IP Library Granted Patent US 9,180,648
Granted Patent B2
US 9,180,648 · App. 13/139,576 · Granted Nov 10, 2015

Laminate for laminated glass

Inventors: Juichi Fukatani (Shiga, JP); Izumi Omoto (Shiga, JP); Seiko Ichikawa (Shiga, JP); Kouichi Tanaka (Tokyo, JP); Mayu Kameda (Tokyo, JP)
Assignees: SEKISUI CHEMICAL CO., LTD.; NIPPON KAYAKU KABUSHIKI KAISHA; POLATECHNO CO., LTD.
B32B17/10761B32B17/10458B32B17/10605C08K5/10G02B5/3016G02F1/13363G02F2202/28Y10T428/105
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Quick Facts
Patent No.
US 9,180,648
App. No.
13/139,576
Granted
Nov 10, 2015
Kind
B2
Abstract

A laminate for a laminated glass, comprising an interlayer film for a laminated glass laminated with a retardation element interposed between an adhesive layer A and an adhesive layer B, wherein the retardation element contains a liquid-crystal compound and at least one compound selected from the group consisting of a compound represented by the following formula (1), a compound represented by the following formula (2), and a compound represented by the following formula (3). In formula (1), n represents an integer from 3 to 10 and R 2 represents a —CH 2 —CH 2 — group, a —CH 2 —CH(CH 3 )— group, or a —CH 2 —CH 2 —CH 2 — group. In formula (2), R 3 represents a —(CH 2 ) p — group or a phenylene group and p represents an integer from 4 to 8. In formula (3), R 4 represents a substituted phenylene group. R 1-1 , R 1-2 , and R 1-3 in formulas (1) to (3) are the same or different, each representing an alkyl group that has a branched structure and that contains at least 5 carbon atoms.

Claims (27)

1. A laminate for a laminated glass,

which comprises an interlayer film for a laminated glass laminated with a retardation element interposed between an adhesive layer A and an adhesive layer B,

wherein the retardation element comprises blend of a liquid-crystal compound and at least one compound selected from the group consisting of a compound represented by the following formula (1), a compound represented by the following formula (2), and a compound represented by the following formula (3),

in formula (1), n represents an integer from 3 to 10 and R 2 represents a —CH 2 —CH 2 — group, a —CH 2 —CH(CH 3 )— group, or a —CH 2 —CH 2 —CH 2 — group;

in formula (2), R 3 represents a —(CH 2 ) p — group or a phenylene group and p represents an integer from 4 to 8;

in formula (3), R 4 presents a substituted phenylene group; and

R 1-1 , R 1-2 , and R 1-3 in formulas (1) to (3) are the same or different, each representing an alkyl group that has a branched structure and that contains at least 5 carbon atoms,

wherein the retardation element has excellent heat resistance, exhibits little variation in its retardation value in high-temperature atmospheres, and can maintain stable optical properties

wherein the liquid-crystal compound is a polymerizable liquid crystal, and the polymerizable liquid crystal has been polymerized, and

wherein the polymerizable liquid crystal is a polymerizable liquid crystal represented by the following formula (4),

in formula (4), q and r each represent an integer from 1 to 10; X represents —COO— or —O—; Y represents —OC(O)O— or —O—; Z represents —COO or —OCO—; R 5 represents a phenylene group; R 6 represents a substituted phenylene group, a substituted biphenylene group, or a fluorenyl group; R 7 represents —H, —(CH 2 ) w —CH 3 or —COO—(CH 2 ) w —CH 3 ; and w represents an integer from 0 to 11.

2. The laminate for a laminated glass according to claim 1 ,

wherein the compound represented by formula (1) is triethylene glycol di-2-ethylhexanoate, tetraethylene glycol di-2-ethylhexanoate, triethylene glycol di-2-ethylbutyrate, tetraethylene glycol di-2-ethylbutyrate, pentaethylene glycol di-2-ethylhexanoate, octaethylene glycol di-2-ethylhexanoate, nonaethylene glycol di-2-ethylhexanoate, or decaethylene glycol di-2-ethylhexanoate.

3. The laminate for a laminated glass according to claim 1 ,

wherein the compound represented by formula (2) is bis(2-ethylhexyl) adipate, bis(2-ethylbutyl) adipate, bis(2-ethylhexyl) azelate, bis(2-ethylbutyl) azelate, di-2-ethylhexyl sebacate, di-2-ethylbutyl sebacate, di-2-ethylhexyl phthalate, or di-2-ethylbutyl phthalate.

4. The laminate for a laminated glass according to claim 1 ,

wherein the compound represented by formula (3) is tri-2-ethylhexyl trimellitate or tri-2-ethylbutyl trimellitate.

5. The laminate for a laminated glass according to claim 1 ,

wherein the content of the at least one compound selected from the group consisting of the compound represented by formula (1), the compound represented by formula (2), and the compound represented by formula (3), is 0.1 to 300 parts by weight per 100 parts by weight of the liquid-crystal compound.

6. The laminate for a laminated glass according to claim 1 ,

wherein the interlayer film for a laminated glass comprises a thermoplastic resin.

7. The laminate for a laminated glass according to claim 6 ,

wherein the interlayer film for a laminated glass further comprises an ultraviolet absorber.

8. The laminate for a laminated glass according to claim 1 ,

wherein the interlayer film for a laminated glass comprises a polyvinyl acetal resin and a plasticizer.

9. The laminate for a laminated glass according to claim 8 ,

wherein the plasticizer is at least one compound selected from the group consisting of the compound represented by formula (1), the compound represented by formula (2), and the compound represented by formula (3).

Assignments (2)
DE-MERGER Recorded Jan 24, 2022
From: NIPPON KAYAKU CO., LTD.; POLATECHNO CO.,LTD.; SEKISUI CHEMICAL CO., LTD.
To: NIPPON KAYAKU CO., LTD.; SEKISUI CHEMICAL CO., LTD.
Reel/Frame 058921/0234 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 3, 2011
From: FUKATANI, JUICHI; OMOTO, IZUMI; ICHIKAWA, SEIKO; TANAKA, KOUICHI; KAMEDA, MAYU
To: SEKISUI CHEMICAL CO., LTD.; NIPPON KAYAKU KABUSHIKI KAISHA; POLATECHNO CO., LTD.
Reel/Frame 026692/0041 →
Priority Claims (1)
JP 2008-326169 · Dec 22, 2008 · national
Continuity (1)
Related Publication 20110293857A1 · Dec 1, 2011