Core-shell type anode active material for lithium secondary batteries, method for preparing the same and lithium secondary batteries comprising the same
Provided are a core-shell type anode active material for lithium secondary batteries including a carbonaceous material core; and a shell formed outside the carbonaceous material core, the shell including a PTC (Positive Temperature Coefficient) medium. The core-shell type anode active material for lithium secondary batteries has the shell including the PTC medium, and thus has the improved conductivity and high output density, exhibiting excellent electrical characteristics. And, a lithium secondary battery manufactured using the anode active material has excellent safety, in particular safety against overcharge and external short circuit.
1. A core-shell type anode active material for lithium secondary batteries, comprising:
a carbonaceous material core; and
a shell coated on the carbonaceous material core and comprising:
a repetitively usable Positive Temperature Coefficient (PTC) medium; and
at least one metal oxide selected from the group consisting of titanium dioxide and spinel-type lithium titanium oxide,
wherein the weight ratio of the carbonaceous material and the PTC medium (the carbonaceous material : the PTC medium) is 100:1 to 100:2, and
wherein the weight ratio of the carbonaceous material and the metal oxide (the carbonaceous material : the metal oxide) is 100:1 to 100:2.
2. The core-shell type anode active material for lithium secondary batteries according to claim 1 ,
wherein the carbonaceous material of the core is at least one selected from the group consisting of soft carbon, hard carbon, natural graphite, Kish graphite, pyrolytic carbon, mesophase pitch based carbon fiber, meso-carbon microbeads, mesophase pitches, and petroleum and coal tar pitch derived cokes.
3. The core-shell type anode active material for lithium secondary batteries according to claim 1 ,
wherein the PTC medium has an average particle size of 2 nm to 1 μ.
4. The core-shell type anode active material for lithium secondary batteries according to claim 1 ,
wherein the PTC medium is barium titanate.
5. The core-shell type anode active material for lithium secondary batteries according to claim 1 ,
wherein the metal oxide has an average particle size of 20 to 800 nm.
6. The core-shell type anode active material for lithium secondary batteries according to claim 1 ,
wherein the shell further comprises a conductive material.
7. A method for preparing a core-shell type anode active material for lithium secondary batteries, comprising:
(S1) preparing a core forming carbonaceous material; and
(S2) forming a shell by coating the carbonaceous material core with a shell forming material comprising a PTC medium.
8. The method for preparing a core-shell type anode active material for lithium secondary batteries according to claim 7 ,
wherein, in the step (S2), the coating is dry coating.
9. The method for preparing a core-shell type anode active material for lithium secondary batteries according to claim 7 ,
wherein, in the step (S2), the shell forming material further comprises at least one metal oxide selected from the group consisting of titan dioxide and spinel-type lithium titan oxide.
10. The method for preparing a core-shell type anode active material for lithium secondary batteries according to claim 7 ,
wherein, in the step (S2), the shell forming material further comprises a conductive material.
11. An anode of lithium secondary batteries, formed on at least one side of an anode current collector and having an anode active material layer including an anode active material of claim 1 , a binder and a conductive material.
12. A lithium secondary battery, comprising the anode of claim 11 .