbonate-polysiloxane polymer:
i. has a weight average molecular weight from about 28,000 to about 32,000 as measured by gel permeation chromatography;
ii. is present in an amount from about 5 wt % to about 10 wt % based on the total weight of a), b), and c) being 100%;
iii. comprises a polydiorganosiloxane block with an average block length of from about 30 to about 100; and
iv. comprises a diorganosiloxane content from about 15 wt % to about 30 wt % based on the total weight of the second polysiloxane-polycarbonate being 100%
c) a first polycarbonate polymer comprising bisphenol A residues, wherein the first polycarbonate polymer:
i. has a weight average molecular weight from about 17.500 to about 19,500 as measured by gel permeation chromatography; and
ii. is present in an amount greater than or equal to about 5 wt % based on the total weight of the polycarbonate blend composition being 100%; and
wherein the wt % ratio of the first polycarbonate-polysiloxane polymer to the second polycarbonate-polysiloxane polymer is greater than or equal to about 8;
wherein the polycarbonate blend composition has a total diorganosiloxane content of from about 2.5 wt % to about 7.5 wt % based on the total weight of the polycarbonate blend composition being 100%; and
wherein the polycarbonate blend composition has a melt volume rate from about 14 cm 3 10 min to about 25 cm 3 /min when determined in accordance with ASTM D1238 at about 300° C. under a load of about 1.2 kg.