Cold rolled steel sheet
In order to obtain a cold rolled steel sheet having excellent press formability, a cold rolled steel sheet has an inorganic film containing a crystalline layered material having an average film thickness of 10 nm to 2000 nm on a surface thereof. The crystalline layered material preferably is, for example, a layered double hydroxide represented by [M 2+ 1−X M 3+ X (OH) 2 ][A n− ] x/n .zH 2 O, where: M 2+ is one or more of Mg 2+ , Ca 2+ , Fe 2+ , Ni 2+ , and Zn 2+ ; M 3+ is one or more of Al 3+ , Fe 3+ , and Cr 3+ ; and A n− is one or more of OH − , CO 3 2− , Cl − , and (SO 4 ) 2− .
1. A cold rolled steel sheet comprising an inorganic film containing a crystalline layered material on a surface thereof, wherein the inorganic film has an average film thickness of 10 nm to 2000 nm, wherein the crystalline layered material is a layered double hydroxide represented by [M 2+ 1-X M 3+ X (OH) 2 ][A n− ] x/n .zH 2 O, wherein:
M 2+ is one or more of Ca 2+ , Zn 2+ , Pb 2+ , and Sn 2+ ;
M 3+ is one or more of Cr 3+ , 3/4Zr 4+ , and Mo 3+ ; and
A n− is one or more of F − , Cl − , Br − , (C 2 O 4 ) 2− , I − , (NO 3 ) − , (SO 4 ) 2− , (BrO 3 ) − , (IO 3 ) − , (V 10 O 28 ) 6− , (Si 2 O 5 ) 2− , (ClO 4 ) − , (CH 3 COO) − , [C 6 H 4 (CO 2 ) 2 ] 2− , (C 6 H 5 COO) − , [C 8 H 16 (CO 2 ) 2 ] 2− , n(C 8 H 17 SO 4 ) − , n(C 12 H 25 SO 4 ) − , n(C 18 H 37 SO 4 ) − , and SiO 4 4− ,
and wherein 0<x≦0.33, 1≦n≦2, and 0.33≦z≦1.
2. A cold rolled steel sheet comprising an inorganic film containing a crystalline layered material on a surface thereof, wherein the inorganic film has an average film thickness of 10 nm to 2000 nm, wherein the crystalline layered material is a layered double hydroxide represented by [M 2+ 1-X M 3+ X (OH) 2 ][A n− ] x/n .zH 2 O, wherein:
M 2+ is one or more of Ca 2+ and Zn 2+ ;
M 3+ is Cr 3+ ; and
A n− is one or more of Cl − and (SO 4 ) 2− ,
and wherein 0<x≦0.33, 15≦n≦2, and 0.33≦z≦1.